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141.
Chikako Yoshikawa-Murakami Yuki Mizutani Akemi Ryu Eiji Naru Takashi Teramura Yuta Homma Mitsunori Fukuda 《International journal of molecular sciences》2020,21(22)
Melanin incorporated into keratinocytes plays an important role in photoprotection; however, abnormal melanin accumulation causes hyperpigmentary disorders. To understand the mechanism behind the accumulation of excess melanin in the skin, it is essential to clarify the spatial distribution of melanosomes or melanin in the epidermis. Although several markers have been used to detect melanosomes or melanin, no suitable markers to determine the precise localization of melanin in the epidermis have been reported. In this study, we showed that melanocore-interacting Kif1c-tail (M-INK), a recently developed fluorescent probe for visualizing mature melanosomes, binds to purified melanin in vitro, and applied it for detecting melanin in human skin tissues. Frozen skin sections from different phototypes were co-stained for the hemagglutinin (HA)-tagged M-INK probe and markers of melanocytes or keratinocytes, and a wide distribution of melanin was observed in the epidermis. Analysis of the different skin phototypes indicated that the fluorescent signals of HA-M-INK correlated well with skin color. The reconstruction of three-dimensional images of epidermal sheets enabled us to observe the spatial distribution of melanin in the epidermis. Thus, the HA-M-INK probe is an ideal tool to individually visualize melanin (or melanosome) distribution in melanocytes and in keratinocytes in skin tissues. 相似文献
142.
Taku Matsushita Atsushi Kuze Ryosuke Kawai Mitsunori Hieda Nobuo Wada 《Journal of Low Temperature Physics》2013,171(5-6):657-663
4He and 3He films adsorbed in nanoporous silicates have shown similar heat capacities until the quantum-fluid layer appears at coverages over the first-layer completion n 1. To obtain information on dynamics of adatoms at low coverages below the quantum fluid region, we have done pulsed-NMR experiment at 3.3 MHz for 3He films adsorbed in straight 2.4 nm nanochannels of FSM silicates. The spin-lattice and spin-spin relaxation times T 1 and T 2 observed at 0.54–7 K were well described by the two-dimensional version of the Bloembergen-Purcell-Pound model. At coverages 0.4–1.7n 1, minima of T 1, indicating the spin correlation time τ c of 4.8×10?8 sec, were observed at temperatures between 6 and 3 K. With decreasing temperature, changes in T 1 and T 2 become small below about 1.5 K, suggesting crossover from thermally-activated motion to quantum tunneling. In contrast to large variations below n 1, both relaxation times above n 1 are almost independent of coverage, which is likely to indicate that τ c is determined by interlayer exchange of adatoms. Below n 1, onsets for localization of adatoms were suggested by a decrease in T 2. 相似文献
143.
Shigeyasu Kuroda Mitsunori Oda Hiroaki Takamatsu Hirofumi Hatakeyama Chisa Noda Yanmei Zhang 《Science and Technology of Advanced Materials》2013,14(4):306-317
Two types of polycyclic quinones condensed with 1,6-methano[10]annulenes as type A: 1,6-methanonaphtho[2,3-c][10]annulene-7,12-dione 5a, and type B: 1,6-methanonaphtho[2,3-c][10]annulene-5,14-dione 18, bis(1,6-methano[10]annuleno[3,4-b; 3,4-g])anthracene-10,21-dione 20, 1,6-methanoanthraceno[2,3-c][10]annulene-5,16-dione 22, 1,6-methanotetraceno[2,3-c][10]annulene-6,17-dione 23, and 1,6-methano phenanthreno[2,3-c][10]annulene-5,6-dione 24 have been synthesized. The acene derivative 6 corresponding to that of 5a was synthesized by the reduction of quinone 5a. The physical, spectral, and chemical properties of these new compounds have been investigated. 相似文献
144.
Shigeyasu Kuroda Mitsunori Oda Hirofumi Hatakeyama Yanmei Zhang Nguyen Chung Thanh Mayumi Kyougoku 《Science and Technology of Advanced Materials》2007,8(4):306-317
Two types of polycyclic quinones condensed with 1,6-methano[10]annulenes as type A: 1,6-methanonaphtho[2,3-c][10]annulene-7,12-dione 5a, and type B: 1,6-methanonaphtho[2,3-c][10]annulene-5,14-dione 18, bis(1,6-methano[10]annuleno[3,4-b; 3,4-g])anthracene-10,21-dione 20, 1,6-methanoanthraceno[2,3-c][10]annulene-5,16-dione 22, 1,6-methanotetraceno[2,3-c][10]annulene-6,17-dione 23, and 1,6-methano phenanthreno[2,3-c][10]annulene-5,6-dione 24 have been synthesized. The acene derivative 6 corresponding to that of 5a was synthesized by the reduction of quinone 5a. The physical, spectral, and chemical properties of these new compounds have been investigated. 相似文献
145.
Yohei Kono Yoshihiko Susuki Mitsunori Hayashida Igor Mezić Takashi Hikihara 《Journal of Building Performance Simulation》2018,11(2):145-163
This paper develops a method for modelling of in-room temperature distribution incorporated with data collected by human sensors. This modelling is based on a standard two-dimensional heat diffusion equation with an effective diffusion coefficient. The effective diffusion coefficient is nominally identified from characteristics of air flow inside a room and its architectural design. For modelling multiple time-scale influence of human occupancy on the in-room temperature distribution, two independent parameters—the effective diffusion coefficient and human heat input—of the equation are modulated with the human sensor data that capture spatio-temporal dynamics of the occupancy in high resolution. The developed method is applied to a practical office space in commercial building in Japan so that its effectiveness is demonstrated by comparing numerical simulations of the equation with measured data on temperature. 相似文献
146.
Kenjiro Fukuda Tomohito Sekine Yu Kobayashi Daisuke Kumaki Mitsunori Itoh Minami Nagaoka Takami Toda Sayaka Saito Masato Kurihara Masatomi Sakamoto Shizuo Tokito 《Organic Electronics》2012,13(9):1660-1664
We have fabricated electronically stable organic thin-film transistor (TFT) devices that are fully solution-processed and adopt printed electrodes using silver nanoparticles dispersed in organic solvents, whose sintering temperatures are 100 °C or less. The bottom-contact organic TFT devices showed good electrical characteristics, and exhibited threshold voltage shifts less than 2.0 V after applying a DC bias voltage stress for 104 s, which is attributed to relatively low contact resistance. These results demonstrate the feasibility of producing stable organic TFTs that are fully solution-processed at relatively low temperatures, for use in large-area flexible electronics applications. 相似文献
147.
148.
Hom Nath Luitel Takanori Watari Rumi Chand Toshio Torikai Mitsunori Yada Hiroshi Mizukami 《Materials Science and Engineering: B》2013,178(12):834-842
Color point tuning is an important challenge for improving the practical applications of various displays, especially there are very limited white color single hosts that emits in the white spectrum. In this paper, the possibility of color tuning by substituting part of host lattice cation (Sr2+ ions) by Ca2+ or Ba2+ ions in an efficient strontium aluminate phosphor, Sr4Al14O25:Eu2+,Dy3+, is reported and found to be very promising for displays. A detail study by replacing part of Sr2+ with Ca2+ or Ba2+ has been investigated. X-ray diffraction study showed that crystal structure of Sr4Al14O25 is preserved up to 20 mol of Ca2+ ion exchange while it is limited to 10 mol of Ba2+ ions exchange. Substantial shift in the emission band and color were observed by substitution of Sr2+ by Ca2+ or Ba2+ ions. A bluish-white emission and afterglow was observed at higher Ca2+ ions substitution. Further, partial Ca2+ substitutions (up to 0.8 mol) resulted in enhanced afterglow of Sr4Al14O25:Eu2+,Dy3+ phosphor. However, Ba2+ substitution decreased the fluorescence as well afterglow of the Sr4Al14O25:Eu2+,Dy3+ phosphor significantly. The enhanced phosphorescence by partial Ca2+ substitution is explained on the basis of increased density of shallow traps associated with higher solubility of Dy3+ ions in to the host lattice due to equivalent size of Ca2+ and Dy3+ ions. Thus, Ca2+ substitution in the Sr4Al14O25:Eu2+,Dy3+ phosphor is a promising method for tuning the emission color and improving the afterglow intensity of the phosphor. 相似文献