Rapid multi-component phase-split calculations using volume functions and reduction methods

We present a new family of fast and robust methods for the calculation of the vapor–liquid equilibrium at isobaric-isothermal (PT-flash), isochoric-isothermal (VT-flash), isenthalpic-isobaric (HP-flash), and isoenergetic-isochoric (UV-flash) conditions. The framework is provided by formulating phase-equilibrium conditions for multi-component mixtures in an effectively reduced space based on the molar specific value of the recently introduced volume function derived from the Helmholtz free energy. The proposed algorithmic implementation can fully exploit the optimum quadratic convergence of a Newton method with the analytical Jacobian matrix. This article provides all required exact analytic expressions for the general cubic equation of state. Computational results demonstrate the effectivity and efficiency of the new methods. Compared to conventional methods, the proposed reduced-space iteration leads to a considerable speed-up as well as to improved robustness and better convergence behavior near the spinodal and coexistence curves of multi-component mixtures, where the preconditioning by the reduction method is most effective.     

Highly porous Zr-MCM-48 immobilized Cu-porphyrin for photocatalytic reduction of CO2 to methanol in a slurry reactor

Journal of Materials Science: Materials in Electronics - This study involves the development of novel mesoporous Zr-MCM-48 photocatalyst impregnated with Cu-porphyrin (CuTPP) having Si/Zr ratio of...     

Development of a voltammetric sensor based on a molecularly imprinted polymer (MIP) for caffeine measurement

A new voltammetric sensor for caffeine measurement is introduced. A caffeine-selective molecularly imprinted polymer (MIP) and a non-imprinted polymer (NIP) were synthesized and then used for carbon paste (CP) electrode preparation. The MIP, embedded in the carbon paste electrode, functioned as a selective recognition element and a pre-concentrator agent for caffeine determination. The prepared electrode was used for caffeine measurement via a three-step procedure including analyte extraction in the electrode, electrode washing and electrochemical measurement of caffeine. The MIP-CP electrode showed very high recognition ability in comparison to NIP-CP. It was shown that electrode washing after caffeine extraction led to enhanced selectivity. Differential pulse voltammetry for caffeine determination was more effective than square wave voltammetry. Some parameters affecting sensor response were optimized, and a calibration curve was then plotted. A linear range of 6 × 10⁻⁸ to 2.5 × 10⁻⁵ mol L⁻¹ was obtained. The detection limit of the sensor was calculated to be equal to 1.5 × 10⁻⁸ mol L⁻¹. This sensor was used successfully for caffeine determination in spiked beverage and tea samples.     

Removal of Parabens from Aqueous Solution Using β-Cyclodextrin Cross-Linked Polymer

The removal of four parabens, methyl-, ethyl-, propyl-, and benzyl-paraben, by β-cyclodextrin (β-CD) polymer from aqueous solution was studied. Different β-CD polymers were prepared by using two cross-linkers, i.e., hexamethylene diisocyanate (HMDI) and toluene-2,6-diisocyanate (TDI), with various molar ratios of cross-linker. β-CD-HMDI polymer with molar ratio of 1:7 and β-CD-TDI polymer with ratio 1:4 gave the highest adsorption of parabens among the β-CD-HMDI and β-CD-TDI series, and were subsequently used for further studies. The adsorption capacity of β-CD-HMDI is 0.0305, 0.0376, 0.1854 and 0.3026 mmol/g for methyl-, ethyl-, propyl-, and benzyl-paraben, respectively. β-CD-TDI have higher adsorption capacities compared with β-CD-HMDI, the adsorption capacity are 0.1019, 0.1286, 0.2551, and 0.3699 mmol/g methyl-, ethyl-, propyl-, and benzyl-paraben respectively. The parameters studied were adsorption capacity, water retention, and reusability. Role of both cross-linker in adsorption, hydrophobicity of polymers, and adsorption capacity of different parabens were compared and discussed. All experiments were conducted in batch adsorption technique. These polymers were applied to real samples and showed positive results.     

A review on solar cold production through absorption technology

Recently, the traditional energy types have failed to satisfy the human needs because of their limited quantity as well as their negative environmental impacts. Conventional cold producing machines that are based on vapor compression principle are primary electricity consumers and their working fluids are being banned by international legislation. From this perspective, solar powered cooling systems as a green cold production technology are the best alternative. Absorption refrigeration is a mature technology that has proved its applicability with the possibility to be driven by low grade solar and waste heat. In this study, we present a comprehensive literature review on absorption based refrigeration and air conditioning systems that are powered by solar energy. Various systems along with their thermodynamic operating principle are presented. Moreover, the previous experimental and numerical simulation studies for these systems are discussed.     

The low velocity impact response of foam-based sandwich panels

This paper describes the results of a combined experimental/numerical study to investigate the perforation resistance of sandwich structures. The impact response of plain foam samples and their associated sandwich panels was characterised by determining the energy required to perforate the panels. The dynamic response of the panels was predicted using the finite element analysis package ABAQUS/Explicit. The experimental arrangement, as well as the FE model were also used to investigate, for the first time, the effect of oblique loading on sandwich structures and also to study the impact response of sandwich panels on an aqueous support.     

Mechanical and durability properties of ternary concretes containing silica fume and low reactivity blast furnace slag

In this study, the effect of incorporation of silica fume in enhancing strength development rate and durability characteristics of binary concretes containing a low reactivity slag has been investigated. Binary concretes studied included mixes containing slag at cement replacement levels of 15%, 30% and 50% and mixes containing silica fume at cement replacement levels of 2.5%, 5%, 7.5% and 10%. Ternary concretes included combinations of silica fume and slag at various cement replacement levels. The w/b ratio and total cementitious materials content were kept constant for all mixes at 0.38 and 420 kg/m³ respectively. Concrete mixes were evaluated for compressive strength, electrical resistance, chloride permeability (ASTM C1202 RCPT test) and chloride migration (AASHTO TP64 RCMT test), at various ages up to 180 days.The results show that simultaneous use of silica fume has only a moderate effect in improving the slow rate of strength gain of binary mixes containing low reactivity slag. However it improves their durability considerably. Using appropriate combination of low reactivity slag and silica fume, it is possible to obtain ternary mixes with 28 day strength comparable to the control mix and improve durability particularly in the long term. Ternary mixes also have the added advantage of reduced water demand.     

Acoustic Emission Methodology to Evaluate the Fracture Toughness in Heat Treated AISI D2 Tool Steel

In this article, fracture toughness behavior of tool steel was investigated using Acoustic Emission (AE) monitoring. Fracture toughness (K _IC) values of a specific tool steel was determined by applying various approaches based on conventional AE parameters, such as Acoustic Emission Cumulative Count (AECC), Acoustic Emission Energy Rate (AEER), and the combination of mechanical characteristics and AE information called sentry function. The critical fracture toughness values during crack propagation were achieved by means of relationship between the integral of the sentry function and cumulative fracture toughness (KICUM). Specimens were selected from AISI D2 cold-work tool steel and were heat treated at four different tempering conditions (300, 450, 525, and 575?°C). The results achieved through AE approaches were then compared with a methodology proposed by compact specimen testing according to ASTM standard E399. It was concluded that AE information was an efficient method to investigate fracture characteristics.     

Realization of high capacity transmission in fiber optic communication systems using Absolute Polar Duty Cycle Division Multiplexing (AP-DCDM) technique

An electrical multiplexing technique, namely Absolute Polar Duty Cycle Division Multiplexing (AP-DCDM) is reported for high-speed optical fiber communication systems. It is demonstrated that 40 Gb/s (4 × 10 Gb/s) AP-DCDM system shows a clear advantage over conventional 40 Gb/s RZ-OOK with 50% duty cycle in terms of dispersion tolerance and spectral efficiency. At 40 Gb/s its tolerance to chromatic dispersion (CD) is 124 ps/nm and 194 ps/nm for the worst and the best user, respectively. These values are higher than that of 40 Gb/s RZ-OOK, which is around 100 ps/nm. The spectral efficiency, receiver sensitivity and OSNR for different number of channels are discussed. Comparison against other modulation formats namely duobinary, Non-Return-to-Zero (NRZ)-OOK and RZ-Differential Quadrature Phase-Shift Keying (RZ-DQPSK) at 40 Gb/s are made. It is shown that AP-DCDM has the best receiver sensitivity (−32 dBm) and better CD tolerance (±200 ps/nm) than NRZ-OOK and RZ-DQPSK. In reference to duobinary, AP-DCDM has better receiver sensitivity but worse dispersion tolerance.     

Toward Understanding the Mechanisms of Malignant Peripheral Nerve Sheath Tumor Development

Malignant peripheral nerve sheath tumors (MPNSTs) originate from the neural crest lineage and are associated with the neurofibromatosis type I syndrome. MPNST is an unmet clinical need. In this review article, we summarize the knowledge and discuss research perspectives related to (1) the natural history of MPNST development; (2) the mouse models recapitulating the progression from precursor lesions to MPNST; (3) the role of the tumor microenvironment in MPNST development, and (4) the signaling pathways linked to MPNST development.