Conducting polymers inducing catalysis: Enhanced formic acid electro-oxidation at a Pt/polyaniline nanocatalyst

Research is moving rapidly to sustain convenient energy resources fulfilling the global climate legislations. Herein, a novel catalyst of platinum nanoparticles (PtNPs) dispersed onto polyaniline (PANi) is recommended for formic acid electro-oxidation (FAO); the fundamental anodic reaction in direct formic acid fuel cells (DFAFCs). The catalyst's preparation scheme allows a sequential electrodeposition of fibril PANi and spherical PtNPs (ca. 65 nm in size) on a glassy carbon (GC) substrate and permits a precise control over the deposition sequence and loading. Interestingly, incorporation of PANi into the catalyst's ingredients can significantly (ca. 16 times) improve the catalytic activity of the catalyst towards FAO by shifting the mechanism towards the desirable dehydrogenation pathway and mitigating the undesirable poisoning dehydration pathway. The catalytic efficiency is tuned by manipulating the deposition order and loading of different catalyst's ingredients. Several techniques are employed to confirm the successful deposition of the catalyst and to evaluate its morphology, composition and crystal structure. While PtNPs are essential for FA adsorption, PANi improves the dispersion of PtNPs and mediates FAO to facilitate the charge transfer and mitigate CO poisoning. A promising catalytic stability is achieved in a long continuous (150 CVs) electrolysis experiment.     

Oxy‐fuel combustion technology: current status,applications, and trends

The increased level of emissions of carbon dioxide into the atmosphere due to burning of fossil fuels represents one of the main barriers toward the reduction of greenhouse gases and the control of global warming. In the last decades, the use of renewable and clean sources of energies such as solar and wind energies has been increased extensively. However, due to the tremendously increasing world energy demand, fossil fuels would continue in use for decades which necessitates the integration of carbon capture technologies (CCTs) in power plants. These technologies include oxycombustion, pre‐combustion, and post‐combustion carbon capture. Oxycombustion technology is one of the most promising carbon capture technologies as it can be applied with slight modifications to existing power plants or to new power plants. In this technology, fuel is burned using an oxidizer mixture of pure oxygen plus recycled exhaust gases (consists mainly of CO₂). The oxycombustion process results in highly CO₂‐concentrated exhaust gases, which facilitates the capture process of CO₂ after H₂O condensation. The captured CO₂ can be used for industrial applications or can be sequestrated. The current work reviews the current status of oxycombustion technology and its applications in existing conventional combustion systems (including gas turbines and boilers) and novel oxygen transport reactors (OTRs). The review starts with an introduction to the available CCTs with emphasis on their different applications and limitations of use, followed by a review on oxycombustion applications in different combustion systems utilizing gaseous, liquid, and coal fuels. The current status and technology readiness level of oxycombustion technology is discussed. The novel application of oxycombustion technology in OTRs is analyzed in some details. The analyses of OTRs include oxygen permeation technique, fabrication of oxygen transport membranes (OTMs), calculation of oxygen permeation flux, and coupling between oxygen separation and oxycombustion of fuel within the same unit called OTR. The oxycombustion process inside OTR is analyzed considering coal and gaseous fuels. The future trends of oxycombustion technology are itemized and discussed in details in the present study including: (i) ITMs for syngas production; (ii) combustion utilizing liquid fuels in OTRs; (iii) oxy‐combustion integrated power plants and (iv) third generation technologies for CO₂ capture. Techno‐economic analysis of oxycombustion integrated systems is also discussed trying to assess the future prospects of this technology. Copyright © 2017 John Wiley & Sons, Ltd.     

Effect of Power Amplifier Nonlinearity on the Physical Layer Security of MIMO Systems

Wireless Personal Communications - This paper presents an analytical investigation on the effect of nonlinear high-power amplifiers on the physical layer security of multiple-input-multiple-output...     

Design of a new efficient and secure multi-secret images sharing scheme

We propose a new (n,n) multi-secret images sharing scheme that provides high level of provable security with fast sharing and reconstruction procedures. It uses simple Boolean operations conjointly with a secure stream cipher and a cryptographic hash function in order to enable an efficient sharing of n secret images among a set of n different participants. This approach overcomes the security weakness detected in existing similar schemes, and provides additional advantages such as high sensitivity to alterations and ability to share heterogeneous images having diverse resolutions. Obtained experimental results show the effectiveness and robustness of the method compared to existing schemes, particularly its ability to ensure higher security level with competitive computational performances.     

Real-time wrist localization in color images based on corner analysis

Hand detection and gestures recognition have become very popular in recent human-computer interaction systems. Although several methods of hand detection have been proposed in the literature, they exist few methods that use the wrist as a factor of detection, others impose constraints on the length of the sleeves and on the orientation of the hand. In this work, we present a new two-stage algorithm of wrist localization designed for hand detection and gestures recognition systems. The first stage of the algorithm consists in separating the skin region containing the hand from the background, and in the second stage, the wrist is localized from the resulted skin mask. The main contribution of the proposed method is based on the analysis of corners along the contour of the skin masks to localize the wrist emplacement. Based on an evaluation on 437 color images with their ground-truth and three sets of skin masks, we compared our method with other efficient methods of literature and the results obtained were very satisfactory.     

Low rate error modeling of articulated heavy vehicle dynamics and experimental validation

International Journal of Control, Automation and Systems - In the automotive domain, adequate control and diagnosis rely on the use of state observers and parametric identification systems to...     

Electrochemical degradation of petroleum hydrocarbons (PAHS) from synthetic aqueous solutions

Water separated from crude oil and wastewater discharge from petroleum oil refineries contains significant quantity of dissolved hydrocarbons. Polycyclic aromatic hydrocarbons (PAHs) are major toxicants in wastewater of refineries. It is difficult to treat wastewater containing PAHs due to their recalcitrant property and low solubility. Conventional techniques for the treatment of wastewater are still a concern of toxicity. Electrochemical oxidation process has been found to be a favorable for treating wastewater. Electrodes with high stability and electrocatalytic activity are important factors for a successful electrochemical oxidation of toxic organics in wastewater. In this study titanium anodes were coated with tin, antimony and iridium oxide mixture from their respective salts by thermal decomposition method. FESEM and XRD used for surface characterization of Ti/SnO₂–Sb₂O₅–IrO₂ anode. Quantification of PAHs was done using GC–MS. Results confirm the presence of respective oxides on anode surface. Their electrocatalytic capability was tested for degradation of 16 priority PAHs in aqueous solution. Results reveal the complete degradation of naphthalene, acenaphthylene, acenaphthene and fluorene without using NaCl electrolyte. While in the presence of NaCl naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene and pyrene were completely removed. About 98% of total PAHs removal was found at all initial pH values 3, 6, and 9 in the presence of electrolyte. Current study will be helpful in improving quality of petroleum industry wastewater containing PAHs.     

On business process monitoring using cross-flow coordination

This paper presents an approach for monitoring the execution progress of business processes. The monitoring focuses on the exceptions that could arise during this execution and, hence, could make the processes fail if not handled properly and timely. The approach relies on three flows known as control, communication, and navigation. The control flow connects tasks together with respect to a certain business logic. The communication flow captures the messages exchanged between persons/machines when they perform tasks of processes. Finally, the navigation flow captures the interactions between specialized networks that offer solutions to exceptions. These networks are built upon relations between tasks, between persons, and between machines. The coordination of control, communication, and navigation flows focuses on both the actions that are taken and the messages that are exchanged when handling exceptions. A system demonstrating flow development and coordination is, also, presented in the paper.