SOLUBILITY AND DIFFUSIVITY OF GASES IN AN ORGANIC SOLUTION OF AMINE

Solubilities and diffusivities of carbon dioxide and nitrous oxide in a mixture of toluene and isopropanol organic solution of cyclohexylamine were measured at 20°C in the range of pressures of solute from 1 to 3 bars. This was performed with an original chromatographic technique taking into account the presence of the product of the reaction.     

Arylidene polymers. XVIII. Synthesis and thermal behavior of organometallic arylidene polyesters containing ferrocene derivatives in the main chain

A new interesting category of organometallic polyesters based on diarylidenecycloalkanones containing ferrocene derivatives in the polymer main chain has been prepared by interfacial polycondensation of 1,1′-dichlorocarbonyl ferrocene or 1,1′-dichlorocarbonyl-4,4′-diiodoferrocene with 2,5-bis(p-hydroxybenzylidene)cyclopentanone, 2,5-divanillylidenecyclopentanone, 2,6-bis(p-hydroxybenzylidene)cyclohexanone, 2,6-divanillylidenecyclohexanone, and 2,7-bis(p-hydroxybenzylidene) cycloheptanone. The resulting polyesters were characterized by elemental analyses, infrared spectroscopy, solubility, and viscometry measurements. The thermal behavior of the synthesized polymers was evaluated by thermal gravimetric analysis and correlated with their structures. The crystallinity of all polymers were examined by x-ray diffraction analysis. Moreover, the electrical conductivity of a selected example of polymer was investigated above the temperature range (300–500 K) and showed that it followed an Arrhenius-type equation with activation energy 2.09 eV. © 1993 John Wiley & Sons, Inc.     

Numerical and experimental investigation of three-dimensional flow in extrusion dies

The univariant element, Q₁ P₀, and the multivariant elements, QP₀ and R P₀, are compared for the numerical simulation of the flow in extrusion dies. The pressure distribution obtained by using the Q₁ P₀ element was found to be afflicted with the checkerboard pressure mode. On the other hand, the multivariant elements, Q P₀ and R P₀, gave accurate and physically reasonable velocity and pressure distributions. The computed values of the pressure drop across extrusion dies matched well with the pressure drop determined experimentally.     

Effect of various steps of purification on ash content and ash constitution of cellulose. I. Cellulose prepared from cotton linters

The effect of the various steps of purification on the ash content and ash constitution of cellulose prepared from cotton linters has been examined. After each step of purification, samples were analysed for total ash, SiO₂, Ca, Mg, Fe, Al, Cu and Mn. Two methods of bleaching were investigated. The first involves double treatment of cellulose with sodium hypochlorite solution, and the second one treatment with hypochlorite followed by another treatment with sodium chlorite solution. The second method has a better effect in diminishing the ash content.     

Hardened slag–cement pastes of various porosities. III. Surface area in relation to pore structure

The total surface areas, total pore volumes, and the distribution of pore surface and pore volume in pores of different sizes were determined on the hardened slag-cement pastes. Adsorption isotherms of four different adsorbates, namely water, methanol, nitrogen and cyclohexane, were used for surface area and pore structure determinations. The results obtained indicated that water can penetrate into the total pore system, namely both the micropores and the wide pores; whereas methanol can measure wide pores and some of the micropores; moreover, nitrogen and cyclohexane molecules tend to measure only wider groups of pores. The indication gained from this result is that the molecular sieve property plays the most significant role in surface area and pore structure determinations of the hardened cement pastes. The polarity of the molecules seems to be important at low relative vapour pressures, and at high pressures it causes expansion of the pastes.     

Extraction of metals from sulphides using sulphur trioxide in fluidised bed

The kinetics of the reaction of chalcopyrite, iron sulphide, copper sulphide, and nickel sulphide with sulphur trioxide gas were studied using a fluidised bed technique. O₂, N₂, or air was used as a carrier gas for the sulphur trioxide in fluidisation. Binary mixtures of finely ground (0.37–75 μm) samples were reacted with the sulphur trioxide in a Pyrex column at 373–673 K. The reaction products were leached with water and the soluble metals in the solution were determined by atomic absorption spectrometry. The total soluble reaction products were determined gravimetrically. The results obtained showed that a higher yield of soluble salts was obtained when O₂ or air was used as a carrier gas for sulphur trioxide than when an inert gas was used. Higher yields of soluble salts were obtained when the samples were most finely ground. Increase of copper sulphide content in binary mixtures with iron or nickel sulphide led to an increase in the yield of soluble salts. For iron sulphide/nickel sulphide mixtures, the yield of soluble salts increased with the nickel sulphide content. There were maximum values for the soluble metal ratios Ni/Fe and Cu/Ni in the corresponding sulphide binary mixtures and this maximum was at about 50% weight. The soluble Cu/Fe ratio increased with copper sulphide content in mixtures with iron sulphide.     

Photophysical Parameters of Functional Transparent Polymethyl-Methacrylate/Double-Walled Carbon Nanotubes Nanocomposite Sheet Under UV-Irradiation

Polymethyl-methacrylate (PMMA)/double-walled carbon nanotubes DWCNTs was prepared by using casting technique and studying with different spectroscopic techniques. UV/Vis spectral analysis shows that, the transmittance reaches to 92 % for blank PMMA and decreases to 87 % for PMMA doped with 0.01 DWCNTs composite. The calculated refractive index and absorption coefficient increase, while the estimated values of Urbach energy decreased after embedding CNT into PMMA matrix. The optical band gap values were observed to vary slightly with doping amount. Photoluminescence (PL) spectra show that there is no shift in the emission peak position upon doping with CNTs, but PL intensity is enhanced.     

An Eco-Friendly Ultrasound-Assisted Synthesis of Novel Fluorinated Pyridinium Salts-Based Hydrazones and Antimicrobial and Antitumor Screening

The present work reports an efficient synthesis of fluorinated pyridinium salts-based hydrazones under both conventional and eco-friendly ultrasound procedures. The synthetic approach first involves the preparation of halogenated pyridinium salts through the condensation of isonicotinic acid hydrazide (1) with p-fluorobenzaldehyde (2) followed by the nucleophilic alkylation of the resulting N-(4-fluorobenzylidene)isonicotinohydrazide (3) with a different alkyl iodide. The iodide counteranion of 5–10 was subjected to an anion exchange metathesis reaction in the presence of an excess of the appropriate metal salts to afford a new series of fluorinated pyridinium salts tethering a hydrazone linkage 11–40. Ultrasound irradiation led to higher yields in considerably less time than the conventional methods. The newly synthesized ILs were well-characterized with FT-IR, ¹H NMR, ¹³C NMR, ¹¹B, ¹⁹F, ³¹P and mass spectral analyses. The ILs were also screened for their antimicrobial and antitumor activities. Within the series, the salts tethering fluorinated counter anions 11–13, 21–23, 31–33 and 36–38 were found to be more potent against all bacterial and fungal strains at MIC 4–8 µg/mL. The in vitro antiproliferative activity was also investigated against four tumor cell lines (human ductal breast epithelial tumor T47D, human breast adenocarcinoma MCF-7, human epithelial carcinoma HeLa and human epithelial colorectal adenocarcinoma Caco-2) using the MTT assay, which revealed that promising antitumor activity was exhibited by compounds 5, 12 and 14.