Processing techniques for particulate-reinforced metal aluminium matrix composites

The critical need for high strength, lightweight and high stiffness materials has, in recent years, resurrected much interest in discontinuously reinforced powder metallurgy metal matrix composites. These hybrid materials have combined both standard wrought alloys of aluminium and a wide variety of discontinuous reinforcements such as particulates and whiskers of ceramic materials. Renewed interest in these materials as attractive candidates for use in the aerospace and transportation industry has resulted from an attractive and unique combination of physical and mechanical properties, and an ability to offer near isotropic properties coupled with the low cost of these materials when compared with existing monolithic materials. In this paper, the primary processing categories for discontinuously-reinforced metal-matrix composites are highlighted and the salient features of the various techniques in each category are discussed. The variables involved in each processing technique are examined, and the influence of alloy chemistry highlighted. Novel processing techniques for these materials such as the variable co-deposition method is presented as a means to process these novel engineering materials in order to improve their overall mechanical performance.     

Study of hot air generator with quasi-uniform temperature using concentrated solar radiation: Influence of the shape parameters

The non-uniformity of the air temperatures and the slow flow rate at the plane collector exit constitute the main cause of the limitations of the solar drying systems. In order to obtain an uniform and a variable flow rate for different uses, a hot air generator using concentrated solar radiation is proposed. To improve the thermal efficiency of the generator, a study of the influence of different shape parameters is realized. The generator is simulated in the laboratory while investigating the flow induced by a circular disc heated uniformly by Joule effect at constant temperature. This disc is placed at the entrance of an open ended vertical cylinder of a larger diameter. Thermal radiation emitted by the hot disc heats the cylinder wall. The heating of the fluid at the cylinder-inlet generates a thermosiphon flow around the one created by the hot disc. The comparison of the velocity and the temperature profiles of the resulting flow permits to determine the influence of the cylinder height, the vertical source-cylinder spacing and the radius ratio, on the resulting flow at the system exit. Thus, a judicious choice of the shape parameters entails an improvement of the flow rate as well as the thermal flux absorbed by the air and a good homogenization of the air temperature at the generator exit.     

Simultaneous sulfide and acetate oxidation under denitrifying conditions using an inverse fluidized bed reactor

BACKGROUND: Simultaneous removal of sulfur, nitrogen and carbon compounds from wastewaters is a commercially important biological process. The objective was to evaluate the influence of the CH₃COO^?/NO₃^? molar ratio on the sulfide oxidation process using an inverse fluidized bed reactor (IFBR). RESULTS: Three molar ratios of CH₃COO^?/NO₃^? (0.85, 0.72 and 0.62) with a constant S^2?/NO₃^? molar ratio of 0.13 were evaluated. At a CH₃COO^?/NO₃^? molar ratio of 0.85, the nitrate, acetate and sulfide removal efficiencies were approximately 100%. The N₂ yield (g N₂ g^?1 NO₃^?‐N consumed) was 0.81. Acetate was mineralized, resulting in a yield of 0.65 g inorganic‐C g^?1 CH₃COO^?‐C consumed. Sulfide was partially oxidized to S⁰, and 71% of the S^2? consumed was recovered as elemental sulfur by a settler installed in the IFBR. At a CH₃COO^?/NO₃^? molar ratio of 0.72, the efficiencies of nitrate, acetate and sulfide consumption were of 100%, with N₂ and inorganic‐C yields of 0.84 and 0.69, respectively. The sulfide was recovered as sulfate instead of S⁰, with a yield of 0.92 g SO₄^2?‐S g^?1 S^2? consumed. CONCLUSIONS: The CH₃COO^?/NO₃^? molar ratio was shown to be an important parameter that can be used to control the fate of sulfide oxidation to either S⁰ or sulfate. In this study, the potential of denitrification for the simultaneous removal of organic matter, sulfide and nitrate from wastewaters was demonstrated, obtaining CO₂, S⁰ and N₂ as the major end products. Copyright © 2008 Society of Chemical Industry     

Case Study-Based Challenges of Quality Concrete Finishing for Architecturally Complex Structures

This paper focuses on the procedure utilized in the construction of tilt-up irregular concrete panels that are constructed on-site using concrete slabs and wooden formwork. The case study required high-quality concrete finishing. The erection and installation procedure called for a maximum panel-to-panel joint tolerance of 1.27?cm (0.5?in.), often 90° joints between panels. To meet precision requirements, the casting slabs were leveled and flattened with laser screed technology and smoothed with chemical solutions. To ensure that the final result met expectations, a mock-up model was built using different types of materials and to simulate site constraints. The architectural design is a composition of precast concrete panels like “Lego” pieces assembled similarly to a jigsaw puzzle. The unique construction process required a state-of-the-art analysis to produce the set quality. Quality conditions as set by the owner included creating a smooth concrete surface on all panels while avoiding damages and reducing equipment and material costs. The proposed methodology is described through its implementation on the case study, which is also described in this paper.     

Preparation of glucose oxidase immobilized in different carriers using radiation polymerization

Glucose oxidase (EC 1.1.3.4) was immobilized on different polymeric materials using different immobilization techniques (entrapping by γ‐irradiation, and covalent binding using epichlorohydrin). Studies were carried out to increase the thermal stability of glucose oxidase (GOD) for different applications. The activity and stability of the resulting biopolymers have been compared with those of free GOD. The effect of different polyvinyl alcohol/polyacrylamide (PVA/PAAm) compositions of the copolymer carrier on the enzymatic activity of the immobilized GOD was studied. The maximum enzymatic activity was obtained with the composition ratio of PVA/PAAm of 60:40. The behaviour of the free and immobilized enzyme was analysed as a function of pH. A broadening in the pH profile (5.5–8) was observed for immobilized preparations. The activity and stability of the resulting biopolymers produced by immobilization of GOD onto different carriers have been compared, in both aqueous and organic media, with those of the free GOD. The enzyme's tolerance toward both heat and organic solvent was enhanced by immobilization onto polymers. The addition of different concentrations of organic solvents (10–50%, v/v) to the enzyme at higher temperature (60 °C) was found to stabilize the enzyme molecule. The strongest stabilizing effect on the enzymatic activity was achieved at a concentration of 10%. Copyright © 2005 Society of Chemical Industry     

Handwritten word recognition with character and inter-characterneural networks

An off-line handwritten word recognition system is described. Images of handwritten words are matched to lexicons of candidate strings. A word image is segmented into primitives. The best match between sequences of unions of primitives and a lexicon string is found using dynamic programming. Neural networks assign match scores between characters and segments. Two particularly unique features are that neural networks assign confidence that pairs of segments are compatible with character confidence assignments and that this confidence is integrated into the dynamic programming. Experimental results are provided on data from the U.S. Postal Service.