Zero-valent iron treatment of RDX-containing and perchlorate-containing wastewaters from an ammunition-manufacturing plant at elevated temperatures.

The use of zero-valent iron for treating wastewaters containing RDX and perchlorate from an army ammunition plant (AAP) in the USA at elevated temperatures and moderately elevated temperature with chemical addition was evaluated through batch and column experiments. RDX in the wastewater was completely removed in an iron column after 6.4 minutes. Increasing the temperature to 75 degrees C decreased the required retention time to 2.1 minutes for complete RDX removal. Perchlorate in the wastewater was completely removed by iron at an elevated temperature of 150 degrees C in batch reactors in 6 hours without pH control. Significant reduction of perchlorate by zero-valent iron was also achieved at a more moderate temperature (75 degrees C) through use of a 0.2 M acetate buffer. Based on the evaluation results, we propose two innovative processes for treating RDX-containing and perchlorate-containing wastewaters: a temperature and pressure-controlled batch iron reactor and subsequent oxidation by existing industrial wastewater treatment plant; and reduction by consecutive iron columns with heating and acid addition capabilities and subsequent oxidation.     

A simplified method for modelling the effect of blinds on window thermal performance

An approximate method is presented for predicting the effect of a louvered blind on the centre‐glass thermal performance of a fenestration. The method combines a one‐dimensional heat transfer model with data from a numerical simulation of the window and blind. Sample results for a blind mounted on the indoor surface of a window show the effect of blind slat angle on heat transmission. Both summer and winter conditions are considered. The results show that a louvered blind can improve the U‐value of a standard double‐glazed window by up to 37%. Also, the radiation heat exchange with the room can be dramatically reduced (by up to 60%), which will improve the level of occupant comfort. However, there was found to be a trade‐off between U‐value and occupant comfort; placing the blind closer to the window improves the U‐value, but increases the radiation heat exchange with the room. The predictions from the present simplified method compare well with results from a full two‐dimensional computational fluid dynamics solution of the conjugate blind/window interaction. Copyright © 2005 John Wiley & Sons, Ltd.     

Matrix mediated alignment of single wall carbon nanotubes in polymer composite films

Alignment of single wall carbon nanotubes (SWNT) in liquid crystalline (LC) polymer matrix imparting orientation to the nanotubes along the nematic director was studied by atomic force microscopy, measurements of electrical conductivity and Raman spectroscopy of the composite in the directions parallel and perpendicular to the nematic director. The composites were prepared through dispersion of SWNT with LC monomer in a common solvent, their alignment in nematic monomer and consequent UV polymerization of the monomer. The anisotropy of electrical and optical properties of the system depends strongly on the concentration of the nanotubes in the range of 1-10% SWNT being especially strong for smaller concentrations and negligible at higher loads. A simple semi-quantitative model is suggested to account for the orientational behavior of nanotubes in nematic matrices. It successfully describes the observed anisotropy of physical properties at microscale (up to 200 μm) in terms of anchoring of the polymer chains to the nanotubes surface and adjustment of the nanotubes orientation to the nematic direction due to such coupling. The increasing disorientation of the nematic domains at higher nanotubes loads is explained as a development of larger number of LC defects induced by the nanotubes in the nematic matrix due to their intrinsic nature of aggregation. The anisotropy of physical properties at macro scale (several millimeters) is much smaller and less dependable on SWNT concentration because differently oriented LC domains effectively wash out the anisotropy.     

Influence of the deposition atmosphere on the characteristics of Pd–Mg thin films prepared by pulsed laser deposition

Bilayered palladium (30 nm thick)–magnesium (350 nm thick) thin films were prepared using the pulsed laser deposition technique in the presence of various background gases (Ar, He and a mixture He + H₂) under different partial pressures (47 and 27 Pa). According to the deposition atmosphere, the Pd/Mg interface shows either a sharp or an extended transition. The electrochemical hydriding properties and the mechanical stability upon cycling of the Pd/Mg film are greatly improved when an extended «intermixing» zone between the Pd and Mg layers is present. The Pd–Mg films prepared under pure helium fulfill these conditions.     

Statistical model of an undermoded reverberation chamber

Weibull distribution is adopted to model the electric field component of a Reverberation Chamber (RC). Its first property is to include the asymptotic laws, such as Rayleigh and exponential, and its main advantage lies in the fact that the Weibull shape parameter enables a model of the departure from overmoded to undermoded RC regime. Applications are given, such as an RC modal finite element modeling and a Monte Carlo simulation: they prove that the Weibull two-parameter distribution correctly models the quality factor influence. Moreover, the relevance of the use of this extreme value distribution is illustrated.     

Nonequilibrium nonstoichiometry in ionic compounds

Ionic substances under normal conditions are stoichiometric compounds with phase diagrams featuring no homogeneity regions. Crystals grown under nonequilibrium conditions, in particular, under significant centrifugal acceleration, are characterized by nonstoichiometric compositions (e.g., K_2−x Br_1.07). In this way, it is possible to obtain nonequilibrium nonstoichiometric ionic compounds possessing certain homogeneity regions. Nonstoichiometric crystals of KCl, KBr, and KI grown under various accelerations ranging within (1.3–100.0)×10³ g exhibit insignificant variations in the lattice constants and a significant increase in micro-hardness with acceleration.     

Fractal vortex structure in a superconductor lattice model

The vortex structure is considered within the framework of a superconductor lattice model with a kinetic term of the Harper type. The problem is reduced to the analysis of discrete maps typical of the theory of fractal structures.     

Development of an end-point detector for parylene deposition process

Parylene is an emerging material for MEMS. It is an organic material that is grown by using the chemical vapor deposition method at room temperature. The deposition thickness is commonly controlled by the amount of solid-phase dimer loaded in a sublimation chamber. In a conventional deposition machine, the end point of the process is designated by the moment the dimer is exhausted. However, this end-of-process criterion does not offer precise, repeatable control of film thickness. We present the results of the development of an in situ end-point detector for a Parylene chemical vapor deposition process. The detector is based on the thermal transfer principle and can be implemented on commercial parylene deposition systems with minimal system modification. Such a sensor enables a user to stop the deposition when a targeted thickness is reached. The end point detector is very simple to implement on existing parylene deposition systems. A series of such sensors with different target deposition thickness would allow extraction of the actual deposition rate within a deposition run.