Effect of thermal insulation using leather and carpentry wastes on thermal comfort and energy consumption in a residential building

In this work, we investigate the effect of the thermal insulation by leather wastes (wet-blue chrome shavings and buffing dust) and carpentry wastes (wood shavings and sawdust) on the energy consumption of a model building using the average climatic data of the city of Casablanca (Morocco). For this study, we used the dynamic thermal simulation tool “TRNSYS 16” which predicts the thermal behavior of building and systems associated with it. Using this software, we evaluated the effect of the above material wastes on thermal comfort and building energy consumption. The type and the thickness of the materials were considered as variants to choose the better solution. The average temperatures of building supposed thermally insulated compared to those obtained without insulation clearly show the thermal insulation ability of tested materials during the cold and warm periods of the year. Increasing the thickness of the insulator makes locals increasingly comfortable. Because of their performance, leather and carpentry wastes can compete with conventional insulating materials such as polystyrene and cork.     

A newly synthesized single crystal zinc complex as molecular electrocatalyst for efficient hydrogen generation from neutral aqueous solutions

A new chlorobis(2-aminomethylbenzimidazole)zinc(II) perchlorate complex [Zn(AMB)₂Cl](ClO₄) 1 has been synthesized and characterized. Spectral and X-ray structural features led to the conclusion that the zinc(II) complex has a square-pyramidal environment around zinc(II) center with coordination chromophore ZnN₄Cl. Different amounts of complex 1 were supported on glassy carbon (GC) electrode yielding three GC-supported complex 1 electrodes with different loading densities (0.2, 0.4, and 0.8 mg cm^?2). These electrodes were tested as molecular electrocatalysts for the hydrogen evolution reaction (HER) in phosphate buffer aqueous solutions (pH 7), employing linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). Results showed that GC-complex 1 catalysts are highly active for the HER, and this catalytic activity enhances with the loading density. The one with the highest loading density (0.8 mg cm^?2) exhibited high HER catalytic activity with low onset potential of ?140 mV vs. RHE and a high exchange current density of 0.22 mA cm^?2. It required an overpotential of 240 mV to achieve a current density of 10 mA cm^?2. It also recorded a turnover frequency (TOF) of 1722 mol of hydrogen per mole of catalyst per hour at overpotential 500 mV, which is comparable with the most active molecular electrocatalysts reported in the literature for H₂ generation from aqueous neutral solutions. A catalytic cycle is proposed for the generation of hydrogen by complex 1 and the mechanism of the HER is discussed based on the measured Tafel slope (140 mV dec^?1).     

Synthesis of cadmium sulfide‐reduced graphene oxide nanocomposites by pulsed laser ablation in liquid for the enhanced photocatalytic reactions in the visible light

The large‐scale applications of cadmium sulfide (CdS) nanoparticles (NPs) as a photo‐catalyst are limited by their poor stability (high aggregation tendency) and consequent reduction in the surface area and increased rate of recombination of photoinduced electron‐hole pairs, despite its inherent positive feature of being visible light active. It has been reported that the photocatalytic performance of CdS can be considerably improved if CdS is made as a composite material with reduced graphene oxide (rGO) in an optimum ratio. In this work, for the first time, we adopted the technique of pulsed laser ablation in liquids (PLAL) to synthesize highly pure CdS NPs and the required CdS/rGO nanocomposites using high purity (99.9%) microstructured CdS and graphene oxide as chemical precursors. PLAL is a simple and rapid 1‐step synthesis process (where the reaction time is reduced from several hours to a few minutes), which does not require high temperature, toxic chemicals, and the final treatment to remove the unwanted by‐products. The optical and morphological characterizations revealed that the anchoring of CdS on rGO transformed the CdS/rGO composite into an efficient photo‐catalyst by enhancing the following positive attributes required for a good photo‐catalyst: (1) The inherent tendency of aggregation of CdS is considerably reduced; CdS NPs with an average grain size of 20 nm are well placed on the rGO sheets; and hence, the surface area of the catalyst was significantly increased to provide more active sites. (2) The reduced rate of photoinduced electron‐hole recombination manifested in the photoluminescence spectrum indicated the effective charge separation. (3) The enhanced light absorption in the visible/infrared region ensured the effectiveness of this material in naturally abundant solar radiation. In the CdS/rGO composite, the rGO sheets play the role of a supporting matrix, cocatalyst, and electron acceptor for CdS. To evaluate the photo‐catalytic performance of CdS/rGO, we applied it as a visible light‐driven photo‐catalyst for degrading methylene blue dye and found that CdS/rGO nanocomposite was more efficient than pure CdS in the visible spectral region. Therefore, PLAL provides a simple and 1‐step route to synthesize high‐purity visible light–driven photo‐catalysts and solar cell material.     

Flow and heat transfer in a porous medium saturated with a Sisko nanofluid over a nonlinearly stretching sheet with heat generation/absorption

This work is focused on steady flow and heat transfer in a porous medium saturated with a Sisko nanofluid (non‐Newtonian power‐law) over a nonlinearly stretching sheet in the presence of heat generation/absorption. Nonlinear PDEs are transformed into a system of coupled nonlinear ODEs with related boundary conditions using similarity transformation. The reduced equations are then solved numerically using the Runge–Kutta–Fehlberg fourth–fifth order method (RKF45) with Maple 14.0 software. The solutions depend on the power‐law index n and the effect of pertinent parameter such as the Brownian motion parameter, thermophoresis parameter, Lewis number, the permeability, and the heat generation/absorption on the dimensionless velocity, temperature, and nanoparticles volume fraction and also on the skin friction, local Nusselt, and Sherwood numbers are produced for values of the influence parameter. A rapprochement of the numerical results of the actual study with formerly published data detected an excellent agreement.     

Novel chaos game optimization tuned-fractional-order PID fractional-order PI controller for load–frequency control of interconnected power systems

In this work, chaos game optimization (CGO), a robust optimization approach, is employed for efficient design of a novel cascade controller for four test systems with interconnected power systems (IPSs) to tackle load–frequency control (LFC) difficulties. The CGO method is based on chaos theory principles, in which the structure of fractals is seen via the chaotic game principle and the fractals’ self-similarity characteristics are considered. CGO is applied in LFC studies as a novel application, which reveals further research gaps to be filled. For practical implementation, it is also highly desirable to keep the controller structure simple. Accordingly, in this paper, a CGO-based controller of fractional-order (FO) proportional–integral–derivative–FO proportional–integral (FOPID–FOPI) controller is proposed, and the integral time multiplied absolute error performance function is used. Initially, the proposed CGO-based FOPID–FOPI controller is tested with and without the nonlinearity of the governor dead band for a two-area two-source model of a non-reheat unit. This is a common test system in the literature. A two-area multi-unit system with reheater–hydro–gas in both areas is implemented. To further generalize the advantages of the proposed scheme, a model of a three-area hydrothermal IPS including generation rate constraint nonlinearity is employed. For each test system, comparisons with relevant existing studies are performed. These demonstrate the superiority of the proposed scheme in reducing settling time, and frequency and tie-line power deviations.     

Two-dimensional problem for thermoviscoelastic materials with fractional order heat transfer

Abstract

The model of equations of thermo-viscoelasticity with fractional order heat transfer is constructed. Some fundamental theorems on the linear coupled and generalized theories of thermo-viscoelasticity can be easily obtained as special cases. The medium is assumed initially quiescent. Laplace and Fourier integral transforms are utilized. The method of the matrix exponential which constitutes the basis of the state–space approach of modern control theory is applied to the system of two-dimensional equations. The resulting formulation is applied to a thermal shock half-space problem. The inversion process for Fourier and Laplace transforms is carried out using numerical method based on Fourier series expansions. Numerical results are given and illustrated graphically for the problem considered. Comparisons are made with the results predicted by the coupled theory and generalized theory. The effect of the fractional order parameter on all the considered fields is examined.     

Enhancing the Performance of a Parallel Solver for Turbulent Reacting Flow Simulations

This article describes results of an effort to improve the parallel efficiency of a solver for turbulent reacting flows on two computer architectures. The compact finite-difference scheme employed for the solution of the differential equations involves the inversion of multiple tridiagonal matrices at each time step. Detailed performance evaluation of the standard LU, parallel partition LU, and parallel diagonal dominant algorithms are presented. The speed-up and efficiencies of these parallel strategies are critically compared and evaluated based on both computation and communication complexities, on the CRAY XT4 and IBM Blue Gene/P architectures.     

Photovoltaic technology in Malaysia: past,present, and future plan

This article presents solar energy or specifically the solar photovoltaic (PV) development outlook in Malaysia. The paper first introduces the massive potential of solar energy in the country, the key players in the solar energy development and the early solar energy policies, and programmes in the country. The most important to the PV development is the Malaysia Building Integrated Photovoltaic initiative, which is presented in this paper followed by an explanation on the Feed-in Tariff recently introduced in the country to encourage new solar PV projects. The outlook for solar PV in Malaysia is optimistic and as the uptake of solar PV increases, the unit cost is coming down rapidly. Solar PV is expected to be the most competitive Renewable Energy (RE) source, with the potential to achieve grid parity for electrical power in the country in the near future, and surpassing all other REs combined by 2050.     

Modeling of ion transport reactor for oxy‐fuel combustion

This paper aims at investigating the performance of a cylindrical ion transport reactor designed for oxy‐fuel combustion. The cylindrical reactor walls are made of dense, nonporous, mixed‐conducting ceramic membranes that only allow oxygen permeation from the outside air into the combustion chamber. The sweep gas (CO₂ and CH₄) enters the reactor from one side and mixes with the oxygen permeate, and the products are discharged from the other side. The process of oxygen permeation through the reactor walls is influenced by the flow condition and composition of air at the feed side (inlet air side) and the gas mixture at the permeate side (sweep gas side). The modeling of the flow process is based on the numerical solution of the conservation equations of mass, momentum, energy, and species in the axisymmetric flow domain. The membrane is modeled as a selective layer in which the oxygen permeation depends on the prevailing temperatures as well as the oxygen partial pressure at both sides of the membrane. The CFD calculations were carried out using fluent 12.1 (ANSYS, Inc., Canonsburg, PA, USA), whereas the mass transfer of oxygen through the membrane is modeled by a set of user defined functions. The model results were validated against previous experimental data, and the comparison showed a good agreement. The study focused on the effect of oxygen partial pressure and temperature on the resulting combustion zones inside the reactor for the two cases of co‐current and counter‐current flow regimes. The results indicated that the oxygen to fuel mass ratio increases as the percentage of CO₂ increases in the inflow sweep gas for both co‐current and counter‐current flows. The obtained sweep mixture ratio (CO₂/CH₄) of 24 is found within the stoichiometric limit over most of the reactor length in the co‐current configuration, whereas the sweep mixture ratio of 15.67 is found in the counter‐current configuration owing to the high O₂ permeation. Copyright © 2012 John Wiley & Sons, Ltd.     

Effects of Acidity and Method of Preparation on Nucleate Pool Boiling of Nanofluids

Past research has shown contradicting trends in the rate of heat transfer during pool boiling of nanofluids, which could be attributed either to their stability or to their method of preparation or to both. An experimental study has been conducted to investigate the effects of electrostatic stabilization and preparation method of nanofluids on their pool boiling rate of heat transfer. Nanofluids made from water and alumina nanoparticles at 0.1 vol% concentration were used. The effect of electrostatic stabilization was investigated by changing the pH value from 6.5, neutral, to 5, acidic. The effect of preparation method has been investigated by using nanofluids prepared from dry particles and from ready-made suspensions. Compared with water, all nanofluids investigated resulted in deterioration in the rate of heat transfer during pool boiling. Neutral nanofluids made from ready-made suspensions and from dry particles resulted into almost the same deterioration in the rate of heat transfer of 49% and 45%, respectively, with respect to that of pure water. The most significant effect of electrostatic stabilization was found in the case of acidic nanofluids made from dry particles, which resulted in deterioration in the rate of heat transfer of 31%. However, acidic nanofluids made from ready-made suspensions resulted in a deterioration of 46%, which is almost the same as that of suspension-made and dry particles-made nanofluids. These results indicate that electrostatic stabilization using acid addition is most effective with nanofluids made from dry particles.