A Strategy to Produce High Efficiency,High Stability Perovskite Solar Cells Using Functionalized Ionic Liquid‐Dopants

Functionalized imidazolium iodide salts (ionic liquids) modified with ? CH₂? CH?CH₂, ? CH₂C?CH, or ? CH₂C?N groups are applied as dopants in the synthesis of CH₃NH₃PbI₃‐type perovskites together with a fumigation step. Notably, a solar cell device prepared from the perovskite film doped with the salt containing the ? CH₂? CH?CH₂ side‐chain has a power conversion efficiency of 19.21%, which is the highest efficiency reported for perovskite solar cells involving a fumigation step. However, doping with the imidazolium salts with the ? CH₂C?CH and ? CH₂C?N groups result in perovskite layers that lead to solar cell devices with similar or lower power conversion efficiencies than the dopant‐free cell.     

Conductivity and anticorrosion performance of polyaniline/zinc composites: Investigation of zinc particle size and distribution effect

Polyaniline/zinc composites and nanocomposites were prepared using solution mixing method. Zinc (Zn) particles with an average particle size of 60 μm and zinc nanoparticles with an average particle size of 35 nm were used as fillers in polyaniline (PANI) matrix. Films and coatings of PANI/Zn composites and nanocomposites were prepared by the solution casting method. Electrical conductivity and anticorrosion properties of PANI/Zn composite and nanocomposite films and coatings with different zinc loadings were evaluated. According to the results, electrical conductivity and anticorrosion performances of both PANI/Zn composites and nanocomposites were increased by increasing the zinc loading. Also results showed that the PANI/Zn nanocomposite films and coatings have better electrical conductivity and corrosion protection effect on iron coupons compared to that of PANI/Zn composite.     

ARO: A new model free optimization algorithm for real time applications inspired by the asexual reproduction

This paper presents a new individual based optimization algorithm, which is inspired from asexual reproduction known as a remarkable biological phenomenon, called as asexual reproduction optimization (ARO). ARO can be essentially considered as an evolutionary based algorithm that mathematically models the budding mechanism of asexual reproduction. In ARO, a parent produces a bud through a reproduction operator; thereafter the parent and its bud compete to survive according to a performance index obtained from the underlying objective function of the optimization problem; this leads to the fitter individual. ARO adaptive search ability along with its strength and weakness points are fully described in the paper. Furthermore, the ARO convergence to the global optimum is mathematically analyzed. To approve the effectiveness of the ARO performance, it is tested with several benchmark functions frequently used in the area of optimization. Finally, the ARO performance is statistically compared with that of an improved genetic algorithm (GA). Results of simulation illustrate that ARO remarkably outperforms GA.     

An investigation of the effect of changes of planning criteria on power system expansion planning with a case study of the Jordanian power system

Many factors contribute to the planning process of power systems. In the context of expansion planning, focus is paid to selection criteria that enable the optimization of related factors that will result in the best performance. This is described as meeting demand whilst reducing costs and maintaining minimal risk in operation. In this paper, different criteria used in the planning of power system expansion studies are investigated with the objective of identifying their impact on the expansion plan. The results of these criteria on the expansion study of the Jordanian power system are presented. Results show good correspondence to the actual adopted solutions. The spinning reserve is the most influential planning criterion on the overall system expansion cost. This is followed by the peak load changes, and the forced outage rate of the candidate units used for capacity additions to meet future expected demand. Finally, the loss of load expectation and cost of energy not served have the least effect on the overall system expansion cost. These results highlight the importance to be placed on performing sensitivity analyses to determine the most cost effective and acceptable expansion plan of the electric power system. There is a need to continually update the planning criteria to cater for changes and developments in the power system and the economic situation. Finally, the methodology of this study can be generalized to other power systems.     

Direct power control of DFIG based on discrete space vector modulation

This paper presents a new direct power control (DPC) strategy for a double fed induction generator (DFIG) based wind energy generation system. Switching vectors for rotor side converter were selected from the optimal switching table using the estimated stator flux position and the errors of the active and reactive power. A few number of voltage vectors may cause undesired power and stator current ripple. In this paper the increased number of voltage vectors with application of the Discrete Space Vector Modulation (DSVM) will be presented. Then a new switching table in supersynchronous and subsynchronous frames will be proposed. Simulation results of a 2 MW DFIG system demonstrate the effectiveness and robustness of the proposed control strategy during variations of active and reactive power, machine parameters, and wind speed.     

Mathematical modeling of a multi-stage naphtha reforming process using novel thermally coupled recuperative reactors to enhance aromatic production

In this study, a novel thermally coupled reactor containing the naphtha reforming process in the endothermic side and the hydrogenation of nitrobenzene to aniline in the exothermic side has been investigated. Considering the higher thermal efficiency as well as the smaller size of the reactor, utilizing the recuperative coupled reactor is given priority. In this novel configuration, the first and the second reactor of the conventional naphtha reforming process have been substituted by the recuperative coupled reactors which contain the naphtha reforming reactions in the shell side, and the hydrogenation reaction in the tube side. The achieved results of this simulation have been compared with the results of the conventional fixed-bed naphtha reforming reactors. Acceptable enhancement can be noticed in the performance of the reactors. The production rate of the high octane aromatics and the consumption rate of the paraffins have improved 17% and 72%, respectively. The conversion of the nitrobenzene is acceptable and the effect of the number of the tubes also has been taken into account. However, the performance of the new configuration needs to be tested experimentally over a range of parameters under practical operating conditions.     

Characterization of hot-air drying and infrared drying of spearmint (<Emphasis Type="Italic">Mentha spicata</Emphasis> L.) leaves

In this study, spearmint leaves were dried using hot-air (HA) and infrared (IR) techniques. Dried products were comprehensively analyzed for their drying time, specific energy consumption (SEC), rehydration, essential oil content and color changes. The IR drying process was carried out at radiation intensity levels of 1562, 3125 and 4688 W/m², emitter to sample distances of 10, 15 and 20 cm and air temperatures of 30, 40 and 50 °C. For HA drying, three levels of air temperature (30, 40 and 50 °C) and air velocity (0.5, 1 and 1.5 m/s) were applied. The results indicated that drying time, SEC and color changes were lower in IR drying of spearmint than in HA drying. IR drying gave the highest essential oil content (0.95 %) and rehydration ratio (0.788 kg water/kg dry matter (DM)). Totally, it was observed that IR drying of spearmint resulted in better quality preservation and had lower energy costs in comparison to HA drying.     

Oil revenue shocks and government spending behavior in Iran

Oil revenues play an important role in the political economy of Iran. On average, 60% of the Iranian government revenues and 90% of export revenues originate from oil and gas resources. Current international sanctions on Iran have mainly targeted the oil production capacity of Iran and its exports to the global markets. In this study, we analyze the dynamic effects of oil shocks on different categories of the Iranian government expenditures from 1959 to 2007, using impulse response functions (IRF) and variance decomposition analysis (VDC) techniques. The main results show that Iran's military and security expenditures significantly respond to a shock in oil revenues (or oil prices), while social spending components do not show significant reactions to such shocks.     

Numerical investigation of fluid flow and heat transfer around a solid circular cylinder utilizing nanofluid

In this study, flow-field and heat transfer through a copper–water nanofluid around circular cylinder has been numerically investigated. Governing equations containing continuity, N–S equation and energy equation have been developed in polar coordinate system. The equations have been numerically solved using a finite volume method over a staggered grid system. SIMPLE algorithm has been applied for solving the pressure linked equations. Reynolds and Peclet numbers (based on the cylinder diameter and the velocity of free stream) are within the range of 1 to 40. Furthermore, volume fraction of nanoparticles (φ) varies within the range of 0 to 0.05. Effective thermal conductivity and effective viscosity of nanofluid have been estimated by Hamilton–Crosser and Brinkman models, respectively. The effect of volume fraction of nanoparticles on the fluid flow and heat transfer characteristics are investigated. It is found that the vorticity, pressure coefficient, recirculation length are increased by the addition of nanoparticles into clear fluid. Moreover, the local and mean Nusselt numbers are enhanced due to adding nanoparticles into base fluid.     

Effect of some BED blends on the equivalence ratio, exhaust oxygen fraction and water and oil temperature of a diesel engine

Nowadays, natural-based oxygenated fuels, especially biodiesel and ethanol, have been considered as substitutes for fossil fuels. Because of relatively lower energy content of oxygenated fuels, it is necessary to blend them with fossil ones. In this research, authors conducted an investigation on some BED blends to determine and compare their effects on equivalence ratio, exhaust oxygen fraction and water and oil temperature in a diesel engine. For this purpose, 18 different blendes of ethanol and biodiesel with net diesel fuel were tested in a MT4-244 engine¹ considering two engine speeds in full load condition. In almost all samples the equivalence ratio decreased with increasing of biodiesel and ethanol percents. Exhaust oxygen fraction in all of samples increased with increasing of biodiesel and ethanol percents, whereas the engine water and oil temperatures slightly reduced.