Electrical and mechanical properties of grafted and ungrafted polyacrylamide–rubber blends

A systematic dielectric and mechanical study was carried out on an ethylene propylene diene monomer (EPDM) and a nitrile rubber (NBR) blended with polyacrylamide (PAM). From the compatibility investigations, it was found that EPDM/PAM is incompatible while NBR/PAM is semicompatible. To overcome the problem of phase separation between rubber and PAM, PAM was grafted with two different monomers, acrylonitrile (AN) and acrylic acid (AA), and added with 10 phr to both EPDM and NBR. Poly(vinyl chloride) (PVC) was also added as a compatiblizing agent to both types of blend. It was concluded that the addition of either a grafted polymer or PVC to the rubber–plastic blend could improve to some extent the compatibility of such blends. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 70: 2053–2059, 1998     

哒嗪与联苯胺的新型共轭共聚物的合成及其表征

报道了联苯二胺在二价镍配合物存在下直接与3,6-二氯哒嗪的格氏(Grignard)试剂共聚合成了联苯二胺与哒嗪共聚物,新合成方法所得的共聚物通过红外光谱(FT IR),核磁共振谱(1H NMR)等进行了表征。该合成方法所得聚合物收率为60%。该类聚合物的紫外-可见吸收光谱中在313 nm处观察到最大吸收峰。根据聚合物的粉末X-射线衍射谱(XRD),热重分析(TG)对所得聚合物的结晶性和热稳定性进行了分析。     

Effect of location on virgin olive oils of the two main Tunisian olive cultivars

The olive oil content in phenolic compounds depends on the variety of the fruit used for its extraction as well as on the predominant climate conditions in the tree cultivation area. Here, we report on the characterization of virgin olive oil samples obtained from fruits of the main Tunisian olive cultivars Chemlali and Chétoui, grown in three different Tunisian locations, Zaghouan (North), Sousse (Center) and Sfax (South). Chétoui olive oil samples obtained from fruits of olive trees cultivated in Zaghouan and Chemlali olive oil samples obtained from fruits of olive trees cultivated in Sousse were found to have a higher mean total phenol content (1004 and 330 mg/kg, respectively). Olive oil samples obtained from fruits of both cultivars had different phenolic profiles and a higher content in 3,4‐DHPEA‐EDA when the olive trees were cultivated in Zaghouan. Both olive cultivars were found to have different responses to environmental conditions. Chétoui olive oil showed decreased oxidative stability when the fruits were obtained from olive trees cultivated in the center of Tunisia (34.8 h) and in Sfax (16.17 h). Furthermore, statistical data showed that the phenolic composition and oxidative stability of Chétoui olive oil varied more by location than those of Chemlali olive oils.     

Dielectric relaxation of poly(tetrafluoroethylene–perfluorovinyl ether) films

Dielectric constant and dielectric loss have been studied for poly(tetrafluoroethylene–perfluorovinyl ether) (PFA) films over a wide temperature range in the frequency range 0.1–100 kHz. Two relaxation peaks were observed, one at room temperature (α_a-relaxation) and the other in the range 170–140 K (β-relaxation), with activation energies of 143·2 and 16·4 kcal/mol, respectively. The β-absorption is attributed to the short segmental local mode motion of the main chains. The α_a-relaxation can be interpreted as due to large-scale conformational rearrangement. The Cole–Cole diagrams are given at different temperatures and the distribution parameters (ϵ₀–ϵ_∞) and (1–α) of the relaxation times were calculated. The X-ray diffraction pattern of PFA shows both a diffuse halo and sharp reflections, characteristic of amorphous and crystalline phases of conventional semicrystalline polymers. Also, no evidence of crystallinity in the films due to thermal treatment during dielectric measurements was observed. IR spectra revealed the absence of any new peaks after the heat treatment.     

Experimental optimization of composite collapsible tubular energy absorber device

A four-phase program to improve the specific energy absorbed by axially crushed composite collapsible tubular energy absorber devices was undertaken. In the first phase, examining of the crushing behaviour of non-triggered tubes was carried out. The second phase is aimed at obtaining the best position for the triggered wall. The third phase focuses on the effects of material sizing in order to understand the influence of triggered wall length on the responses of composite circular tubes to the axial crushing load. The results of these three phases of the study contribute to the fourth whose objective is to optimize the shape geometry of the cross-section area to further improving in tube energy absorption capability. The experimental results demonstrated the strong potential benefits of optimizing the material distribution. The sizing and shape optimization of composite collapsible tubes exhibited a pronounced effect on their capability to absorb high specific energy under axial compressive load.     

A new composite energy absorbing system for aircraft and helicopter

In this paper, an innovative lightweight composite energy-absorbing keel beam system has been developed to be retrofitted in aircraft and helicopter in order to improve their crashworthiness performance. The developed system consists of everting stringer and keel beam. The sub-floor stringers were designed as everting stringer to guide and control the failure mechanisms at pre-crush and post-crush failure stages of composite keel beam webs and core. Polyurethane foam was employed to fill the core of the beam to eliminate any hypothesis of global buckling. Quasi-static axial crushing behaviour of the composite keel beam is investigated experimentally. The results showed that the crushing behaviour of the developed system is found to be sensitive to the change in keel beam web thickness. Laminate sequence has a significant influence on the failure mode types, average crush loads and energy absorption capability of composite keel beam. The desired energy absorbing mechanism revealed that the innovated system can be used for aircraft and helicopter and meet the requirements, together with substantial weight saving.     

Floating ring journal bearings: theory, design and optimization

The performance characteristics and design data for journal bearings with a precise floating ring inserted between the rotating journal and a rigid housing are investigated theoretically. Based on convenient boundary conditions, a theory has been developed to predict the floating ring behaviour. Performance charts are presented with curves provided with optimum design areas to help in practical design applications. Induced ring speed, hydrodynamic behaviour, oil film variation, load capacity and frictional drag could thus be analytically or graphically determined. Results indicate that the ring dimensions are a dominant factor in deciding the final bearing behaviour and that the oil film thickness between the ring and the housing is much thinner than that between the journal and the ring. The floating ring bearing showed less frictional power loss than a fixed sleeve bearing, but this may have been achieved at the expense of the load capacity.     

The effect of hardness on the frictional behaviour of metals

It is shown experimentally that hard metals have lower frictional resistance than softer metals owing to stronger interatomic linking bonds. In hard metals the atomic bonds are strong and hence the resistance to adhesion is increased, providing low frictional characteristics. Surfaces hardened by heat treatment are also characterized by low friction. This is explained by metallurgical changes leading to changes in the structure by phase transformation, increase in the surface energy and the induction of internal (residual) stresses.     

Educational Architecture-Oriented Software Linking Conceptual Design and Solar Intensity

Fundamental architectural decisions such as a building’s form and orientation greatly influence the energy performance of a building. As these decisions are taken very early in the design process, it is important for the designer to consider such performance when comparing design alternatives. Unfortunately, this is rarely done by architects. The reason can be easily tracked to the way most architects learn about energy. Simple charts and some rules of thumb are preferred over complex calculations used by engineers and energy specialists. This paper presents an experiment conducted by the writer to tackle this problem. The writer used a purpose-made software program that is developed to help architecture students learn the impact of the conceptual design decisions on the expected energy performance of a building represented in the solar intensity on the building surfaces. The paper describes the capabilities and the structure of the software program as well as the context and the results of the experiment.     

Rapidly reconfigurable optical phase encoder-decoders based on fiber Bragg gratings

We demonstrate the capacity for fast dynamic reconfiguration of optical code-division multiple access (OCDMA) phase en/decoders based on fiber Bragg gratings and a thermal phase-tuning technique. The tuning time between two different phase codes is measured to be less than 2 s. An OCDMA system using tunable-phase decoders is compared with a system using fixed-phase decoders and, although the system using fixed-phase decoders exhibits a shorter output autocorrelation pulsewidth and lower sidelobes, the system using tunable-phase decoders has advantages of flexibility and a more relaxed requirement on the input pulsewidth.