Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopic studies on the ferroelectric behavior of poly(vinylidene fluoride–trifluoroethylene) ultrathin films

Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopy was used to characterize the ferroelectric behavior of a thin poly(vinylidene fluoride–trifluoroethylene) P(VDF–TrFE) copolymer. The lab-built GIRA-FTIR apparatus allowed the heating and corona poling process to be carried out whilst collecting the GIRA spectra of the thin polymer film. The Curie transition from the ferroelectric to paraelectric phase was confirmed from the abrupt change in intensity of the 849 cm⁻¹ band in the RA-FTIR spectrum. It was found that the Curie temperature dropped dramatically when the film thickness was lowered to below a certain critical value of approximately 100 nm. The switching of the CF₂ dipoles in the ferroelectric crystals after applying the external electric field could be determined by monitoring the change in the 849 cm⁻¹ band intensity. For the 600 nm thick P(VDF–TrFE) film, the switching of the dipoles appears to occur almost instantaneously, while the kinetics of dipole switching of the 75 nm thick film were significantly retarded. The repeated switchability of the CF₂ dipoles upon the application of a bipolar cyclic electric field was also confirmed. The bistability of the film due to remnant polarization was also confirmed from the absorbance of the 849 cm⁻¹ band after removing the applied voltage during corona poling.     

Effects of surfactant/silica and silica/cerium ratios on the characteristics of mesoporous Ce-MCM-41

Using the surfactant CTMABr (cetyltrimethyl ammonium bromide) and cerium(IV) sulfate, mesoporous Ce-MCM-41 molecular sieves were produced under a hydrothermal condition with various surfactant/silica (surfactant/Si) and silica/cerium (Si/Ce) ratios. Changes to the structural traits caused by changing the molar ratios of both surfactant/Si and Si/Ce were investigated. XRD (X-ray diffraction), FT-IR (fourier transform infrared spectroscopy), and SEM (scanning electro microscopy) were used for the characterization of prepared mesoporous samples. Among the tested molar ratios, surfactant/Si ratio of 0.5 and 0.2 showed highest values of d_1 0 0 and intensity, respectively, for the Si-MCM-41. XRD analysis also identified a quintessential hexagonal structure of Ce-MCM-41 for the Si/Ce molar ratio higher than 40 (maintaining the surfactant/Si ratio at 0.2). When cerium content was increased to have the Si/Ce molar ratio of 20, the hexagonal structure of Ce-MCM-41 was collapsed due to the structural stress of substituted cerium. FT-IR results confirmed calcination of Ce-MCM-41 and the incorporation of Ce⁴⁺ ions of cerium sulfate into the silica surface with proper removal of the surfactant. Rod-like shape with rounded edges of the prepared Ce-MCM-41 samples was identified by SEM. These results suggest surfactant/Si ratio of 0.2 and Si/Ce ratio of 40 for the production of Ce-MCM-41 with the highest level of crystallinity.     

逆向工程技术在机械领域的应用

逆向工程技术已成为联系新产品开发过程中各种先进技术的纽带,并成为实现新产品快速开发的重要技术手段.介绍了逆向工程的概念、技术流程、测量系统、常用软件以及实际应用.     

Imitation of Human-Eye Motion—How to Fix Gaze of an Active Vision System

This paper is about gaze control in active vision. The problem to tackle is, given a camera imaging a particular 3-D point, to place the 3-D point at the center of the image by rotating the camera about its own optical center. For separating this procedure from structure estimation, we use a normalized camera coordinate system, which leads to formulation defined on the unit sphere. In designing the algorithm, we try to avoid the disadvantages of local coordinates or approximation. For this purpose, we design the algorithm by considering the intrinsic geometric properties of the underlying space, not using any kinds of parameterization or approximation. The proposed algorithm is simple and of a closed form, and that makes it suitable for real-time application.     

Behaviors of concrete-filled steel tubular members subjected to combined loading

The present study is an investigation on the behaviors of concrete-filled thin-walled steel tubular members subjected to combined loading, such as compression and torsion, bending and torsion, compression, bending and torsion. ABAQUS software is used in this paper for the finite element analysis (FEA). A comparison of results calculated using this modeling shows generally good agreement with test results. The FEA modeling is then used to investigate the influence of important parameters that determine the ultimate strength of the composite members under combined loading, such as compression and torsion, bending and torsion, compression, bending and torsion. The parametric studies provide information for the development of formulae for calculating the ultimate strength of the composite members subjected to combined loading.     

On Ultra-Fine Leak Detection of Hermetic Wafer Level Packages

Theoretical and practical ranges of leak rates measurable by the helium mass spectrometer are characterized. The effect of noise due to: 1) background helium present in the spectrometer and 2) desorption of helium that attaches itself to the specimen surface during bombing is quantified experimentally. The results guide a framework to extract the true leak rate from the measured leak rate profile. An optical interferometry based hermeticity measurement technique for ultra-fine leaks is proposed. The setup to implement the technique is described and a preliminary experimental result is reported.     

Investigation of Mechanical and Electrical Characteristics for Cracked Conductive Particle in Anisotropic Conductive Adhesive (ACA) Assembly

In an anisotropic conductive adhesive (ACA) assembly, the electrical conduction is usually achieved with the conductive particles between the bumps of integrated circuit (IC) and corresponding conductive tracks on the glass substrate. Fully understanding of the mechanical and electrical characteristics of ACA particles can help to optimize the assembly process and improve the reliability of ACA interconnection. Most conductive particles used in the ACA assembly are with cracks in the metal coating of the particles after the ACA bonding. This paper introduced the fracture analysis by applying the cohesive elements in the numerical model of the nickel-coated polymer particle and further simulating the cracks initiation and propagation in the nickel coating during the ACA bonding. The simulation results showed that the stress distribution on the nickel-coated particle with cracks was significantly different from that on the nickel-coated particle without crack, indicating that the stress analysis by taking the crack into consideration is very important for the reliability assessment of the ACA interconnection. The stress analysis of cohesive elements indicated that the cracks initiated at the central area of the nickel coating and propagated to the polar area. Furthermore, by the introduction of a new parameter of the virtual resistance, a mathematical model was established to describe the electrical characteristics of the nickel-coated particle with cracks. The particle resistance of the nickel-coated particle with cracks was found to be much higher than that of the particle without crack in the optimized bonding pressure range, indicating that it is necessary to take the crack into consideration for the particle conduction analysis as well. Therefore, the fracture analysis on the conductive particle by taking the crack into consideration could accurately evaluate the reliability of ACA interconnection and avoid serious reliability issues.     

Effects of Y and Ce on Microstructures and Properties of Nb-Si System Composites

The effects of yttrium and cerium on microstructures and properties of Nb-Si system composites were investigated by scanning electron microscopy( SEM), energy dispersive spectrum(EDS), X-ray diffraction(XRD) and high temperature oxidation experiments.It is found that the coarse primary silicide phase became finer and more homogeneous with Y and Ce addition.The results of high temperature oxidation experiments show that the oxidation rates of NbSi system composites with an appropriate amount of Y and Ce decrease compared with those of alloys without Y or Ce addition, and oxidation products mainly distribute along the phase boundaries between the Nb solid solution and silicide.     

Reduction of optical beat interference using gain-saturated RSOA in upstream WDM/SCM optical links

A new scheme for reducing optical beat interference (OBI) noise in optical network units is proposed for subcarrier multiplexing-based access network applications. The optical spectrum of the transmit lasers is broadened by using a radio frequency (RF) clipping tone with a modulation depth greater than one. This reduces the impact of the OBI noise. The distortions caused by an RF clipping tone are also suppressed by introducing a gain-saturated reflective optical amplifier, which shows the characteristics of high-pass filter. The proposed scheme has been verified by measuring the error vector magnitude of 16QAM signal with 20 Mbps. Error-free transmission has been achieved even when the light of OBI-noise-causing lasers is stronger than that of the signal laser by 7 dB     

Cu—Zn—Al系合金热弹性马氏体相变的热滞

本文通过热处理工艺及添加第四组元研究了Cu－Zn－Al系记忆合金的相变热滞。结果表明，淬火冷却速度影响合金的相变热滞大小，随着母相时效时间的延长，马氏体相变热滞变大．Mn元素的加入可以减小CU－Zn－Al合金相变热滞．