Visible-light photocatalytic activity of TiO2−x by heat treatment and plasma-heat treatment

The partial reduction of TiO₂ was attempted by heat treatment and plasma-heat treatment and it was carried out to investigate the photocatalytic characteristics of partially reduced TiO₂ (TiO_2?x) in the visible-light region. As a result, the plasma-heat treatment shows significantly stronger than the heat treatment for the visible-light photocatalytic activity of TiO₂. The red-shifted absorption bands in the visible-light region of TiO_2?x by plasma-heat treatment gave broader than one by heat treatment. The TiO_2?x by heat treatment and plasma-heat treatment was changed white to beige color, and white to navy, respectively.     

Adaptive approximation bounds for vertex based contour encoding

When approximating the shape of a region, a fixed bound on the tolerable distortion is set for approximating its contour points. An adaptive approximation bound for lossy coding of the contour points is proposed. A function representing the relative significance of the contour points is defined to adjust the distortion bound along the region contour allowing an adaptive approximation of the region shape. The effectiveness of the adaptive contour coding approach for a region-based coding system is verified through experiments.     

Fabrication of Multiscale Gradient Polymer Patterns by Direct Molding and Spatially Controlled Reflow

Size variations of pattern spacing as well as gradient control of the as‐formed polymeric pattern via a spatially controlled reflow process are presented. Micro‐ and nanopatterns of polymethyl methacrylate (PMMA) in the form of line‐and‐space strips are first generated by capillary force lithography (CFL), and the residual layers are removed by ashing process. Subsequently, the exposed PMMA strips underwent a controlled reflow process above the glass transition temperature (T_g) while heating single or both sides of the substrate either in parallel to the line pattern (parallel reflow) or perpendicular to the line pattern (perpendicular reflow). As a result of this controlled reflow, a linear or a parabolic profile of pattern spacing is achieved depending on the heating mode. Furthermore, multiscale gradient patterns are formed with the spacing ranging from 98 nm to 4.23 μm (a difference of two orders of magnitude) in a single patterned layer using the original micropattern of 16 μm width and 8 μm spacing. In order to explain reflow behaviors, a simple theoretical model relating the normalized pattern width to the polymer viscosity is derived based on a leveling kinetics of polymer melt. Also, gradient PMMA channels are fabricated and bonded to a glass substrate, which are used to flow a liquid inside the channels by capillarity‐driven flow.     

Finite Element Analysis of Deformation Homogeneity During Continuous and Batch Type Equal Channel Angular Pressing

Equal channel angular pressing (ECAP) is the most promising and interesting process for refining the grain size to an ultrafine grain or nanosize by imposing severe plastic deformation into the workpiece and repeating the process while maintaining the original cross-section of the workpiece. In this paper, we simulated the batch type ECAP and the continuous type equal channel multi-angular pressing (ECMAP), which can impose large deformation by repeating the shear deformation, using the finite element method and investigated the similarity and difference of the two processes. In particular, modified die design of the continuous type ECMAP was proposed for strain uniformity.     

Linear-Time Construction of Two-Dimensional Suffix Trees

The two-dimensional suffix tree of a matrix A is a compacted tree that represents all square submatrices of A. We present the first complete version of a deterministic linear-time algorithm to construct the two-dimensional suffix tree by applying a divide-and-conquer approach.     

A design of multi‐layered location registration areas in microcellular systems

Multi‐layered location registration areas are considered to minimize the control signals at boundary cells in the microcellular systems. The decision of multi‐layered location registration (LR) areas is formulated as an integer programming problem by examining the regional subscriber densities, traffic flows and call arrival rates. By relaxing the constraints of forward and reverse control channels the problem is decomposed into a number of subproblems each of which corresponds to a layer. Each subproblem is solved via a modified graph partitioning algorithm. Feasible LR areas are obtained by considering the two relaxed constraints. Computational experiments are performed in a system with 80 microcells to investigate the performance of the proposed multi‐layer scheme. The simulation results indicate that the two‐layer scheme generally outperforms the one‐layer and three‐layer methods in view of control signals. This revised version was published online in August 2006 with corrections to the Cover Date.     

Simultaneous removal of organic and strong nitrogen from sewage in a pilot-scale BNR process supplemented with food waste.

As the sewerage system is incomplete, sewage in Korea lacks easily biodegradable organics for nutrient removal. In this country, about 11,400 tons of food waste of high organic materials is produced daily. Therefore, the potential of food waste as an external carbon source was examined in a pilot-scale BNR (biological nutrient removal) process for a half year. It was found that as the supply of the external carbon increased, the average removal efficiencies of T-N (total nitrogen) and T-P (total phosphorus) increased from 53% and 55% to 97% and 93%, respectively. VFAs (volatile fatty acids) concentration of the external carbon source strongly affected denitrification efficiency and EBPR (enhanced biological phosphorus removal) activity. Biological phosphorus removal was increased to 93% when T-N removal efficiency increased from 78% to 97%. In this study, several kinds of PHAs (poly-hydroxyalkanoates) in cells were observed. The observed PHAs was composed of 37% 3HB (poly-3-hydroxybutyrate), 47% 3HV (poly-3-hydroxyvalerate), 9% 3HH (poly-3-hydroxyhexanoate), 5% 3HO (poly-3-hydroxyoctanoate), and 2% 3HD (poly-3-hydroxydecanoate).     

Effects of shearing and comonomer content on the crystallization behavior of poly(butylene succinate‐co‐butylene 2‐ethyl‐2‐methyl succinate)

Poly(butylene succinate‐co‐butylene 2‐ethyl‐2‐methyl succinate) (PBSEMS) random copolymers were prepared with different comonomer compositions. The effects of shearing and comonomer content on the crystallization behavior of these copolymers were investigated at 80 °C. The thermal and morphological properties of the resulting samples were also discussed. The copolymers showed a longer induction time and a slower crystallization rate with increasing comonomer content. The promoting effect of shear on the overall crystallization behavior was more notable for those copolymers containing more 2‐ethyl‐2‐methyl succinic acid (EMSA) units. The melting temperature of ‘as‐prepared’ poly(butylene succinate) (PBS) was ca. 115 °C, while that of the copolymers varied from 112 to 102 °C. Higher comonomer contents in the copolymers gave rise to lower melting temperatures and broader melting peaks. In addition, the isothermally crystallized samples showed multiple melting endothermic behavior, the extent of which depended on the comonomer content. The copolymers showed different wide‐angle X‐ray diffraction (WAXD) patterns from that of neat PBS, depending on the comonomer content and shear applied during crystallization. With increasing comonomer content, the copolymers crystallized without shearing, showing the shifting of a diffraction peak to a higher angle, while those crystallized under shear did not show any peak shift. Copyright © 2004 Society of Chemical Industry