Mathematical model evaluating for degradation of azo dye in contaminated water by UV/persulfate process

In the present study, the photooxidative degradation of Acid Red 14 (AR 14) was investigated in the UV/persulfate process, and the results of the degradation rate of AR 14 were parametrically represented by ordinary differential equations to find mathematical model for the degradation rate of AR 14 in this process. Our experimental observations led to a model for AR 14 degradation in the UV/persulfate system that could be used to predict removal efficiency by changes of S₂O₈²⁻ (X₁) and dye concentration (X₂), pH (X₃), temperature (X₄) and also distance of UV lamp from solution (X₅). It was found that persulfate and dye concentrations were the most important parameters for AR 14 degradation rate. Moreover, the results showed that the degradation rate was in good agreement with the first-order kinetics for all the parameter values studied. Moreover, the results of the mathematical model agree well with the experimental values (R² = 0.96). Our findings in this study showed that degradation efficiency of UV/S₂O₈²⁻ process for AR 14 was obtained as 98%. Therefore, this model could be applicable before scaling up the AR 14 degradation using UV/persulfate process.     

Preparation and characterization of novel derivatives of chitosan and trimethyl chitosan conjugated with dipeptides and vitamin B12 as candidates for oral delivery of insulin

Chitosan and its derivatives are widely used in drug delivery systems due to their bio-degradebility, bio-compatibility and absorption enhancing properties. Many peptide and protein derived therapeutics cannot be administered through oral rout because of the proteolytic condition of gastro-intestinal tract and their low bio-availability. Insulin is a peptide drug which is widely used in diabetics as repeated daily injection. Due to the fact that there are receptors for didpeptides and vitamine B12 in small intestine, in this research work novel derivatives of chitosan and trimethyl chitosan conjugated with glycyl-glycine, alanyl-alaninie and vitamine B12 were synthesized and characterized. The structure of conjugates as well as substitution of different functional groups was confirmed by different instrumental analytical methods such as Fourier transform infrared, magnetic resonance, and X-ray diffraction spectroscopy. Nano-particles of aforementioned loaded with insulin were prepared and their size, surface electrical charge and morphology characterized and their release profile were studied. The results are promising and reveal that these new chitosan and trimethyl chitosan derivatives are potential vehicles for protein and peptide drug molecules.     

Preliminary analysis of spatial development of karst using a geostatistical simulation approach

Earth science phenomena are primarily spatially dependent with variations occurring on varying scales. Geostatistics is a well-known approach for the assessment of spatial models of regionalized variables, such as porosity. In this study, we used the results of 953 Lugeon tests (402 tests in exploratory wells and 550 tests in grouting wells) to assess effective porosity and karst development at the Tangab Dam site, Iran. Lugeon values were first normalized, following which the variogram method (i.e., range, sill, and nugget effect) was used to identify the spatial variability of Lugeon values. A high correlation range of 200 m was obtained along the grout curtain galleries, while the range was about 40 m in the vertical direction. The simple kriging method with Gaussian variograms was determined to be the best method for estimating the Lugeon values in the study area using cross validation-criteria (e.g., RMSE = 0.835 and ρ = 0.914). Spatial variation of Lugeon values was mapped using a simulated annealing approach. The analysis revealed: (1) a higher potential for karst development on the left abutment of the Tangab Dam site, (2) the average of simulated Lugeon values decreased from values of about 180 close to the ground surface at 1,440 m a.s.l. to lower values of about 50 at 1,260 m a.s.l., and (3) high Lugeon values in the abutments of the dam site approximately followed the 15° bedrock dip, which confirms the potential development of karst features in the Asmari limestone. A schematic model for development of karst at the Tangab Dam site is proposed based on hydrogeological data and results of simulated Lugeon values around the dam site.     

Dual-Rotation Speed Friction Stir Welding: Experimentation and Modeling

Implementing differential rotation speeds of pin and shoulder in the friction stir welding process is considered. Experimental investigations were carried out using a newly designed and fabricated apparatus for dual-rotation speed friction stir welding. Metallographic studies demonstrated that appropriate selection of separate pin and the shoulder rotation speeds not only results in defect-free joints, but also affects the weld zone by controlling the heat input delivered. An energy model for predicting maximum temperature was extended to the dual-rotation speed friction stir process. The model was verified using the previous experimental results reported in the literature.     

Training based, moving digital filter method for real time heat flux function estimation

In this paper the neural networks is utilized to estimate the “filter coefficients” needed to estimate heat flux in a particular system. In developing the training phase of the network inspiration is drawn from the Burgraff's exact solution of the IHCP as well as the filter method. Thus, the estimation phase neither requires any temperature field nor the sensitivity coefficients calculations. The neural network used in this work is a 2-layer perceptron. It is shown via classical triangular heat flux test cases that the method can yield very accurate, very efficient as well as stable estimations.     

Classical coupled thermoelasticity in laminated composite plates based on third-order shear deformation theory

A new mixed finite element formulation is proposed to analyze transient coupled thermoelastic problems. Coupled model of dynamic thermoelasticity is selected for a laminated composite and a homogeneous isotropic plate. For the particular finite element developed here, there are 15 degrees of freedom at each node. Two simply supported plates are considered subjected to sinusoidally distributed mechanical and thermal loading. It is seen, by comparing the present results with results from the NISA II FEM code, that they are in good agreement.     

Dynamic Behavior of Steel Deck Tension-Tied Arch Bridges to Seismic Excitation

The dynamic responses of steel deck, tension-tied, arch bridges subjected to earthquake excitations were investigated. The 620 ft (189 m) Birmingham Bridge, located in Pittsburgh, was selected as an analytical model for the study. The bridge has a single deck tension-tied arch span and is supported by two bridge piers, which in turn are supported by the pile foundations. Due to the complex configuration of the deck system, two analytical models were considered to represent the bridge deck system. Using the normal mode method, seismic responses were calculated for two bridge models and the results were compared with each other. Three orthogonal records of the El Centro 1940 earthquake were used as input for the seismic response analysis. The modal contributions were also checked in order to obtain a reasonable representation of the response and to minimize computational cost. Displacements and stresses at the panel points of the bridge are calculated and presented in graphical form.     

PVC membrane potentiometric sensor based on 5-pyridino-2,8-dithia[9](2,9)-1,10-phenanthroline-phane for selective determination of neodymium(III)

Spectrofluorometric studies on the binding properties of 5-pyridino-2,8-dithia[9](2,9)-1,10-phenanthrolinephane (L) toward La3+, Sm3+, Gd3+, Yb3+, and Nd3+ in methanol solution revealed the occurrence of both 1:1 and 2:1 (ligand/metal) complexation with a stability order of Nd3+ > Yb3+ > Gd3+ > Sm3+ > La3+. Consequently, L was used as a suitable neutral ionophore for the preparation of a novel polymeric membrane-selective electrode for Nd3+ ion. The electrode exhibited a Nernstian response over a wide concentration range (1.0 x 10(-6)-1.0 x 10(-2) M) with a low limit of detection of 7.9 x 10(-7) M. The electrode possesses a fast response time of <5 s and can be used for at least 9 weeks without observing any considerable deviation. The proposed electrode revealed a very good selectivity for Nd3+ over a wide variety of alkali, alkaline earth, transition, and heavy metal ions, including members of the lanthanide family other than Nd3+. The potentiometric response of the electrode is independent of the pH of test solution in the pH range 4.0-6.5. The proposed electrode was successfully applied to the recovery of Nd3+ ion from tap water samples and, also, as an indicator electrode, in potentiometric titration of neodymium(III) ions.