Humidity sensing properties of Cu2O-PEPC nanocomposite films

In this study, the blend of copper oxide nanopowder (Cu2O), 3 wt.% and poly-N-epoxypropylcarbazole (PEPC), 2 wt.% in benzol were drop-casted on glass substrates with pre-deposited surface-type silver electrodes for the fabrication of Cu2O-PEPC nanocomposite thin films. The thicknesses of the Cu2O-PEPC films were in the range of 10-13 μm. The effect of humidity on the electrical properties of the nanocomposite films was investigated by measurement of the capacitance and dissipation of the samples at two different frequencies of the applied voltage: 120 Hz and 1 kHz. The AC resistance of the samples was determined from values of dissipation. The DC resistance was measured directly. The effect of ageing on the humidity sensing properties of the nanocomposite was observed. After the ageing it was observed that at 120 Hz and 1 kHz, under humidity of up to 86% RH , the capacitance of the cell increased by 85 and 8 times and resistance decreased by 345 and 157 times, accordingly, with respect to 30% RH conditions. It was found that with increase of the frequency, the capacitance and resistance of the samples decreased. It is assumed that the humidity response of the cell is associated with diffusion of water vapors and doping of the semiconductor nanocomposite by water molecules.     

Gaining Insight into the Effect of Organic Interface Layer on Suppressing Ion Migration Induced Interfacial Degradation in Perovskite Solar Cells

Ion migration induced interfacial degradation is a detrimental factor for the stability of perovskite solar cells (PSCs) and hence requires special attention to address this issue for the development of efficient PSCs with improved stability. Here, an “S‐shaped, hook‐like” organic small molecule, naphthalene diimide derivative (NDI‐BN), is employed as a cathode interface layer (CIL) to tailor the [6,6]‐phenylC61‐butyric acid methylester (PCBM)/Ag interface in inverted PSCs. By realizing enhanced electron extraction capability via the incorporation of NDI‐BN, a peak power conversion efficiency of 21.32% is achieved. Capacitance–voltage measurements and X‐ray photoelectron spectroscopy analysis confirmed an obvious role of this new organic CIL in successfully blocking ionic diffusion pathways toward the Ag cathode, thereby preventing interfacial degradation and improving device stability. The molecular packing motif of NDI‐BN further unveils its densely packed structure with π–π stacking force which has the ability to effectually hinder ion migration. Furthermore, theoretical calculations reveal that intercalation of decomposed perovskite species into the NDI clusters is considerably more difficult compared with the PCBM counterparts. This substantial contrast between NDI‐BN and PCBM molecules in terms of their structures and packing fashion determines the different tendencies of ion migration and unveils the superior potential of NDI‐BN in curtailing interfacial degradation.     

EMI Shielding Characteristics of Electrically Conductive Polymer Blends of PS/PANI in Microwave and IR Region

Conductive polymeric blends (CPBs) of polystyrene and polyaniline (PS/PANI) were prepared by solution casting method in various compositions. Film thickness of CPBs was achieved?～?250 micron. PS/PANI blend films were analyzed for electromagnetic interference (EMI) shielding characteristics in microwave and near-infrared (NIR) regions. PS/PANI blends showed remarkable features. Most mobile telecommunications use GHz frequency range and shielding effectiveness was observed in 9 GHz to 18 GHz. In 9 GHz to 18 GHz frequency range, 45 dB shielding effectiveness was measured. CPBs were also analyzed in the NIR region and showed transmittance of <1%. Microwaves and NIR radiation are the most abundant in the environment and cause damage to human health. Both types of radiation causes serious damage to electronic devices as well.

     

Velocity-image model for online signature verification.

In general, online signature capturing devices provide outputs in the form of shape and velocity signals. In the past, strokes have been extracted while tracking velocity signal minimas. However, the resulting strokes are larger and complicated in shape and thus make the subsequent job of generating a discriminative template difficult. We propose a new stroke-based algorithm that splits velocity signal into various bands. Based on these bands, strokes are extracted which are smaller and more simpler in nature. Training of our proposed system revealed that low- and high-velocity bands of the signal are unstable, whereas the medium-velocity band can be used for discrimination purposes. Euclidean distances of strokes extracted on the basis of medium velocity band are used for verification purpose. The experiments conducted show improvement in discriminative capability of the proposed stroke-based system.     

Efficient identity-based security schemes for ad hoc network routing protocols

Wireless ad hoc networks consist of nodes with no central administration and rely on the participating nodes to share network responsibilities. Such networks are more vulnerable to security attacks than conventional wireless networks. We propose two efficient security schemes for these networks that use pairwise symmetric keys computed non-interactively by the nodes which reduces communication overhead. We allow nodes to generate their broadcast keys for different groups and propose a collision-free method for computing such keys. We use identity-based keys that do not require certificates which simplifies key management. Our key escrow free scheme also uses identity-based keys but eliminates inherent key escrow in identity-based keys. Our system requires a minimum number of keys to be generated by the third party as compared to conventional pairwise schemes. We also propose an authenticated broadcast scheme based on symmetric keys and a corresponding signature scheme.     

Live video streaming service with pay-as-you-use model on Ethereum Blockchain and InterPlanetary file system

Wireless Networks - In centralized video streaming platforms, the platform owner, rather than the content producer, controls most of the content uploaded on the centralized video...     

PAPR reduction in mobile WiMAX: a novel DST precoding based random interleaved OFDMA uplink system

Mobile WiMAX is a 3rd generation broadband wireless technology that enables the convergence of mobile and fixed broadband networks through a wide area radio-access. Since January 2007, the IEEE 802.16 working group has been developing a new amendment the IEEE 802.16 standard i.e. IEEE 802.16 m as an advanced air interface to meet the requirements of ITU-R/IMT-Advanced for 4G systems. The mobile WiMAX air interface adopts orthogonal frequency division multiple access (OFDMA) as multiple access technique for its uplink and downlink to improve signal performance affected by multipath distortion. All OFDMA based networks, including mobile WiMAX, experience the problem of high peak-to-average power ratio (PAPR). This paper presents a discrete-sine-transform precoding technique based random-interleaved OFDMA (RI-OFDMA) uplink system for PAPR reduction in mobile WiMAX. The PAPR of proposed system is analyzed with root-raised-cosine pulse shaping filter to keep out of band radiation low and to fulfill the spectrum mask requirements. Simulation results show that, the proposed system has low PAPR compared to the Hadamard transform precoded RI-OFDMA uplink systems and the conventional RI-OFDMA uplink systems.     

Using Sorted Switching Median Filter to remove high-density impulse noises

We propose a novel Sorted Switching Median Filter (i.e. SSMF) for effectively denoising extremely corrupted images while preserving the image details. The center pixel is considered as “uncorrupted” or “corrupted” noise in the detecting stage. The corrupted pixels that possess more noise-free surroundings will have higher processing priority in the SSMF sorting and filtering stages to rescue the heavily noisy neighbors. Five noise models are considered to assess the performance of the proposed SSMF algorithm. Several extensive simulation results conducted on both grayscale and color images with a wide range (from 10% to 90%) of noise corruption clearly show that the proposed SSMF substantially outperforms all other existing median-based filters.     

Facile Fabrication of PbS Nanocrystal:C60 Fullerite Broadband Photodetectors with High Detectivity

Hybrid PbS nanocrystal/C₆₀ fullerite photodetectors are fabricated using a simple one‐step drop casting procedure onto pre‐patterned interdigitated electrodes. The devices exhibit a broad spectral response from the near UV through to the near infrared yielding a detectivity, D*, of above 10¹⁰ Jones from 400 nm to ≈1050 nm. The ability to further extend the spectral response to wavelengths ≈1350 nm in the near infrared via tuning of the PbS nanocrystal diameter is also demonstrated. The dynamic responses of the devices are presented, exhibiting a fast photocurrent rise time (<40 ns) followed by a long bi‐exponential decay with characteristic lifetimes of τ₁ = 5.3 μs ± 0.1 μs and τ₂ = 37.8 μs ± 0.7 μs. These devices, which have a detectivity approaching that of commercial detectors, a broader spectral response, and a fast rise time, offer an attractive low‐cost solution for large‐area broadband photodetectors.     

Ultra-Robust Flexible Electronics by Laser-Driven Polymer-Nanomaterials Integration

Polyethylene terephthalate (PET) is the most widely used polymer in the world. For the first time, the laser-driven integration of aluminum nanoparticles (Al NPs) into PET to realize a laser-induced graphene/Al NPs/polymer composite, which demonstrates excellent toughness and high electrical conductivity with the formation of aluminum carbide into the polymer is shown. The conductive structures show an impressive mechanical resistance against >10000 bending cycles, projectile impact, hammering, abrasion, and structural and chemical stability when in contact with different solvents (ethanol, water, and aqueous electrolytes). Devices including thermal heaters, carbon electrodes for energy storage, electrochemical and bending sensors show this technology's practical application for ultra-robust polymer electronics. This laser-based technology can be extended to integrating other nanomaterials and create hybrid graphene-based structures with excellent properties in a wide range of flexible electronics’ applications.