Formation of alkylated aromatic acids in groundwater by anaerobic degradation of alkylbenzenes

Evidence for the presence of previously unreported alkylated aromatic acids in anaerobic groundwater samples from a jet fuel-contaminated site is presented. The redox conditions are dominated by sulfate reduction. A gas chromatography/mass spectrometry screening showed a composition of aromatic hydrocarbons ranging from BTEX (C(0)-C(2)-substituted benzenes) up to C(7)-benzenes. Known metabolites like methylbenzoates (C(1)-BA), C(2)-BA, C(3)-BA as well as methylbenzylsuccinates (C(1)-BSA) were detected. Additionally, previously unreported metabolites of higher alkylated benzenes have been identified in the extracts: those are C(2)-BSA to C(5)-BSA as well as C(4)-BA to C(6)-BA, which were detected in the microg/l-concentration range. The formation of C(1)- and C(2)-BSA as well as the C(1)- and C(2)-BA can be linked to structurally corresponding parent contaminants like the xylene isomers and the trimethylbenzene isomers. The C(3)-BSA and C(3)-BA represent metabolites of C(4)-benzenes. The occurrence of C(4)-C(5)-BSA and C(4)-C(6)-BA is attributed to C(5)-C(7)-benzenes acting as parent compounds. The concentration of total aromatic contaminants decreased along the plume centre line. In contrast, benzoates and benzylsuccinates (BA and BSA) showed constant concentrations over a distance of 84 m. BA concentrations were up to 162 times higher compared to BSA, as indicated by the ratio f(BA/BSA). A pronounced transient behaviour of BSA or an overall persistent behaviour of BA can explain this. Hence, along the plume centre line, f(BA/BSA) was constant over a distance of 128 m. The degradation products detected in a monitoring well are not necessarily tied to contaminants detected in that well. Therefore, the metabolite plume is partly located in front of the contaminant plume, but does not significantly migrate downstream the plume toe.     

Radon and 'King Solomon's Miners': Faynan Orefield, Jordanian Desert

Concentrations of 222Rn were measured in ancient copper mines which exploited the Faynan Orefield in the South-Western Jordanian Desert. The concentrations of radon gas detected indicate that the ancient metal workers would have been exposed to a significant health risk and indicate that any future attempt to exploit the copper ores must deal with the hazard identified. Seasonal variations in radon concentrations are noted and these are linked to the ventilation of the mines. These modern data are used to explore the differential exposure to radon and the health of ancient mining communities.     

Land management as a factor controlling dissolved organic carbon release from upland peat soils 2: Changes in DOC productivity over four decades

Increasing DOC concentrations in surface waters have been observed across parts of Europe and North America over the past few decades. Most proposed explanations for these widespread trends invoke climate change or reductions in sulphate deposition. However, these factors do not seem apposite to explain either the fine-scale (within kilometres) or regional-scale spatial variation in DOC concentrations observed across the UK.We have reconstructed DOC concentrations and land use for one North Pennine and five South Pennine catchments (UK), located in three discrete areas, over the last four decades. Rainfall, temperature and sulphate deposition data, where available, were also collated and the potential influence of these factors on surface water DOC concentrations was assessed.Four of the six catchments examined showed highly significant (p < 0.001) increases (53-92%) in humic coloured DOC (hDOC) concentrations in drainage waters over the period 1990-2005. Changes in temperature and sulphate deposition may explain 20-30% of this trend in these four catchments. However, the rapid expansion of new moorland burn on blanket peat can explain a far greater degree (> 80%) of the change in hDOC. Far smaller increases in hDOC (10-18%) were identified for the two remaining catchments. These two sites experienced similar changes in sulphur deposition and temperature to those that had seen largest increases in DOC, but contained little or no moorland burn management on blanket peat.This study shows that regional-scale factors undoubtedly underlie some of the recent observed increases in drainage humic coloured DOC. However, changes in land management, in this case the extensive use of fire management on blanket peat, are a far more important driver of increased hDOC release from upland catchments in some parts of the UK. It suggests that the recent rapid increase in the use of burning on blanket peat moorland has implications for ecosystem services and carbon budgets.     

Engineering geology today

Summary The author discusses the development and present state of the engineering geology. He warns the engineering geologists against a merely mechanical approach and emphasizes that an engineer needs to understand geology as well. Further an analysis of the relation between geology and civil engineering and between engineering geology and soil and rock mechanics is presented. Finally the paper deals with the tasks of engineering geology at designing and construction of structures as well as with the problems of education in engineering geology.

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La Géologie De l’Ingénieur Aujourd’Hui

Résumé L’auteur examine la question du développement et de la situation acutelle de la géologie de l’ingénieur. II préviend d’un accès simplement méchanical en accentuant, qu’il est vraiement nécéssaire pour un ingénieur de comprendre aussi la géologie. Puis, l’auteur analyse la rélation entre la géologie et la construction ainsi qu’entre la géologie de l’ingénieur et la mécanique du sol. Enfin, le travail traits les taches de la géologie de l’ingénieur dans la sphère des projets et de la réalisation des constructions ainsi que les problèmes de l’éducation.

     

Arsenic and heavy metals in soils associated with regional geochemical anomalies in South-West England

Regional geochemical maps have shown extensive anomalies of arsenic, copper and other heavy metals in those parts of South-West England associated with mineralised zones around the granite intrusion. Studies in the vicinity of the River Tamar and of the metamorphic aureole around Dartmoor have confirmed significantly higher concentrations of arsenic and heavy metals in soils contaminated by mining, smelting and mineralisation compared with those from nearby control areas. Arsenic and copper show the greatest degree of enhancement ranging up to 900 ppm As and 2000 ppm Cu in both alluvial and upland topsoils within the Tamar area. Preliminary analyses indicate that the trace metal content of pasture herbage-reflects in part the degree of soil contamination. Maximum concentrations of 35 ppm As and 22 ppm Cu in autumn sampled herbage were found at contaminated sites compared with mean values of less than 0.5 ppm As and 8 ppm Cu in control areas. Geochemical reconnaissance surveys based on stream sediment sampling provide a useful indication of areas wherein widescale soil contamination may occur.     

Solar heating and night radiation cooling by a Roof Radiation Trap

The paper describes a new system, the Roof Radiation Trap, which utilizes solar energy for heating of buildings in winter and nocturnal radiation for cooling in summer. The radiation trap consists of fixed insulating layer separated from the flat roof and glazing, protected by hinged insulating panel, in the southern gap between the roof and the fixed insulation. This fixed insulating layer is covered by corrugated metal sheets, painted white, which serve as nocturnal radiators in summer.The radiation trap is integrated with the building, thermally as well as architecturally. In winter the sun energy penetrates through the glazing and is absorbed directly in the roof, which serves as a combined collector, storage for one night and heat distribution system.The hot air in the space between the flat roof and the fixed insulation is blown into a thermal storage of gravel, under the floor or inside the building. The stored heat is “recovered” by forced convection during cloudy days.In summer the penetration of solar radiation during daytime is prevented by the hinged insulating panel. At night the painted external metal layer is cooled by outgoing radiation and the air under the corrugations is blown into the space of the radiation trap and cools the roof, which, in turn, serves as a heat sink during the next day. Nocturnal evaporative cooling can supplement the radiant cooling.     

Electromagnetic Effect of an Alternating Current Traction Power Supply System with a High-Voltage Power Cord on Electrical Installations and Networks of Nontraction Consumers

Russian Electrical Engineering - In this paper, we ground a method for calculating switching overvoltages including the discharge of lightning currents into the contact network and into a...     

Diagnostics of Multioperation Processes Using Basic Cells of Digital Homogeneous Structures

Russian Electrical Engineering - The cells of homogeneous digital structures designed for multioperation process diagnostics are considered in the form of graphic models. Digital circuits and...