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81.
Deniz Ozdil Halil Murat Aydin 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2014,89(12):1793-1810
Recent decades have seen great advancements in medical research into materials, both natural and synthetic, that facilitate the repair and regeneration of compromised tissues through the delivery and support of cells and/or biomolecules. Biocompatible polymeric materials have become the most heavily investigated materials used for such purposes. Naturally‐occurring and synthetic polymers, including their various composites and blends, have been successful in a range of medical applications, proving to be particularly suitable for tissue engineering (TE) approaches. The increasing advances in polymeric biomaterial research combined with the developments in manufacturing techniques have expanded capabilities in tissue engineering and other medical applications of these materials. This review will present an overview of the major classes of polymeric biomaterials, highlight their key properties, advantages, limitations and discuss their applications. © 2014 Society of Chemical Industry 相似文献
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Mustafa Yıldırım Murat Tonaroğlu Murat E. Selçuk Cem Akgüner 《Bulletin of Engineering Geology and the Environment》2013,72(3-4):413-420
For over 50 years, the Upper Oligocene–Upper Miocene sedimentary sequence in Istanbul has been considered to be formed of two distinct sequences separated by an unconformity. However, recent field observations and an analysis of numerous borehole data indicate the Gürp?nar, Çukurçe?me and Güngören Formations are in fact a single sequence of alternating clay–sand/sandstone beds/lenses, here named the Avc?lar Formation. The Bak?rköy Formation, which is typically composed of carbonate rocks, conformably overlies the Avc?lar Formation. The paper provides the geotechnical parameters of the units within the Avc?lar Formation which it is hoped will facilitate selecting suitable geotechnical and engineering geological parameters to represent the deposits and minimize errors in the interpretation/evaluation of in-situ conditions. 相似文献
85.
Tan Fırat Eyüboğlu Murat Türkün Necdet Erdilek Mutlu Özcan 《Journal of Adhesion Science and Technology》2016,30(14):1574-1584
This study evaluated the long-term microleakage of access cavities conditioned with phosphoric acid and deproteinizing agents for root-canal-treated teeth using fluid filtration and microscopical analysis. Occlusal surfaces of extracted human mandibular premolars (N = 90) were removed leaving a 4 mm coronal length from the cemento-enamel junction. After root canal treatment, the specimens were randomly divided into four experimental groups (n = 21) and the remaining teeth were used for positive control group (n = 6): SB: 35% H3PO4 + Adper Single Bond 2; SSB: 35% H3PO4 + 5.25% NaOCl + 10% Sodium ascorbate (C6H7NaO6) + Adper Single Bond 2; XP: 35% H3PO4+XP Bond; SXP: 35% H3PO4+5.25% NaOCl + 10% Sodium ascorbate + XP Bond. All cavities were restored with a resin composite (Filtek Z250). After removing the root filling from the apical side, teeth were subjected to fluid filtration test for 1 week, 6 and 12 months followed by ×2500 thermocycling after 1st week and 6th months each. Data were analyzed using one-way ANOVA and Dunnet T3 tests (α = 0.05). SEM analyses were carried out after each microleakage evaluation in two random teeth from all groups. Microleakage values in groups SB and XP presented no significant difference in any of the evaluated period (p > 0.05). Microleakage results of SXP (0.01665) group showed significant difference compared to XP (0.03377) and SB (0.03049) groups after 12 months. SSB group (0.00901) showed significantly less microleakage among all other groups (0.01665–0.03377) (p < 0.05). Prior to endodontic treatment, in access cavities, acid etching with 35% H3PO4 followed by the application of NaOCl and sodium ascorbate completely destroyed the collagen layer, reducing the microleakage and resin–dentin interface degradation up to 12 months. 相似文献
86.
Polypyrrole/multi-walled carbon nanotube, poly(3,4-ethylenedioxythiophene)/multi-walled carbon nanotube and their nanocomposites P(EDOT-co-Py)/multi-walled carbon nanotube and P(EDOT-co-Py)/copper (II) oxide, (CuO) in the initial feed ratio of [EDOT]0/[Py]0 = 1/5 were electrosynthesized on glassy carbon electrode by cyclic voltammetric method. Their characterizations were performed by cyclic voltammetric, Fourier transform infrared-attenuated total reflectance, scanning electron microscopy, energy dispersion X-ray analysis, and electrochemical impedance spectroscopy. To the best of authors’ knowledge, the first report on polypyrrole/multi-walled carbon nanotube, PEDOT/multi-walled carbon nanotube, P(EDOT-co-Py)/multi-walled carbon nanotube and P(EDOT-co-Py)/CuO nanocomposite films were comparatively examined in 0.1 M NaClO4/CH3CN and in 0.1 M sodium dodecyl sulfate solutions. The highest specific capacitance for PEDOT/multi-walled carbon nanotube and polypyrrole/multi-walled carbon nanotube composite films were obtained as Csp = 306 mF × cm?2 for 3% multi-walled carbon nanotube and Csp = 804 mF × cm?2 for 1% multi-walled carbon nanotube, respectively. The highest specific capacitances were obtained as Csp = 27.40 mF × cm?2 and Csp = 26.90 mF × cm?2 for P(EDOT-co-Py)/multi-walled carbon nanotube includes the wt percent of 1% multi-walled carbon nanotube and P(EDOT-co-Py)/CuO includes the wt percent of 3% CuO, respectively. The Csp of P(EDOT-co-Py)/CNT composite films were calculated as 9.43 and 11.49 mF × cm?2 for 3 and 5% multi-walled carbon nanotube, respectively. In addition, The EIS results were simulated with the equivalent circuit model of Rs(Cdl1(R1(QR2)))(Cdl2R3). 相似文献
87.
Synthesis,characterization and,swelling behavior of semi‐IPN nanocomposite hydrogels of alginate with poly(N‐isopropylacrylamide) crosslinked by nanoclay 下载免费PDF全文
pH and temperature responsive nanocomposite hydrogels were synthesized with sodium alginate (NaAlg), N‐isopropylacrylamide (NIPA), and nanoclay. The structure, morphology, thermal behavior, and swelling and deswelling behaviors of the hydrogels were studied. The NaAlgm/PNIPA/Clayn hydrogels revealed a highly porous structure in which the pore sizes decreased and the amount of pores increased with increasing the nanoclay content in the hydrogels. PNIPA retained its own characteristics regardless of the amount of NaAlg and nanoclay. The effect of pH and nanoclay content on the swelling and effect of temperature on the deswelling behavior were investigated. The equilibrium swelling ratios of the nanocomposite hydrogels increased with increasing the pH from 2 to 6. The maximum swelling was attained at pH 6. Deswelling increased with increasing the nanoclay content in the hydrogels. The hydrogels were found to be pH and temperature responsive. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43222. 相似文献
88.
Novel colloidal nanofiber electrolytes from PVA‐organoclay/poly(MA‐alt‐MVE), and their NaOH and Ag‐carrying polymer complexes 下载免费PDF全文
Murat Şimşek Zakir M. O. Rzayev Selim Acar Bahtiyar Salamov Ulviya Bunyatova 《Polymer Engineering and Science》2016,56(2):204-213
Novel multifunctional polymer nanofiber electrolytes with covalence crosslinked structures from various solution blends of reactive intercalated poly(vinyl alcohol)/octadecylamine montmorillonite (as a matrix polymer), poly(maleic anhydride‐alt‐methyl vinyl ether) (as a partner polymer) and their NaOH‐absorbing and Ag‐carrying polymer complexes were fabricated via electrospinning. Chemical, physical, morphological, and electrical properties of nanofiber structures were investigated by FTIR, XRD, SEM, and electrical analysis methods. Ag precursors in fiber composites significantly improved phase separation processing, fiber morphologies, diameter distributions, and electrical properties of the fibers. In situ generation of Ag nanoparticles and their distribution on nanofiber surfaces during fiber formation occurred via complex formation between silver cations and electronegative functional groups from both matrix and partner polymers as stabilizing/reducing agents. Electrical resistance and conductivity strongly depended on matrix/partner polymer ratios and absorption time of NaOH solution on nanofibers. Addition of NaOH changed the electrical properties of fiber structures from almost dielectric state to excellent conductivity form. The fabricated unique nanofiber electrolytes are promising candidates for applications in power and fuel cell nanotechnology, electrochemical, and bioengineering processes as reactive semiconductive platforms. POLYM. ENG. SCI., 56:204–213, 2016. © 2015 Society of Plastics Engineers 相似文献
89.
该文提出了一种新的描述图像纹理信息的复杂度直方图特征,实验结果表明该特征用于图像检索可以取得较好的检索效果。文章同时将该特征与图像色彩直方图组合特征用于图像检索,实验结果证实使用组合特征可以得到更高的检索效率。 相似文献
90.
A new series of poly(azomethine-imide)s having siloxane moities in backbone was prepared using different dianhydrides.Thermal, optical, and morphological properties of these polymers were clarified. Also, bulky CO and CF3 group effects and meta or para-substituted aldeyhde effects on the mentioned properties were evaluated. The structural characterization of poly(azomethine-imide)s was carried out using a FT-IR spectroscopy. The optical properties of the polymers were performed via an UV–Vis spectrophotometer. Optical band gap of the poly(imide)s containing azomethine was calculated between 2.20 and 2.33 eV. Thermal behavior of poly(azomethine-imide)s was also studied using TG-DTA, DSC, and DMA techniques. The onset degradation temperature and percentage char values of the polyimides were found in the range from 429 to 545 °C and 22 to 35%, respectively. Thermal stability results demonstrated that benzophenone bearing poly(azomethine-imide)s have higher onset temperature, percentage char, and the glass transition temperature than poly(azomethine-imide)s derived from hexafluoroisopropylidene. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48364. 相似文献