Radioactivity concentrations in soil and dose assessment for Samsun City Centre, Turkey

In this study, natural gamma radioactivity levels were determined in the soil samples of the Samsun city centre by using the gamma ray spectrometry method. The analysis carried out with the high-purity germanium gamma spectrometry system has shown that average activity concentrations of (238)U, (232)Th, (40)K and (137)Cs were 19±2, 22±4, 521±23 and 15±1 Bq kg(-1), respectively. From the gamma analysis of soil samples, the average value of the absorbed gamma dose rates in air and the average value of the external annual effective dose rates were calculated as 45±4 nGy h(-1) and 55±5 μSv y(-1), respectively. The external hazard index has also been calculated and it has been found that the radiation hazard in Samsun is insignificant.     

A minisum location problem with regional demand considering farthest Euclidean distances

We consider a continuous multi-facility location-allocation problem that aims to minimize the sum of weighted farthest Euclidean distances between (closed convex) polygonal and/or circular demand regions, and facilities they are assigned to. We show that the single facility version of the problem has a straightforward second-order cone programming formulation and can therefore be efficiently solved to optimality. To solve large size instances, we adapt a multi-dimensional direct search descent algorithm to our problem which is not guaranteed to find the optimal solution. In a special case with circular and rectangular demand regions, this algorithm, if converges, finds the optimal solution. We also apply a simple subgradient method to the problem. Furthermore, we review the algorithms proposed for the problem in the literature and compare all these algorithms in terms of both solution quality and time. Finally, we consider the multi-facility version of the problem and model it as a mixed integer second-order cone programming problem. As this formulation is weak, we use the alternate location-allocation heuristic to solve large size instances.     

Renewable and Storage Energy Integration for Smart Grid Housing

This paper presents the design,implementation and testing of an embedded system that integrates solar and storage energy resources to smart homes within the smart microgrid.The proposed system provides the required home energy by installing renewable energy and storage devices.It also manages and schedules the power flow during peak and off-peak periods.In addition,a two-way communication protocol is developed to enable the home owners and the utility service provider to improve the energy flow and the consumption efficiency.The system can be an integral part for homes in a smart grid or smart microgrid power networks.A prototype for the proposed system was designed,implemented and tested by using a controlled load bank to simulate a scaled random real house consumption behavior.Three different scenarios were tested and the results and findings are reported.Moreover,data flow security among the home,home owners and utility server is developed to minimize cyber-attacks.     

TRPA1 Role in Inflammatory Disorders: What Is Known So Far?

The transient receptor potential ankyrin 1 (TRPA1), a member of the TRP superfamily of channels, is primarily localized in a subpopulation of primary sensory neurons of the trigeminal, vagal, and dorsal root ganglia, where its activation mediates neurogenic inflammatory responses. TRPA1 expression in resident tissue cells, inflammatory, and immune cells, through the indirect modulation of a large series of intracellular pathways, orchestrates a range of cellular processes, such as cytokine production, cell differentiation, and cytotoxicity. Therefore, the TRPA1 pathway has been proposed as a protective mechanism to detect and respond to harmful agents in various pathological conditions, including several inflammatory diseases. Specific attention has been paid to TRPA1 contribution to the transition of inflammation and immune responses from an early defensive response to a chronic pathological condition. In this view, TRPA1 antagonists may be regarded as beneficial tools for the treatment of inflammatory conditions.     

Biocompatibility and Mechanical Stability of Nanopatterned Titanium Films on Stainless Steel Vascular Stents

Nanoporous ceramic coatings such as titania are promoted to produce drug-free cardiovascular stents with a low risk of in-stent restenosis (ISR) because of their selectivity towards vascular cell proliferation. The brittle coatings applied on stents are prone to cracking because they are subjected to plastic deformation during implantation. This study aims to overcome this problem by using a unique process without refraining from biocompatibility. Accordingly, a titanium film with 1 µm thickness was deposited on 316 LVM stainless-steel sheets using magnetron sputtering. Then, the samples were anodized to produce nanoporous oxide. The nanoporous oxide was removed by ultrasonication, leaving an approximately 500 nm metallic titanium layer with a nanopatterned surface. XPS studies revealed the presence of a 5 nm-thick TiO₂ surface layer with a trace amount of fluorinated titanium on nanopatterned surfaces. Oxygen plasma treatment of the nanopatterned surface produced an additional 5 nm-thick fluoride-free oxide layer. The samples did not exhibit any cracking or spallation during plastic deformation. Cell viability studies showed that nanopatterned surfaces stimulate endothelial cell proliferation while reducing the proliferation of smooth muscle cells. Plasma treatment further accelerated the proliferation of endothelial cells. Activation of blood platelets did not occur on oxygen plasma-treated, fluoride-free nanopatterned surfaces. The presented surface treatment method can also be applied to other stent materials such as CoCr, nitinol, and orthopedic implants.     

Electrolyte/Structure?Dependent Cocktail Mediation Enabling High?Rate/Low?Plateau Metal Sulfide Anodes for Sodium Storage

As promising anodes for sodium-ion batteries, metal sulfides ubiquitously suffer from low-rate and high-plateau issues, greatly hindering their application in f...     

Efficiency of an Otto engine under alternative power optimizations

The proper optimization criterion to be chosen for the optimum design of the heat engines may differ depending on their purposes and working conditions. In this study, a comparative performance analysis is carried out for a reversible Otto cycle based on three alternative performance criteria namely maximum power (mp), maximum power density (mpd) and maximum efficient power (mep). The power density criterion is defined as the power per minimum specific volume in the cycle and the efficient power criterion is defined as multiplication of the power by the efficiency of the Otto cycle. Maximizing the efficient power gives a compromise between power and efficiency. Three different objective functions are defined and maximization of these functions is carried out under different design parameters of the Otto engine. The variations of power, power density and efficient power outputs are derived and presented with respect to the thermal efficiency of the cycle for various temperature ratios. It has been found that the design parameters at mep conditions lead to more efficient engines than that at the mp condition and the mep criterion may have a significant power advantage compared with mpd criterion. Copyright © 2009 John Wiley & Sons, Ltd.     

Ring Opening of Epoxidized Soybean Oil with Compounds Containing Two Different Functional Groups

Epoxidized vegetable oils are desirable chemicals due to their eco‐friendly characteristics and their being a major source of many green products. Ring opening is one of the ways to convert these epoxidized oils to some new intermediates. The use of mono‐functional amines, alcohols, acid anhydrides and thioethers for epoxy ring opening has been reported in the literature. In this study, thioglycolic acid (TGA) bearing thiol and carboxylic acid as two different functional groups and methyl ester of thioglycolic acid (TGAME) were used. Currently, there is no reported literature describing epoxy ring opening using chemicals bearing two different functional groups simultaneously. In this way, two new polyols were synthesized, one with TGA (polyol 1) and one with TGAME (polyol 2). FTIR and ¹H‐ and ¹³C‐NMR spectroscopy confirmed that the ring was opened by the carboxylic acid group of TGA, and the thiol group was not involved in the ring opening whereas the ring was opened by the thiol group in the case of TGAME.