Comparison of the effects of multiple injection strategy on the emissions between moderate and heavy EGR rate conditions: part 2-post injections

To draw a comparison of the effect of multiple injection strategy on the engine-out emissions under two different EGR rate conditions, the effect of pilot injection on emissions and combustion was evaluated and discussed in part 1. Thus, in the second research as part 2, the effects of post injection on the engine-out emissions were systemically evaluated for two different EGR rate conditions (30 % and 60 %). Since the behavior of diesel combustion is significantly different as EGR rate is changed, the characteristics of post injection was different between two EGR rate conditions. This research was investigated as varying injection parameters such as the timing and quantity of the post injection. The results show that the close post injection with injection interval as 10 degree has the potential to reduce PM emission, regardless of EGR rate. However, the reason of reduction of PM emission is different for each case. For a moderate EGR rate condition, close post injection with interval 10 degree enhances the fuel at bottom of bowl. Thus, the distribution of fuel can be improved. On the other hand, for a heavy EGR rate condition, close post injection with interval 10 degree has the charge cooling effect to prolong the ignition delay, rather than well-matched injection targeting. Especially, there is an effect to oxidize PM emission under moderate EGR rate condition as post injection is applied. However, post injection for late cycle of combustion under heavy EGR rate condition does not oxidize PM emission due to low oxygen concentration (～ 10%).     

Convex hull-based velocity transmission capability of parallel manipulators

This paper presents a convex hull-based velocity transmission capability analysis of parallel manipulators (PMs) for more accurate design and performance evaluation of PMs. The velocity transmission capability analysis based on the manipulability ellipsoid does not provide accurate information on how fast a PM can move along an arbitrary direction since the joint velocities are normalized by the two-norm (≤?1). Therefore, for an accurate velocity transmission capability, a computationally efficient convex hull-based approach is proposed here using minimum infinity-norm solutions. Due to the calculation complexity and the dimensional inconsistency, the velocity transmission capability was analyzed separately for the translational and rotational velocity convex hulls. Moreover, for quantitative measures of the translational and rotational velocities, three performance indices (PI), i.e., local, global, and weighted PI, are proposed to visualize dexterousness of PMs. The proposed method is applied to a general 6 degrees of freedom PM to show the effectiveness of the proposed approach.     

Rotordynamic analysis and experimental validation of a high speed induction motor made by copper die casting process

A copper die casting induction motor can obtain an energy saving effect of about 2–3% compared to previous aluminum die casing induction motors. In addition, copper die casting motors can reduce the size of motors and reduce material costs. The critical speed and unbalance response of high speed machines need to be verified by rotordynamic analysis for dynamic stability of the rotors. The critical speed analysis, harmonic analysis and transient analysis by unbalance are performed for dynamic stability. The unbalance analysis results are compared with the experiment considering allowable vibration displacement (API 611) and balancing grade (ISO 1940-1). This paper dealt with the design, analysis and experimental validation of a high speed induction motor. The dynamic stability of the prototype is verified successfully, and two experimental methods by ISO 10816-3 are suitable and reliable for the allowable vibration evaluation of rotating machine.     

Pre-annealing effect of electroless Ni−B deposit as a diffusion barrier for electroplated Cu electrodes

Ni−B film of 1 μm thickness was electrolessly deposited on an electroplated Cu bus electrode. The film, which encapsulates the Cu bus electrodes, prevents Cu oxidation and serves as a diffusion barrier against Cu contamination of the transparent dielectric layer in a plasma display during the firing process at 580 °C. The microstructure of theas-deposited barrier film was amorphous phase and crystallized to Ni and Ni₃B after annealing at 300 °C. The good barrier properties observed here can be explained by Ni₃B precipitates at the grain boundaries acting as a fast diffusion path via pre-annealing at 300 °C before the firing process at 580 °C.     

Oxidation Resistance Coating of LSM and LSCF on SOFC Metallic Interconnects by the Aerosol Deposition Process

Conductive La_0.8Sr_0.2MnO₃ (LSM) and La_0.6Sr_0.4Co_0.2Fe_0.8O₃ (LSCF) layers with a thickness of ∼10 μm were deposited on ferritic stainless steel (SS) by the aerosol deposition method, for use as an oxidation resistance-coating layer in the metallic interconnector of a solid oxide fuel cell. The coated layers were fairly dense without pores or cracks, and maintained good adhesion even after oxidation at 800°C for 100 h. The surface of the bare SS after annealing at 800°C for 100 h was covered with Cr₂O₃ and Fe₃O₄ oxide scales, and the electrical conductivity was sharply decreased. However, the LSM- and LSCF-coated SSs showed a surface microstructure with almost no oxidation and maintained good electrical conductivity after annealing at 800°C for 100 h. The area-specific resistance (ASR) of LSM- and LSCF-coated alloys after 100 h of oxidation at 800°C was 20.6 and 11.7 mΩ·cm², respectively.     

Enhancing textile ink-jet printing with chitosan

Following on from previous research, the possibility of using chitosan in preparing the pretreatment print paste for textile ink-jet printing was investigated but the final colour was not as good as expected. In this study, chitosan was applied separately on cotton fabric for ink-jet printing. A two-bath method was proposed and it was confirmed that a better colour yield was achieved with this method. However, the use of chitosan reduced the tensile strength of the ink-jet printed fabric slightly.     

First dicadmium(II) complex of tripodal amide ligand with one edge-sharing monocapped octahedral geometry

A new dicadmium(II) complex [Cd₂(L)₂(H₂O)₂](NO₃)₄ · 8H₂O (1) with the tripodal amide ligand L (tris[3-aza-2-oxo-4-(2-pyridyl)butyl]amine) was synthesized and structurally characterized. Complex 1 is revealed as a dinuclear 2:2 (Cd:L) complex, in which each cadmium(II) ion is hepta-coordinated with the coordination surrounding of distorted monocapped octahedral geometry. Two cadmium(II) ions are dibridged by two carbonyl μ-O atoms forming a Cd₂(μ-O)₂ parallelogram-type moiety. Interestingly, the dinuclear coordination sphere can be seen as resulting from the fusion of two distorted monocapped octahedral [Cd(L)(H₂O)]²⁺ units through sharing one edge originated from the two carbonyl μ-O atoms as a first example. Comparative NMR, IR and FAB-mass data of 1 are also discussed.     

Polymer electrolytes based on poly(ethylene glycol) and cyanoresin

Polymer electrolytes based on a mixed polymer matrix consisting of poly(ethylene glycol) (PEG) and cyanoresins with lithium salt and plasticizer were prepared with an in situ blending process to improve both the mechanical properties and the ionic conductivity (σ). The PEG/lithium perchlorate (LiClO₄) complexes, including blends of cyanoethyl pullulan (CRS) and cyanoethyl poly(vinyl alcohol) (CRV), exhibited higher σ's than a simple PEG/LiClO₄ complex when the blend compositions of CRS/CRV were 5 : 5 or 3 : 7 or than CRV alone. When the CRS/CRV blend was compared with a copolymer of cyanoethyl pullulan and cyanoethyl poly(vinyl alcohol) (CRM) in the same molar ratio, the σ values of the polymer electrolytes containing the CRM copolymer series were slightly higher than those of the CRS/CRV blends containing PEG/LiClO₄ complexes. Moreover, the addition of cyanoresin to PEG/LiClO₄/(ethylene carbonate–propylene carbonate) polymer electrolytes provided better thermal stability and dynamic mechanical properties. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2402–2408, 2007     

Sulfonated polyimide and poly (ethylene glycol) diacrylate based semi‐interpenetrating polymer network membranes for fuel cells

Semi‐interpenetrating polymer network (semi‐IPN) membranes based on novel sulfonated polyimide (SPI) and poly (ethylene glycol) diacrylate (PEGDA) have been prepared for the fuel cell applications. SPI was synthesized from 1,4,5,8‐naphthalenetetracarboxylic dianhydride, 4,4′‐diaminobiphenyl 2,2′‐disulfonic acid, and 2‐bis [4‐(4‐aminophenoxy) phenyl] hexafluoropropane. PEGDA was polymerized in the presence of SPI to synthesize semi‐IPN membranes of different ionic contents. These membranes were characterized by determining, ion exchange capacity, water uptake, water stability, proton conductivity, and thermal stability. The proton conductivity of the membranes increased with increasing PEGDA content in the order of 10^?1 S cm^?1 at 90°C. These interpenetrating network membranes showed higher water stability than the pure acid polyimide membrane. This study shows that semi‐IPN SPI membranes based on PEGDA which gives hydrophilic group and structural stability can be available candidates comparable to Nafion® 117 over 70°C. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007