A Gas-Recirculation Control System in a Battery of Fuel Cells

Currently, power plants based on hydrogen—oxygen fuel cells are widely used. The advantages of such electrochemical generators are environmental friendliness, efficiency, and a wide power-output range. Some components of such engines are still being developed. One of these components is the working gasrecirculation system, which increases the efficiency of an installation. In addition, this system helps support the water balance in a fuel-cell stack by removing the water that occurs in the cavities of the membrane—electrode block as a result of the electrochemical reaction. With consideration of the complexity of the reactions that occur in an installation, an automatic control system (ACS) is necessary for the gas recirculation system. This article deals with the organization of an automatic control system based on a microprocessor controller, sensors, and actuators, which implements control algorithms for the components of the gas recirculation system.     

High Temperature Oxidation Behavior of Conventional and Nb-Modified MAR-M246 Ni-Based Superalloy

The present investigations focused on the thermal oxidation of two variants of MAR-M246 alloy having the same contents of Ta and Nb in at. pct, considering the effects of total replacement of Ta by Nb. The alloys were produced by investment casting using high purity elements in induction furnace under vacuum atmosphere. The alloys were oxidized pseudo-isothermally at 800 °C, 900 °C and 1000 °C up to 1000 hours under lab air. Protective oxidation products growing on the surface of the oxidized samples were mainly Al₂O₃, Cr₂O₃. Other less protective oxide such as spinels (NiCr₂O₄ and CoCr₂O₄) and TiO₂ were also detected as oxidation products. The conventional alloy exhibited slight internal oxidation at 800 °C and an enhanced resistance at 900 °C and 1000 °C. The Nb-modified alloy presented an exacerbated internal oxidation and nitridation at 900 °C and 1000 °C and an enhanced resistance at 800 °C. At 1000 °C, Nb-modified alloy was particularly affected by excessive spalling as the main damage mechanisms. From a kinetic point of view, both alloys exhibit the same behavior at 800 °C and 900 °C, with k_p values typical of alumina forming alloys (2 × 10⁻¹⁴ to 3.6 × 10⁻¹³ g² cm⁻⁴ s⁻¹). However, Ta modified alloys exhibited superior oxidation resistance at 1000 °C when compared to the Nb modified alloy due to better adherence of the protective oxide scale.

     

Plastic Deformation Resistance of Steel Grades EP450-Sh and EP823-Sh in Hot and Cold State

Metallurgist - The article presents the results of plastometric studies on hot deformation and studies on the hardening curves in cold deformation of EP450-Sh (12H12M1BFR-Sh) and EP823-Sh...     

Effect of Conditions of High-Temperature Treatment on the Structure and Tribological Properties of Nickel-Based Laser-Clad Coating

Russian Journal of Non-Ferrous Metals - Laser cladding, which is characterized by the minimal thermal impact on the substrate, is an advanced technique to restore the working dimensions of parts...     

Microdistortions,Hardness, and Young’s Modulus of Multicomponent Bcc Solid Solutions

Powder Metallurgy and Metal Ceramics - The phase composition, type II microstresses, and coherent scattering domains (CSDs) of multicomponent (medium- and high-entropy) bcc solid solutions with an...     

The Influence of Hydrogen Concentration in an Ar–H2 Mixture on the Electrical Properties of Solid Oxide Fuel Cells

Powder Metallurgy and Metal Ceramics - Fuel cells are today among the most efficient and environmentally friendly devices for the production of electricity. They are developing rapidly and are...     

Lead and cadmium in teeth,bone and kidneys of rats with a standard Pb‐Cd supply

Male Wistar rats received a combination of 25 ppm PbCl₂ and 5 ppm CdCl₂ in drinking water at different developmental stages. Pb and Cd levels of incisors, molars, epiphyses, diaphyses and kidney cortex were recorded by atomic absorption spectrophotometry. The results confirmed that Pb has an affinity for hard tissue and especially to teeth, but it also accumulated in soft tissues under the above conditions. In addition, the results indicated none or only a moderate placental or mammary barrier for Pb, and suggested a high absorption of lead from the intestine of sucklings. The results also confirmed that kidney cortex is a primary target for Cd, and indicated that Cd has crossed the placental and mammary barriers to some degree. The positive significant correlation between Cd levels in molars and kidney cortex suggested that rodent molars indicate a degree of Cd absorption, whereas incisors do not. It is supposed that rodent molars are comparable to human deciduous teeth. It is thus confirmed that human deciduous teeth indicate previous lead exposure. It is further inferred that they also can be used as indicators of previous Cd‐exposures.     

Removal of Lissamine Red From Wastewater Using Waste Materials

Feasibility of a waste material, flyash, as a material for purification of wastewater containing Lissamine Red has been studied. Effects of time and concentration, temperature and pH on the removal of the dye have been studied. Lower concentrations favour the uptake of dye from water and the maximum removal was observed at a dye concentration of 20 mgL m 1 , 30°C, pH of 7 and adsorbent particle size of 53 µm. Dynamics of the uptake was studied using Lagergren's equation. The mass transfer coefficient was found to be 0.05 cmmin m 1 at a concentration of 20 mgL m 1 , 30°C and 53 µm particle size.     

Environmental studies on impacts of dredging

The coastal zone acts as a major interface between the ocean and continents. Harbours located in this zone face grave problems from sedimentation, which is a global issue for most of the harbours of the world. Dredging which counter acts sedimentation, brings about innumerable environmental impacts — both positive and negative. As a case study, this paper reports the impacts of dredging conducted at Cochin harbour which is the second largest port along the west coast of India; this port is a nodal center in trade and commerce connecting south east Asia to European sector. The harbour operation mainly depends on maintenance form of dredging bringing about impacts which have both direct and indirect effects in the long term. The important parameters selected for this study are salinity, current, extinction coefficient, turbidity, nutrients, chlorophyll and bottom fauna. An assessment is made on both positive and negative impacts which indicate rise in turbidity, changes in nutrient content and biota. The current practice on dredging is conducive to harbour operations, regulating the material made available to the near shore areas and highlights the possible venues for utilization of spoil for reclamation of land and wetland development. A flow chart identifies the areas vulnerable to impacts arising out of dredging and its consequential environmental issues.     

Hydrocarbon stress response of four tropical plants in weathered crude oil contaminated soil in microcosms

Responses to hydrocarbon stress of four tropical plants Panicum maximum, Zea mays, Centrosema sp. and Pueraria sp. grown in crude oil contaminated soils (1%, 5% and 10% w/w) were evaluated in a green house. Plants’ percentage survival, shoot heights, biomass development, and phytotoxicity susceptibility were used as indicators of growth, stress response and hydrocarbon tolerance. Relative to control, shoot heights and biomass of plants reduced with increasing hydrocarbon concentration, but 1% w/w oil-in-soil, stimulated shoot heights (5.9% and 6.4%) and weights (21.9% and 2.3%) in P. maximum and Centrosema sp. respectively. P. maximum tolerated the contaminant stress with biomass yields of 113% and 57% of control respectively in 1% and 10% w/w oil-in-soil. All the plants had 100% survival in 1% w/w, but considerably reduced survival in 10% w/w oil-in-soil. These results show that P. maximum has great potential for phytoremediation of petroleum contaminated soil.