Supply amount and marginal price of renewable electricity under the renewables portfolio standard in Japan

The Renewables Portfolio Standard (RPS) in Japan requires that approximately 1.35% of each retail supplier's electricity sales in FY2010 come from renewable energy sources (RES), for example, photovoltaics, wind, biomass, geothermal, and small hydropower. To help retail suppliers and renewable generators develop effective strategies, this study provides a quantitative analysis of the impact of this measure. We assume the supply conditions for electricity generation from renewable energy sources (RES-E) based on regional resource endowments, and we derive the cost-effective compositions of renewable portfolios, RES-E certificate prices, and additional costs to retail suppliers. The future prospects of RES-E are assessed based on technology, region, and year up to FY2010. The analysis reveals that wind power and biomass power generated from municipal waste will provide the majority of the total supply of RES-E under the RPS. It also indicates that the marginal price of RES-E certificates will be approximately 5.8 JPY/kWh (5.2 USc/kWh) in FY2010, in the case wherein the marginal price of electricity is assumed to be 4 JPY/kWh (3.6 USc/kWh). In order to elaborate on this further, sensitivity analyses for some parameters of RES and the price of electricity are provided. The dynamic supply curves of RES-E certificates are also indicated.     

Internal curing of Class-F fly-ash concrete using high-volume roof-tile waste aggregate

The aim of this study was to investigate the effect of a high volume of roof-tile waste coarse aggregate (5–13 mm) as an internal curing agent on the compressive strength, modulus of elasticity, pore structure, and hydration and pozzolanic reactions in paste of fly-ash concrete with a low water-to-binder ratio of 0.30. The fly-ash concrete specimens in which the replacement ratio of cement by Class-F fly ash was 40% by mass and that of normal coarse aggregate by roof-tile waste aggregate was 40% by volume, were cured up to 728 days. Internal curing with roof-tile waste aggregate increased the compressive strength of the fly-ash concrete by 8.4–16.5% and decreased the modulus of elasticity by 4.9–12.8%. The use of a high volume of waste aggregate decreased the volume of the capillary pores in the 0.01–10 µm range and the volume proportion of the 0.02–0.33-µm pores after 28 days, but increased the volume proportion of 0.003–0.02-µm pores slightly at 7 days and significantly up to 728 days, and the consumption of Ca(OH)₂ in the fly-ash concrete. This roof-tile waste aggregate can be used as an internal water reservoir to increase the compressive strength and to improve the pore structure of concrete with a high-volume (40%) replacement of Class-F fly ash.     

Involvement of Autophagy in Rat Tail Static Compression-Induced Intervertebral Disc Degeneration and Notochordal Cell Disappearance

The intervertebral disc is the largest avascular low-nutrient organ in the body. Thus, resident cells may utilize autophagy, a stress-response survival mechanism, by self-digesting and recycling damaged components. Our objective was to elucidate the involvement of autophagy in rat experimental disc degeneration. In vitro, the comparison between human and rat disc nucleus pulposus (NP) and annulus fibrosus (AF) cells found increased autophagic flux under serum deprivation rather in humans than in rats and in NP cells than in AF cells of rats (n = 6). In vivo, time-course Western blotting showed more distinct basal autophagy in rat tail disc NP tissues than in AF tissues; however, both decreased under sustained static compression (n = 24). Then, immunohistochemistry displayed abundant autophagy-related protein expression in large vacuolated disc NP notochordal cells of sham rats. Under temporary static compression (n = 18), multi-color immunofluorescence further identified rapidly decreased brachyury-positive notochordal cells with robust expression of autophagic microtubule-associated protein 1 light chain 3 (LC3) and transiently increased brachyury-negative non-notochordal cells with weaker LC3 expression. Notably, terminal deoxynucleotidyl transferase dUTP nick end labeling-positive apoptotic death was predominant in brachyury-negative non-notochordal cells. Based on the observed notochordal cell autophagy impairment and non-notochordal cell apoptosis induction under unphysiological mechanical loading, further investigation is warranted to clarify possible autophagy-induced protection against notochordal cell disappearance, the earliest sign of disc degeneration, through limiting apoptosis.     

Inhibition of Autophagy at Different Stages by ATG5 Knockdown and Chloroquine Supplementation Enhances Consistent Human Disc Cellular Apoptosis and Senescence Induction rather than Extracellular Matrix Catabolism

The intervertebral disc is the largest avascular organ. Autophagy is an important cell survival mechanism by self-digestion and recycling damaged components under stress, primarily nutrient deprivation. Resident cells would utilize autophagy to cope with the harsh disc environment. Our objective was to elucidate the roles of human disc cellular autophagy. In human disc cells, serum deprivation and pro-inflammatory interleukin-1β (IL-1β) stimulation increased autophagy marker microtubule-associated protein 1 light chain 3 (LC3)-II and decreased autophagy substrate p62/sequestosome 1 (p62/SQSTM1), indicating enhanced autophagy. Then, RNA interference (RNAi) of autophagy-related gene 5 (ATG5), essential for autophagy, showed decreases in ATG5 protein (26.8%–27.4%, p < 0.0001), which suppressed early-stage autophagy with decreased LC3-II and increased p62/SQSTM1. Cell viability was maintained by ATG5 RNAi in serum-supplemented media (95.5%, p = 0.28) but reduced in serum-free media (80.4%, p = 0.0013) with IL-1β (69.9%, p = 0.0008). Moreover, ATG5 RNAi accelerated IL-1β-induced changes in apoptosis and senescence. Meanwhile, ATG5 RNAi unaffected IL-1β-induced catabolic matrix metalloproteinase release, down-regulated anabolic gene expression, and mitogen-activated protein kinase pathway activation. Lysosomotropic chloroquine supplementation presented late-stage autophagy inhibition with apoptosis and senescence induction, while catabolic enzyme production was modest. Disc-tissue analysis detected age-related changes in ATG5, LC3-II, and p62/SQSTM1. In summary, autophagy protects against human disc cellular apoptosis and senescence rather than extracellular matrix catabolism.     

Bandgap and exciton binding energies in lead-iodide-based natural quantum-well crystals

We have performed optical absorption and electroabsorption studies on the lead-iodide-based natural quantum-well perovskite-type crystals with different well width (C₆H₁₃NH₃)₂(CH₃NH₃)_m−1Pb_mI_3m+1. With decreasing well thickness, m, the resonance energies of the lowest-energy excitons shift to higher energy due to the increase of the bandgap. The binding energies and oscillator strengths of the excitons drastically increase due to the spatial confinement and image charge effect with decreasing m. The bandgap of (C₆H₁₃NH₃)₂(CH₃NH₃)_m−1Pb_mI_3m+1 (m≥2) can be reproduced by the effective-mass approximations, while the effective-mass approach is not valid for (C₆H₁₃NH₃)₂PbI₄ (m=1).     

Control of turbulent channel flow over a backward‐facing step by suction or injection

Experiments have been performed for turbulent channel flow over a backward‐facing step. The backward‐facing step is controlled by equipping a slit at the bottom corner of the step. Low momentum fluids in the recirculation region are sucked or high momentum fluids are injected from the slit. The width of the slit is changed between 2, 3, and 5 mm, and the flow ratio is varied from 0.00 to 0.15. The wall static pressure and local heat transfer coefficient are measured behind the backward‐facing step. The wall shear stress is measured using a micro flow sensor. In addition, the velocity profiles and turbulent intensities are measured by a split hot film probe. It is found that the heat transfer and pressure drop characteristics are controlled by the flow ratio. When the suction flow ratio is 0.06, the highest performance is obtained. Enhancement of the heat transfer is related to the increase of turbulence intensity. © 2004 Wiley Periodicals, Inc. Heat Trans Asian Res, 33(8): 490–504, 2004; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20036     

Preparation of copoly(vinyl alcohol–styrenesulfonic acid) resin and its catalytic activity on hydrolysis of carbohydrates. IV. Hydrolysis of dextrin in mixtures of organic solvents with water

The reaction rates of dextrin hydrolysis in the presence of copoly(vinyl alcohol–styrenesulfonic acid) resin in mixtures of dimethyl sulfoxide and dioxane with water were measured and compared with those in the presence of Amberlite 120B. In the case of Amberlite 120B the second-order rate constant, κ₂, of the reaction decreased continuously with increasing vol % of the organic solvents, whereas in the case of the copolymer resin it passed a minimum and increased again at the higher vol % range. The influence of blocking of the hydroxyl groups in the copolymer resin by formalization on the catalysis was investigated. The increase in κ₂ in the higher vol % range of the organic solvent was suppressed with the blocking, and the interactions between hydroxyl groups in the substrate and the copolymer resin was confirmed to play an important role for the increase in the κ₂ in the higher vol % range of the organic solvents. Temperature dependence of κ₂ was also examined, and the increase in κ₂ in the higher vol % range of the organic solvents was found to be due to pronounced decreases in enthalpy of activation, suggesting that the increase might be resulted from the enhancement of interactions between the substrate and the catalytic copolymer resin.     

Grafted chain as spacer for an insoluble polymer ligand. II. Two-step polymerization using tetraethylthiuram disulfide as an initiator

In order to increase the percent grafting in the graft polymerization of chloromethylstyrene onto a crosslinked polystyrene bead with UV light irradiation, a two-step polymerization consisting of a suspension polymerization of styrene containing divinylbenzene using tetraethylthiuram disulfide as an initiator and then a subsequent graft polymerization of chloromethyl-styrene onto the crosslinked polystyrene bead was carried out. The percent grafting of up to 180% was obtained, the value being about twofold larger than that for the usual method using benzoyl peroxide as an initiator. The higher percent grafting was found to result from the higher grafting efficiency due to the preferential decomposition of diethyldithiocarbamate group in the crosslinked polystyrene bead with UV light irradiation. The chloromethyl group in the grafted chain was converted to aminomethyl group, and then to the iminodiacetic acid group, which was a ligand group. The adsorption behavior of Cu(II) by the ligand polymer and the catalytic activity of the complex in the decomposition of hydrogen peroxide were examined, and both properties were found to be improved by introducing grafted chain as spacer, especially markedly at a higher percent grafting.