Synthesis of amphiphilic magnetic microspheres by dispersion copolymerization of styrene and poly(ethylene oxide) macromonomer

Amphiphilic magnetic microspheres ranging in diameter from 5 to 100 µm were prepared by dispersion copolymerization of styrene and poly(ethylene oxide) vinylbenzyl (PEO‐VB) macromonomer (MPEO) in the presence of Fe₃O₄ magnetic fluid. The effects of various polymerization parameters on the average particle size were systematically investigated. The average particle size was found to increase with increasing styrene concentration and initiator concentration. It also increased with decreasing stabilizer concentration and molecular weight of MPEO. The content of the hydroxyl groups localized in the microspheres ranged from 0.01 to 0.2 mmol g^?1. © 2003 Society of Chemical Industry     

射频电缆组件组装工艺浅谈

近年来国内外射频电缆组件的发展很快,射频电缆组件的性能不断提高,对射频电缆组件组装工艺也提出了更高的要求.射频电缆组件组装过程多是手工操作,产品的一致性及性能很难控制,要求有良好的工艺保证,为此介绍了射频电缆组件组装工艺,包括电缆的裁剪及剥皮、内导体的连接、外导体的连接和电气性能的测试;探讨了在组装过程中应注意的问题,以及针对内导体焊接易出现虚焊问题进行研究.     

Goppa geometric codes achieving the Gilbert-Varshamov bound

Based on s-zeta-functions of curves over finite fields, we show that Goppa geometry codes achieve the q-ary Gilbert-Varshamov bound for all prime powers q (including q=2)     

PVC树脂聚合用有机过氧化物引发剂

介绍了目前国内外引发剂的使用及开发方向,并对引发剂的选择及其对树脂质量的影响进行了讨论。     

Effect of dual-scale microstructure on the toughness of laminar zirconia composites

Numerical study by the finite element method (FEM) is performed to investigate the effect of dual-scale microstructure on the toughness of laminar zirconia composite. The computation is based on the micromechanics constitutive model of polycrystal transformation plasticity developed by Sun et al. [10] where both transformation induced shear and softening effects during autocatalytic transformation are taken into account. The numerical simulation presented in this paper successfully reproduced the experimentally observed two effects of the dual-scale microstructure on the toughness of laminar zirconia composite, i.e., the truncation of the elongated transformation frontal zone that forms in single phase Ce-ZrO₂ and the propagation of the transformation zone along the layers normal to the crack plane. Quantitative analysis on the role of microstructure in transformation toughening of laminar zirconia composite is first carried out in the present work which will provide a starting point for the microstructural design of this novel advanced composite in the future.Presented at the Far East Fracture Group (FEFG) International Symposium on Fracture and Strength of Solids. 4–7 July 1994 in Xi'an, China.     

无机膜的应用与展望

本文综述了无机膜的发展、制备方法和应用。     

压电类智能层合结构的力学和计算模型综述

综述了压电类智能层合结构的力学和计算模型。基于大量国内外有关压电类智能层合结构的文献 ,根据各自采用的运动学假设、场变量的近似、压电层的表达法以及曲率和温度的影响 ,对压电层合结构的力学和计算模型进行了分类 ,阐述了各种理论的特点及一般形式。     

Comparison of Markov model and fault tree approach in determining initiating event frequency for systems with two train configurations

This study explores the use of Markov models in some areas of systems analysis in which time evolution of the system may be a significant factor in influencing the system reliability or availability. Comparisons are made between the Markov models and the time-averaged fault tree models for determining support system failure initiating event frequency in a nuclear power plant, for both power and shutdown conditions. Factors affecting consistency between the fault tree approach and the Markov model approach are studied for systems with common two train configurations. A correlation is developed to estimate the ratio between initiator frequencies through both approaches for a two parallel component system. Insights are developed as to when time averaged and simplified fault tree models support a good approximation to the more rigorous time-dependent Markov models.     

负载化非茂单活性中心催化剂乙烯聚合的研究

在硅胶上负载了双(N-环己基-3-叔丁基水杨醛亚胺基)二氯化锆配合物,得到负载化非茂单活性中心催化剂。该催化剂用于乙烯聚合,考察了配合物用量、共聚单体1-己烯用量、聚合温度、聚合压力、聚合时间、三乙基铝用量对乙烯聚合性能的影响及对聚合物的相对分子质量、相对分子质量分布、熔体流动指数和密度的影响。实验结果表明,负载化非茂单活性中心催化剂保持了原均相催化剂的乙烯聚合性能;该催化剂在淤浆聚合工艺中聚合平稳,所得聚合物的颗粒形态良好。     

离子液体用于燃料油深度脱硫的研究进展

首先介绍了加氢催化脱硫和其他脱硫技术的特点,综述了近年来国内外利用离子液体在萃取脱硫、萃取脱硫与氧化脱硫耦合、萃取脱硫与生物脱硫耦合等方面的研究。认为离子液体萃取脱硫具有操作简便、可循环使用、无需氢气、环境友好、能深度脱硫等特点,是一项具有广阔发展前景的技术。若要实现该技术的工业化应用,还需进一步加强离子液体在合成工艺、脱硫选择性及回收再生等方面的研究。