The kinetics of interactions between fecapentaene-12 and DNA

Fecapentaene-12 (Fp-12) is a potent colon cancer mutagen, which interacts with DNA. In this study, the kinetics of its interactions with DNA is investigated. Various pHs are used. Three first-order rates are observed at each pH. This suggests that interaction between Fp-12 and DNA occurs through three different mechanisms.     

A Facile Approach to Chemically Modified Graphene and its Polymer Nanocomposites

A scalable approach for the mass production of chemically modified graphene has yet to be developed, which holds the key to the large‐scale production of stable graphene colloids for optical electronics, energy conversion, and storage materials, catalysis, sensors, composites, etc. Here, a facile approach to fabricating covalently modified graphene and its polymer nanocomposites is presented. The method involves: i) employing a common furnace, rather than a furnace installed with a quartz tube and operated in inert gas as required in previous studies, to treat a commercial graphite intercalation compound with thermal shocking and ultrasonication and fabricate graphene platelets (GnPs) with a thickness of 2.51 ± 0.39 nm that contain only 7 at% oxygen; ii) grafting these GnPs with a commercial, long‐chain surfactant, which is able to create molecular entanglement with polymer matrixes by taking advantage of the reactions between the epoxide groups of the platelets and the end amine groups of the surfactant, to produce chemically modified graphene platelets (m‐ GnPs); and iii) solution‐mixing m‐GnPs with a commonly used polymer to fabricate nanocomposites. These m‐GnPs are well dispersed in a polymer with highly improved mechanical properties and a low percolation threshold of electrical conductivity at 0.25 vol%. This novel approach could lead to the future scalable production of graphene and its nanocomposites.     

The effects of ruminally degraded protein on rumen fermentation and ammonia losses from manure in dairy cows

This experiment investigated the effect of dietary crude protein (CP) and ruminally degraded protein (RDP) levels on rumen fermentation, digestibility, ammonia emission from manure, and performance of lactating dairy cows. The experiment was a replicated 3 × 3 Latin square design with 6 cows. Three diets varying in CP concentration were tested (CP, % of dry matter): 15.4 (high CP, control), 13.4 (medium CP), and 12.9% (low CP). These diets provided metabolizable protein balances of 323, −44, and 40 g/d and RDP balances of 162, −326, and −636 g/d (high, medium, and low, respectively). Both the medium and low CP diets decreased ruminal pH compared with high CP, most likely because of the higher nonfiber carbohydrate concentration in the former diets. Ruminal ammonia pool size (rumen ammonia N was labeled with ¹⁵N) and the concentration of total free amino acids were greater for the high CP diet than for the RDP-deficient diets. Apparent total-tract nutrient digestibilities were not affected by treatment. Both the medium and low CP diets resulted in lower absolute and relative excretion of urinary N compared with the high CP diet, as a proportion of N intake. Excretion of fecal N and milk yield and composition were not affected by diet. Milk N efficiency (milk N ÷ N intake) and the cumulative secretion of ammonia-¹⁵N in milk protein were greater for the RDP-deficient diets, and milk urea N concentration was greater for the high CP diet. Both medium and low CP diets decreased the irreversible loss of ruminal ammonia N compared with the high CP diet. The rate and cumulative ammonia emissions from manure were lower for the medium and low CP diets compared with the high CP diet. Overall, this study demonstrated that dairy diets with reduced CP and RDP concentrations will produce manure with lower ammonia-emitting potential without affecting cow performance, if metabolizable protein requirements are met.     

Interactive instabilities of thin‐walled laminated composite pultrusion box columns

The problem of interactive buckling and post‐buckling of intermediate length thin‐walled columns built of laminated plate elements subjected to compressive load has been proposed and solved analytically. Pultrusion columns have wide‐range applications in high‐rise building due to their low weight and high load carrying capacity. Classic stability theory and laminate theory were implemented to prove the existence of mixed‐mode buckling in thin‐walled pultrusion columns. Interactive stability modes can result in lower loading capacity of most compressive members and affects their post‐buckling behaviour in major proportions. Interactive buckling load analysis has been performed by means of a simplified theoretical model and verified by means of numerical analysis. The calculations were carried out for commonly used square section thin‐walled composite columns dimensions. The post‐buckling performance of selected sections has been investigated and an optimum layup configuration criterion for each section has been extracted according to pre‐ and post‐critical behaviour. Copyright © 2010 John Wiley & Sons, Ltd.     

Culture, cross-role consistency, and adjustment: Testing trait and cultural psychology perspectives.

Trait and cultural psychology perspectives on cross-role consistency and its relation to adjustment were examined in 2 individualistic cultures, the United States (N = 231) and Australia (N = 195), and 4 collectivistic cultures, Mexico (N = 199), the Philippines (N = 195), Malaysia (N = 217), and Japan (N = 180). Cross-role consistency in trait ratings was evident in all cultures, supporting trait perspectives. Cultural comparisons of mean consistency provided support for cultural psychology perspectives as applied to East Asian cultures (i.e., Japan) but not collectivistic cultures more generally. Some but not all of the hypothesized predictors of consistency were supported across cultures. Cross-role consistency predicted aspects of adjustment in all cultures, but prediction was most reliable in the U.S. sample and weakest in the Japanese sample. Alternative constructs proposed by cultural psychologists-personality coherence, social appraisal, and relationship harmony-predicted adjustment in all cultures but were not, as hypothesized, better predictors of adjustment in collectivistic cultures than in individualistic cultures. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Thermal behaviour and crystallization analysis of ethylene-propylene (EP) copolymer and EP-styrene terpolymer

Polyolefin copolymers have been an important commercial product since their invention. Hence, it is crucial to study their co- and terpolymers due to their extensive use. In this paper, in situ synthesis of ethylene-propylene (EP) copolymer, its terpolymer with styrene, and composites with nickel-chromium (NiCr) layered double hydroxide (LDH) has been reported along with their thermal properties. Styrene had a significant impact on the activity, increasing the yield by 195% and 235% with an addition of 0.5 and 1.0 mL styrene, respectively, compared to neat EP. The crystallinity, melting temperature, and thermal stability decreased due to styrene; nevertheless, it performed better compared to a similar work of terpolymer where α-olefin was the third monomer. The incorporation of NiCr LDH as a drop-in filler during in situ polymerization affected adversely the thermal stability of the terpolymer. However, the ultrasonication treatment improved the thermal stability of the final product.     

DEICA: A differential evolution-based improved clustering algorithm for IoT-based heterogeneous wireless sensor networks

With the evolution of technology, many modern applications like habitat monitoring, environmental monitoring, disaster prediction and management, and telehealth care have been proposed on wireless sensor networks (WSNs) with Internet of Things (IoT) integration. However, the performance of these networks is restricted because of the various constraints imposed due to the participating sensor nodes, such as nonreplaceable limited power units, constrained computation, and limited storage. Power limitation is the most severe among these restrictions. Hence, the researchers have sought schemes enabling energy-efficient network operations as the most crucial issue. A metaheuristic clustering scheme is proposed here to address this problem, which employs the differential evolution (DE) technique as a tool. The proposed scheme achieves improved network performance via the formulation of load-balanced clusters, resulting in a more scalable and adaptable network. The proposed scheme considers multiple parameters such as nodes' energy level, degree, proximity, and population for suitable network partitioning. Through various simulation results and experimentation, it establishes its efficacy over state-of-the-art schemes in respect of load-balanced cluster formation, improved network lifetime, network resource utilization, and network throughput. The proposed scheme ensures up to 57.69%, 33.16%, and 57.74% gains in network lifetime, energy utilization, and data packet delivery under varying network configurations. Besides providing the quantitative analysis, a detailed statistical analysis has also been performed that describes the acceptability of the proposed scheme under different network configurations.     

Substituent Effect On Structure,Stability, and Electronic Properties of the Novel Bicyclic Silylenes at DFT

Silicon - The density functional theory (DFT) calculations are carried out to assay the effects of nitrogen atoms on the stability and reactivity of singlet (s) and triplet (t) forms of novel...     

Body landmark detection with an extremely small dataset using transfer learning

Pattern Analysis and Applications - We present a new landmark detection problem on the upper body of a clothed person for tailoring purposes. This is a landmark detection problem unknown in the...     

The role of carbon pricing in the relationship between air freight and environmental resource depletion: a case study of Saudi Arabia

Clean Technologies and Environmental Policy - The relationship between air freight and environmental resource depletion is a widely explored area in different economic settings. There, however, is...