Bioinspired flame retardant polymers of tyrosol

The enzyme catalyzed polymerization of flame retardant (FR) polymers from the renewable resource 2‐(4‐hydroxyphenyl) ethanol (HPE), commonly known as tyrosol, is presented. The synthesis is environmentally friendly and requires only monomer, peroxidase catalyst, dilute hydrogen peroxide, and deionized water. Phenolic polymers are produced in short, one pot, high yield reactions that require minimal purification. Fourier transform infrared spectroscopy and ¹H‐NMR analysis suggest the polymers are coupled through the 1, 2, 4, and 5 positions of the phenol ring and through the phenoxy substituent. Thermogravimetric analysis and pyrolysis combustion flow calorimeter show HPE homopolymers exhibit very low heat release rate and total heat release, while copolymerization with phenol increases already high char yields. Gel permeation chromatography reveals the molecular weight of the polymer increases with ethanol cosolvent concentration. The alcohol cosolvent also increases the proportion of oxyphenylene linkages to the detriment of FR properties. Preliminary quantitative structure–activity relationship toxicity modeling predicts the polymers are negative for developmental toxicity and Ames mutagenicity. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45394.     

Relay technologies and technical issues in IEEE 802.16j Mobile Multi-hop Relay (MMR) networks

An amendment to the 802.16e standard namely IEEE 802.16j specifying relay station (RS) and multi-hop relay base station (MR-BS) was approved in year 2006 supports Mobile Multi-hop Relay networks. (MMR). It provides coverage extension to isolated area and throughput enhancement by specifying relay stations. The physical (PHY) layer of WiMAX IEEE 802.16j standard is based on the IEEE 802.16-2004 and IEEE 802.16e-2005 standards and was designed from IEEE 802.11a. This paper reviews the Relay technologies and technical issues in the physical and MAC layer of IEEE 802.16j such as Data forwarding schemes frame structure, Link adaptation, modulation and coding, these issues belongs to physical layer, QoS scheduling services, Bandwidth allocation and request, Network planning, MAC handover procedures, connection management, path management, interference management, all these issues belongs to MAC layer.     

Classification of small lesions in dynamic breast MRI: eliminating the need for precise lesion segmentation through spatio-temporal analysis of contrast enhancement

Characterizing the dignity of breast lesions as benign or malignant is specifically difficult for small lesions; they do not exhibit typical characteristics of malignancy and are harder to segment since margins are harder to visualize. Previous attempts at using dynamic or morphologic criteria to classify small lesions (mean lesion diameter of about 1 cm) have not yielded satisfactory results. The goal of this work was to improve the classification performance in such small diagnostically challenging lesions while concurrently eliminating the need for precise lesion segmentation. To this end, we introduce a method for topological characterization of lesion enhancement patterns over time. Three Minkowski Functionals were extracted from all five post-contrast images of 60 annotated lesions on dynamic breast MRI exams. For each Minkowski Functional, topological features extracted from each post-contrast image of the lesions were combined into a high-dimensional texture feature vector. These feature vectors were classified in a machine learning task with support vector regression. For comparison, conventional Haralick texture features derived from gray-level co-occurrence matrices (GLCM) were used. A new method for extracting thresholded GLCM features was also introduced and investigated here. The best classification performance was observed with Minkowski Functionals area and perimeter, thresholded GLCM features f8 and f9, and conventional GLCM features f4 and f6. However, both Minkowski Functionals and thresholded GLCM achieved such results without lesion segmentation while the performance of GLCM features significantly deteriorated when lesions were not segmented ( $p<0.05$ ). This suggests that such advanced spatio-temporal characterization can improve the classification performance achieved in such small lesions, while simultaneously eliminating the need for precise segmentation.     

Depth-dependent anisotropies of amides and sugar in perpendicular and parallel sections of articular cartilage by Fourier transform infrared imaging

Full thickness blocks of canine humeral cartilage were microtomed into both perpendicular sections and a series of 100 parallel sections, each 6 μm thick. Fourier transform infrared (IR) imaging was used to image each tissue section eleven times under different IR polarizations (from 0° to 180° polarization states in 20° increments and with an additional 90° polarization), at a spatial resolution of 6.25 μm and a wavenumber step of 8 cm^?1. With increasing depth from the articular surface, amide anisotropies increased in the perpendicular sections and decreased in the parallel sections. Both types of tissue sectioning identified a 90° difference between amide I and amide II in the superficial zone (SZ) of cartilage. The fibrillar distribution in the parallel sections from the SZ was shown to not be random. Sugar had a weak but recognizable anisotropy in the upper part of the radial zone (RZ) in the perpendicular sections. The depth‐dependent anisotropic data were fitted with a theoretical equation that contained three signature parameters, which illustrate the arcade structure of collagens with the aid of a fibril model. Fourier‐transform IR imaging of both perpendicular and parallel sections provides the possibility of determining the three‐dimensional macromolecular structures in articular cartilage. Being sensitive to the orientation of the macromolecular structure in healthy articular cartilage aids the prospect of detecting the early onset of the tissue degradation that may lead to pathological conditions such as osteoarthritis. Microsc. Res. Tech. 74:122–132, 2011. © 2010 Wiley‐Liss, Inc.     

Experimental investigation on a DI diesel engine fuelled with Madhuca Indica ester and diesel blend

Biodiesel is a fatty acid alkyl ester, which is renewable, biodegradable and non-toxic fuel which can be derived from any vegetable oil by transesterification. One of the popularly used biodiesel in India is Mahua oil (Madhuca Indica). In the present investigation Mahua oil was transesterified using methanol in the presence of alkali catalyst and was used to study the performance and emission characteristics. The biodiesel was tested on a single cylinder, four stroke compression ignition engine. Engine performance tests showed that power loss was around 13% combined with 20% increase in fuel consumption with Mahua oil methyl ester at full load. Emissions such as carbon monoxide, hydrocarbon were lesser for Mahua ester compared to diesel by 26% and 20% respectively. Oxides of nitrogen were lesser by 4% for the ester compared to diesel.     

Crevice corrosion behaviour of superaustenitic stainless steels: Dynamic electrochemical impedance spectroscopy and atomic force microscopy studies

Potentiodynamic anodic polarisation and dynamic electrochemical impedance spectroscopic (DEIS) measurements were carried out for 316L SS, alloy 33 and alloy 24 in natural sea water in order to assess their crevice corrosion resistance. DEIS measurements were performed from open circuit potential to dissolution potential. It was shown that the impedance measurements in potentiodynamic conditions allow simultaneous investigation of changes in passive layer structure. The impedance spectra of various potential regions were also discussed. The surface morphology of the alloys after crevice corrosion studies were studied using optical microscope and atomic force microscopy (AFM).     

Effect of scanning speed, nozzle stand-off distance and beam scan-off distance on coating properties of laser surface alloyed 13Cr-4Ni steel

The present work describes an investigation of the effect of 3 different parameters of laser surface alloying—i.e., laser scanning speed (LSS), nozzle stand-off distance (NSOD) and laser beam scan-off distance (LBSOD) on coating height, depth and width. Nickel-based Colmonoy 88 alloy powder has been deposited on 13Cr-4Ni steel by single-step process of laser surface alloying. Laser power and powder feed rate were maintained at 3kW and 25 g/min, respectively. L8 orthogonal array has been designed to study these 3 parameters at 2 levels each. The results of single pass with extent of dilution, surface hardness and microstructures produced by different conditions are presented and discussed. For a specified NSOD and LBSOD, there was a decrease in coating height and depth with increase in LSS. Coating height and depth were not affected much by increase in NSOD. From the present investigation, optimized parameters were identified for enhanced hardness, minimum dilution and desired coating height and coating depth.     

应对高级嵌入式处理器系统调试挑战

FPGA最大的优点在于其灵活性，可激发设计人员创造出无数不同的设计。然而，设计调试通常最后才加以考虑——如果还加以考虑的话，因此调试器通常要适应系统的要求。