Synthesis of optical quality ZnO nanowires utilizing ultrasonic spray pyrolysis

ZnO nanowires were grown by an ultrasonic spray pyrolysis technique. The aspect ratio and size of the wire were dependent mainly on the pH value of a precursor solution and the growth temperature. By high-resolution transmission electron microscopic analysis and photoluminescence measurements, it was confirmed that the nanowires are monocrystalline with good optical quality.     

Near-infrared diode laser based spectroscopic detection of ammonia: a comparative study of photoacoustic and direct optical absorption methods

A photoacoustic spectroscopic (PAS) and a direct optical absorption spectroscopic (OAS) gas sensor, both using continuous-wave room-temperature diode lasers operating at 1531.8 nm, were compared on the basis of ammonia detection. Excellent linear correlation between the detector signals of the two systems was found. Although the physical properties and the mode of operation of both sensors were significantly different, their performances were found to be remarkably similar, with a sub-ppm level minimum detectable concentration of ammonia and a fast response time in the range of a few minutes.     

Design patterns for open tool integration

Design tool integration is a highly relevant area of software engineering that can greatly improve the efficiency of development processes. Design patterns have been widely recognized as important contributors to the success of software systems. This paper describes and compares two large-grain, architectural design patterns that solve specific design tool integration problems. Both patterns have been implemented and used in real-life engineering processes.     

Multiple familiar occurrence of ochronotic arthropathy

Complete papillary muscle rupture is a catastrophic complication of acute myocardial infarction which usually leads to acute severe mitral regurgitation requiring urgent or emergent surgery. A case in which this complication occurred after chordal sparing mitral valve replacement is described. The severed papillary muscle was removed surgically. The incidence and natural history of papillary muscle rupture occurring after chordal sparing mitral valve replacement for ischemic mitral insufficiency is not known.     

Mixed land uses,land-use externalities,and residential property values: A reevaluation

Empirical evidence concerning the impact of neighborhood land-use externalities on residential property value is mixed. That is, no concensus has emerged in the literature as to whether locating non-residential land-use activities in residential neighborhoods can be expected to increase, decrease or leave unaltered surrounding property values. The purpose of this research was two-fold: 1) to construct a theoretical model of consumer behavior in which both the positive and negative effects of neighborhood land-use externalities are taken into account, and 2) to test this generalized model empirically, using hedonic pricing equations. The principal implication of the theoretical model is that the effect of non-residential activity on residential property values isa priori indeterminate, the outcome depending on the relative strength of the associated positive and negative external effects generated. The empirical test of the model was conducted for the city of Tucson, Arizona, where it is shown that over low ranges, increasing the amount of industrial, commercial, multifamily and public land-use activity in a neighborhood tended to increase surrounding residential property values. It is concluded that in locating future economic activity an optimal mix of landuse activities should be sought, not the regional separation of activities.     

Cloning and heterologous expression of a beta-fructofuranosidase gene from Arthrobacter globiformis IFO 3062, and site-directed mutagenesis of the essential aspartic acid and glutamic acid of the active site

We have cloned the gene encoding a beta-fructofuranosidase from Arthrobacter globiformis IFO 3062, and subsequently, the gene was heterologously expressed in Escherichia coli. This beta-fructofuranosidase gene encodes a protein of 548 amino acid residues with a calculated molecular mass of 60,519 Da. We have examined the roles of three residues of A. globiformis IFO 3062 beta-fructofuranosidase by site-directed mutagenesis, and found that aspartic acid 130 and glutamic acid 392, which are two of the apparent catalytic residues, are essential for hydrolase activity. This study provides the first experimental evidence showing that these two amino acid residues of beta-fructofuranosidase play a critical role in hydrolyzing sucrose.     

Mechanisms of heat transfer between a surface and a gas-fluidized bed for combustor application

There is currently considerable interest in the development of fluidized-bed boilers for efficient and environmentally clean combustion of coal. Fluidized beds have the advantages of high heat transfer rates and intimate mixing of additives such as limestone or dolomite for sulfur dioxide absorption produced as a result of combustion of coal containing sulfur. However, design for optimum heat transfer remains uncertain and essentially empirical. The mechanisms of heat transfer are complicated because of the many variables in a commercial combustion operation such as particle size distribution, particle shape, particle and gas thermal properties, reactor geometry and boiler tube design.An understanding of the mechanisms of bed to tube heat transfer is essential to sound design and interpretation of empirically derived correlations. Here we will review and criticize the major mechanisms of heat transfer that have been proposed. These mechanisms are proposed and developed from two schools of thought: (a) The principal resistance to heat transfer is a fluid film, and the moving fluidized particles scour the film to reduce the resistance to heat transfer; (b) Heat is absorbed by the fluidized particles and the rate of heat transfer depends on the rate of heat absorption.Radiant heat transfer is also discussed in this review in detail. Heat transfer by radiation is an important consideration in combustors but has received limited attention. The results of theoretical calculations are given which have been recently reported on the basis of the alternate-slab model of Gabor.The review will predominantly deal with the mechanistic models of heat transfer and various correlations developed over years will not be covered as this topic is dealt with in another review article by Saxena, Grewal, Gabor, Zabrodsky and Galershtein.     

Accurate wavelength measurements of a putative standard for near-infrared diffuse reflection spectrometry

The diffuse reflection (DR) spectrum of a sample consisting of a mixture of rare earth oxides and talc was measured at 2 cm-1 resolution, using five different accessories installed on five different Fourier transform near-infrared (FT-NIR) spectrometers from four manufacturers. Peak positions for 37 peaks were determined using two peak-picking algorithms: center-of-mass and polynomial fitting. The wavenumber of the band center reported by either of these techniques was sensitive to the slope of the baseline, and so the baseline of the spectra was corrected using either a polynomial fit or conversion to the second derivative. Significantly different results were obtained with one combination of spectrometer and accessory than the others. Apparently, the beam path through the interferometer and DR accessory was different for this accessory than for any of the other measurements, causing a severe degradation of the resolution. Spectra measured on this instrument were removed as outliers. For measurements made on FT-NIR spectrometers, it is shown that it is important to check the resolution at which the spectrum has been measured using lines in the vibration-rotation spectrum of atmospheric water vapor and to specify the peak-picking and baseline-correction algorithms that are used to process the measured spectra. The variance between the results given by the four different methods of peak-picking and baseline correction was substantially larger than the variance between the remaining five measurements. Certain bands were found to be more suitable than others for use as wavelength standards. A band at 5943.13 cm-1 (1682.62 nm) was found to be the most stable band between the four methods and the six measurements. A band at 5177.04 cm-1 (1931.61 nm) has the highest precision between different measurements when polynomial baseline correction and polynomial peak-picking algorithms are used.     

Towards a verifiable real-time, autonomic, fault mitigation framework for large scale real-time systems

Designing autonomic fault responses is difficult, particularly in large-scale systems, as there is no single ‘perfect’ fault mitigation response to a given failure. The design of appropriate mitigation actions depend upon the goals and state of the application and environment. Strict time deadlines in real-time systems further exacerbate this problem. Any autonomic behavior in such systems must not only be functionally correct but should also conform to properties of liveness, safety and bounded time responsiveness. This paper details a real-time fault-tolerant framework, which uses a reflex and healing architecture to provide fault mitigation capabilities for large-scale real-time systems. At the heart of this architecture is a real-time reflex engine, which has a state-based failure management logic that can respond to both event- and time-based triggers. We also present a semantic domain for verifying properties of systems, which use this framework of real-time reflex engines. Lastly, a case study, which examines the details of such an approach, is presented.     

Uni-REPM: validated and improved

Software products are usually developed for either a specific customer (bespoke) or a broader market (market-driven). Due to their characteristic, bespoke and market-driven development face different challenges, especially concerning requirements engineering. Many challenges are caused by an inadequate requirements engineering process, and hence there is a need for process improvement frameworks based on empirical research and industry needs. In a previous article we introduced Uni-REPM, a lightweight requirements engineering process assessment framework based on a review of empirically motivated practices in market-driven and bespoke requirements engineering literature. In this article, we validate this framework in academia as well as industry, in order to prepare Uni-REPM for widespread industry use. We conduct two validations; a static validation based on interviews with seven academic experts and a dynamic validation where Uni-REPM is applied in four industrial organisations. Uni-REPM is refined according to the feedback obtained in the validations. The study shows that Uni-REPM is a quick, simple, and cost-effective solution to assess the maturity level of the requirements engineering process of projects. Moreover, the assessment method using checklists is highly usable and applicable in various international development environments.