[Hmim][HSO4], a Green and Recyclable Acidic Ionic Liqiud Medium for the One‐Pot Nitration of TADB to HNIW

An efficient and mild procedure for the one‐pot preparation of CL‐20 from TADB in the presence of the Brønsted acidic ionic liquid 1‐methylimidazolium hydrogen sulfate [Hmim][HSO₄] as catalyst was developed. The ionic liquid was stable during the reaction process and could also be reused several times with steady activity. In order to optimize the process parameters to obtain higher yield and purity, a study was carried out with variation of the ionic liquids and some parameters like temperature, mole ratio of [Hmim][HSO₄] and nitric acid. This procedure may be a practical alternative to the existing procedures to meet the nees of academics as well as industry.     

Low-power scan design using first-level supply gating

Reduction in test power is important to improve battery lifetime in portable electronic devices employing periodic self-test, to increase reliability of testing, and to reduce test cost. In scan-based testing, a significant fraction of total test power is dissipated in the combinational block. In this paper, we present a novel circuit technique to virtually eliminate test power dissipation in combinational logic by masking signal transitions at the logic inputs during scan shifting. We implement the masking effect by inserting an extra supply gating transistor in the supply to ground path for the first-level gates at the outputs of the scan flip-flops. The supply gating transistor is turned off in the scan-in mode, essentially gating the supply. Adding an extra transistor in only one logic level renders significant advantages with respect to area, delay, and power overhead compared to existing methods, which use gating logic at the output of scan flip-flops. Moreover, the proposed gating technique allows a reduction in leakage power by input vector control during scan shifting. Simulation results on ISCAS89 benchmarks show an average improvement of 62% in area overhead, 101% in power overhead (in normal mode), and 94% in delay overhead, compared to the lowest cost existing method.     

Study of the transient release of water vapor from a fuel bed of wet biomass in a reciprocating-grate furnace

The present study investigates how sudden changes in fuel moisture affected the combustion characteristics of the fuel bed in a 4-MW reciprocating-grate furnace. The moisture content of the fuel fed to the furnace was monitored online using a near-infrared spectroscopy device, and the water vapor concentration in the flue gas was measured continuously. To obtain experimental data on fuel-bed conditions, the temperature and gas composition in the bed were measured using a probe. A simplified drying model was developed using the measured gas composition values as inputs. The model was then used to estimate the drying rate and to simulate the extent of the drying zone along the grate. Measurements indicated that a change in the moisture content of the fuel fed to the furnace was detected as a change in water vapor concentration in the flue gas with a delay of about 2 h. The model predicted that a portion of wet fuel would need about 2 h to become dry, in line with the measured time delay of the water vapor concentration change in the flue gas. Overall, there was good alignment between the measured and simulated results, supporting the validity of the model and the assumed mechanisms.     

A novel test method for evaluate asphaltene inhibitor efficiency on damage permeability

Asphaltene deposition has a significant detrimental effect on oilfield production. The key to effective treatment of asphaltene deposition is recognition of the problem. Asphaltene and effective treatment can be identified and quantified using laboratory methods. The most commonly way to asphaltene precipitation reduction is applying an asphaltene inhibitor. Most researchers investigate the effect of asphaltene inhibitors on fluid and precipitation reduction in static tests. This study is a coherent approach to measure effect of asphaltene precipitation on reservoir permeability and survey effect of asphaltene inhibitors on damage permeability.     

Effect of different acids during the synthesis of urea-formaldehyde adhesives and the mechanical properties of medium-density fiberboards bonded with them

The characteristics of urea-formaldehyde (UF) adhesives condensed by catalysis with four different acids, namely formic (HCOOH), hydrochloric (HCl), phosphoric (H₃PO₄), and sulfuric (H₂SO₄) acids, under alkaline–acidic–alkaline conditions at a molar ratio F/U = 1.12 were studied. The thermal curing properties of UF adhesives catalyzed with acid were characterized by differential scanning calorimetry at 10 °C/min heating rate. The resin structure examined by ¹³C-NMR spectroscopy showed that the resin catalyzed with HCl had a lower proportion of methylol groups, resulting in a lower level of formaldehyde emission. It was interesting to note that HCOOH resulted in the best overall mechanical properties of the medium-density fiberboard (MDF) panels. The HCl catalyst resulted in the poorest performance, providing the lowest internal bond strength, modulus of elasticity, and thickness swelling, with the exception of the free formaldehyde content. The resin catalyzed with H₂SO₄ had the highest free formaldehyde and the highest formaldehyde emission. H₂SO₄ and H₃PO₄ resulted in MDF mechanical properties relatively lower than for HCOOH. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47256.     

Investigation of Removal of Cu(II) Ions by Commercial Activated Carbon: Equilibrium and Thermodynamic Studies

Protection of Metals and Physical Chemistry of Surfaces - The present study deals with the application of activated carbon for the adsorptive removal of Cu(II) from its aqueous solutions. This...     

Synthesis and evaluation of several high absorbance black pigments for spacecraft thermal control coatings

Using black coatings and materials with high light absorbance that are capable of absorbing photons at visible and longer wavelengths is a very effective way to reduce unwanted stray light, also known as optical noise, within optical equipment. These lights can be greatly reduced to a reasonable level by functional and performable black coatings that are modified to absorb incident light as much as possible by their specific pigments. In the present work, several carbonaceous pigments were synthesized for the first time from wasteful materials and their optical properties in the visible and near‐infrared ranges studied. First, MCM‐48 and SBA‐15 were synthesized at different conditions and were then used as templates for carbonaceous products. SSS‐1 (the carbonic pigment synthesized by the mixture of sucrose and sodium silicate), SSS‐2 (the carbonic pigment synthesized by the mixture of sawdust and sodium silicate), and mesoporous carbon pigments (CMK‐3 and CMK‐1 with different levels of saturations) were synthesized. Finally, their structure, morphology, and optical properties were investigated by X‐ray diffraction (XRD), Field Emission Scanning Electron Microscopy (FE‐SEM), and Diffuse Reflectance Spectroscopy (DRS). The results indicated that the SSS‐1 pigment had a lower reflectance (below 1%) than carbon black (about 2.5%) in the visible region despite it being more cost‐effective than carbon black. The mesoporous pigments showed very high light absorbance in the visible region (about 2.5%). Compared with other black pigments, the CMK‐1 was the blackest synthesized material with a very low reflectance (about 0.05% in visible region), making it an ideal candidate as a super black pigment for reducing unwanted stray light within optical equipment.     

Proposing a new local density estimation outlier detection algorithm: an empirical case study on flow pattern experiments

Pattern Analysis and Applications - Outlier or anomaly detection is an important branch of data analysis that becomes a crucial task in many application domains. Data objects which significantly...