CH4 reforming with CO2 for syngas production over nickel catalysts supported on mesoporous nanostructured γ-Al2O3

Nanostructured γ-Al₂O₃ with high surface area and mesoporous structure was synthesized by sol-gel method and employed as catalyst support for nickel catalysts in methane reforming with carbon dioxide. The prepared samples were characterized by XRD, BET, TPR, TPH, SEM and TPO techniques. The BET analysis showed a high surface area of 204m²g^?1 and a narrow pore-size distribution centered at a diameter of 5.5 nm for catalyst support. The results revealed that an increase in nickel loading from 5 to 15 wt% decreased the surface area of catalyst from 182 to 160 m²g^?1. In addition, the catalytic results showed an increase in methane conversion with increase in nickel content. TPO analysis revealed that the coke deposition increased with increasing in nickel loading, and the catalyst with 15 wt% of nickel showed the highest degree of carbon formation. SEM and TPH analyses confirmed the formation of whisker type carbon over the spent catalysts. Increasing CO₂/CH₄ ratio increased the methane conversion. The BET analysis of spent catalysts indicated that the mesoporous structure of catalysts still remained after reaction.     

A low-power and robust quaternary SRAM cell for nanoelectronics

This paper presents an efficient and low-power quaternary static random-access memory (SRAM) cell based on a new quaternary inverter. For implementation, carbon nanotube field-effect transistors (CNTFETs) are used. Stacked CNTFETs are appropriately used in the proposed design to achieve a considerably low static power dissipation. The proposed SRAM has a more significant static noise margin due to its single quaternary digit line, and it is appropriate for MVL SRAM design as there are more than two stable states. The simulation results using Synopsys HSPICE with 32 nm Stanford comprehensive CNTFET model demonstrate the correct and robust operation of the proposed designs even in the presence of major process variations. In addition, the proposed SRAM cell is applied in a 4?×?4 SRAM array structure to demonstrate the efficiency of the proposed SRAM. The results indicate that the proposed design significantly lowers the power consumption and provides comparable static noise margins compared to the other state-of-the-art CNTFET-based circuits.

     

High-Stability Platinum Nano-Electrocatalyst Synthesized by Cyclic Voltammetry for Oxygen Reduction Reaction

Cyclic voltammetry as a simple electrochemical deposition method was developed in order to prepare a platinum nano-electrocatalyst for oxygen reduction reaction (ORR) in low-temperature fuel cell systems. The morphology of the prepared platinum was evaluated by scanning electron microscopy and energy dispersive x-ray analysis. The effects of platinum concentration in electrodeposition solution and scan numbers of cyclic voltammetry (scan rate: 50 m V s^?1, between 1.489 and ??0.311 versus reversible hydrogen electrode) on the performance of prepared electrocatalysts for ORR were studied. The fabricated electrodes were evaluated by cyclic voltammetry, linear sweep voltammetry, electrochemical impedance spectroscopy and scanning electron microscopy. The results revealed that the optimum conditions for the preparation of electrocatalysts were 2E?3 M H₂PtCl₆ and 30 scan numbers. The optimized electrode showed high stability after 1200 cycles.     

Effect of reinforcement type on high velocity impact response of GRP plates using a sharp tip projectile

High velocity impact performance of glass reinforced polyester (GRP) resin composite plates with different type of reinforcement was investigated. The projectile used was a sharp tipped (30°) conical head with total length of 30 mm and shank length of 15 mm with weight of 9.74 g. Five different types of E-glass fiber reinforcement were used, including chopped strand mat (CSM), plain weave, satin weave, unidirectional and cross-ply unidirectional fiber reinforcements. A smooth barrel gas gun was used to conduct high velocity impact tests in the velocity range of 80–160 m/s. Composite plates with size of 15 cm × 15 cm were prepared in 3 and 6 mm thickness. Results showed higher ballistic limit velocity (velocity at which samples fully penetrated the target plates with zero residual velocity) for 3 mm GRP plates with cross-ply unidirectional reinforcement followed by unidirectional reinforcement and plain weave, the plates with satin weave and CSM reinforcements were almost in same level. The thicker specimens (6 mm), plates with plain weave reinforcement showed better ballistic performance towards sharp tipped conical projectile impact, followed by cross-ply unidirectional, satin weave, unidirectional and CSM reinforced plates. Experimentally determined ballistic limit velocity for all specimens correlate well with estimated ballistic limit values obtained in full perforation tests. Damage assessment conducted on all specimens indicated fiber tension and shear failure for thin-walled and sever delamination for the thick-walled specimens as the dominant failure modes.     

Non-equilibrium Thermodynamic Model for the Estimation of the Soret Coefficient in Dilute Polymer Solutions

In the present work a theoretical model based on linear non-equilibrium thermodynamics and the concept of Eyring’s activation energy of viscous flow is developed to estimate the Soret coefficient in dilute polymer solutions. The model is capable of predicting a sign change in the Soret coefficient, when the polymer molecular weight changes. The key part of the model is the way that the net heat of transport of the polymer molecules is simulated. Employing the Mark–Houwink equation, which correlates the polymer solution intrinsic viscosity with its molecular weight, the net heat of transport of the polymer is correlated with the activation energy of viscous flow of the polymer’s monomer in the liquid state, the Mark–Houwink solution parameter, and the polymer molecular weight. The model is evaluated against the experimental data, where qualitative and in some cases quantitative agreement is found.     

Stochastic extinction and the selection of the transmission mode in microparasites.

Stochastic fluctuations in the transmission process of microparasites generate a risk of parasite extinction that cannot be assessed by deterministic models, especially in host populations of small size. While this risk of extinction represents a strong selection pressure for microparasites, it is usually not clearly separated from the deterministic ones. We suggest here that this stochastic selection pressure can affect the selection of the transmission mode of microparasites. To avoid extinction, parasites should maximize their inter-population transmission to ensure frequent reintroductions. Since the types of contacts may differ if congeners belong to the same or distinct populations, strains that are mainly transmitted through inter-population contacts might be selected. To examine this assumption, we analyse the issue of the competition between two strains differing in their transmission mode using a stochastic metapopulation model in which hosts may display different behaviours inside and outside their populations. We show that stochastic selection pressures may drive parasite evolution towards a transmission mode that maximizes the persistence of the parasite. We study the conditions under which stochastic selection pressures may surpass the deterministic ones. Our results are illustrated by the cases of feline immunodeficiency virus in cats and of sexually transmitted diseases in mammals.     

Conversion of n-heptane over different catalysts: Effect of catalyst-to-oil ratio and temperature

Catalytic cracking of n–heptane was investigated over various catalysts including ZSM-5, MCM-41, USY and mordenite. The influence of reaction temperature and catalyst-to-oil ratio was investigated in the case of ZSM-5 as more favorable catalyst in terms of conversion and light olefins yield. The highest n-heptane conversion of 97.3 wt.% was achieved over USY zeolite. Both conversion and olefin selectivity were increased by temperature over ZSM-5 zeolite. Increasing catalyst-to-oil ratio enhanced conversion with no significant changes in olefins selectivity. The highest olefin production was achieved over ZSM-5 zeolite in catalyst-to-oil ratios of 1.5 and 3.0 (g/g) at 550°C.     

Aflatoxin B1 degradation by Bacillus subtilis UTBSP1 isolated from pistachio nuts of Iran

Pistachio nuts are among the commodities with the highest risk of aflatoxin contamination in Iran. Aflatoxin B1 (AFB1) is one of the most hazardous mycotoxins for humans and livestock. In nature, there are microorganisms which are capable of reducing aflatoxins contamination in food and feed products. In this study, Bacillus subtilis strain UTBSP1 was isolated from pistachio nuts and studied for the degradation of AFB1. The AFB1 contents were determined by the use of HPTLC and HPLC as well as multiple reactions monitoring (MRM) method in LC-MS/MS. The results indicated B. subtilis UTBSP1 could considerably remediate AFB1 from nutrient broth culture and pistachio nut by 85.66% and 95%, respectively. Cell free supernatant fluid caused an apparent 78.39% decrease in AFB1 content. The optimal conditions for AFB1 degradation by cell free supernatant appeared at 35-40 °C, during 24 h. Furthermore, the results indicated that AFB1 degradation is enzymatic and responsible enzymes are extracellular and constitutively produced. The destructive AFB1 differed from standard AFB1 chemically, and lost a fluorescence property.