A Comparison between Different Ohmic Contacts for ZnO Thin Films

There are several metals that form ohmic contacts for ZnO thin films, such as copper, aluminum and silver. The aim of this work is to make a comparison between these ohmic contacts. To achieve this purpose,polycrystalline ZnO thin films were prepared by the spray pyrolysis technique, and characterized by the I–V measurements at room temperature. Two strips of each metal were thermally evaporated on the surface of the film and measurements were first recorded in the dark and room light, then in the dark before and after annealing for Al,which was found to be the best in the set. Films with aluminum contacts gave the smallest resistivity, best ohmicity and they are slightly affected by light as required. On the other hand, copper was found to be the worst, and films with copper contacts gave the largest resistivity, worst ohmicity and they are the most affected by light. Annealing improved the aluminum contacts due to alloying and doping.     

Wind turbine partial wake merging description and quantification

Individual turbine location within a wind plant defines the flow characterisitcs experienced by a given turbine. Irregular turbine arrays and inflow misalignment can reduce plant efficiency by producing highly asymmetric wakes with enhanced downstream longevity. Changes in wake dynamics as a result of turbine position were quantified in a wind tunnel experiment. Scale model turbines with a rotor diameter of 20 cm and a hub height of 24 cm were placed in symmetric, asymmetric, and rotated configurations. Simultaneous hub height velocity measurements were recorded at 11 spanwise locations for three distances downstream of the turbine array under two inflow conditions. Wake interactions are described in terms of the time‐average streamwise velocity and turbulence intensity as well as the displacement, momentum, and energy thicknesses. The effects of wake merging on power generation are quantified, and the two‐point correlation is used to examine symmetry in the mean velocity between wakes. The results indicate that both asymmetric and rotated wind plant arrangements can produce long‐lasting wakes. At shallow angles, rotated configurations compound the effects of asymmetric arrangements and greatly increase downstream wake persistence.     

Growth and characterization of PECVD semi-insulating polysilicon films and resistors

Semi-insulating polycrystalline (SIPOS) films deposited by plasma-enhanced chemical vapor deposition (PECVD) were investigated. The films were deposited using monosiane, nitrous oxide and argon at 300° C in a parallel-plate plasma reactor. Rapid thermal annealing was shown to restructure and densify the films with an activation energy of 0.7 eV. Nitrogen was found to be incorporated into the as-deposited films but not in annealed films. It was found that the resistivity of PECVD SIPOS was less sensitive to temperature and an order of magnitude lower than the values reported for LPCVD SI-POS. The differences are thought to be due to the more amorphous nature of PECVD material because of the lower deposition temperature of 300° C. This work was supported by a research contract from Sandia National Laboratories.     

Grid to wheel energy efficiency analysis of battery‐ and fuel cell–powered vehicles

Sustainable energy consumption is an important part of the renewable energy economy as renewable energy generation and storage. Almost one‐third of the global energy consumption can be credited to the transportation of goods and people around the globe. To move towards a renewable energy–based economy, we must adopt to a more sustainable energy consumption pattern worldwide especially in the transportation sector. In this article, a comparison is being made between the energy efficiency of a fuel cell vehicle and a battery electric vehicle. A very simple yet logical approach has been followed to determine the overall energy required by each vehicle. Other factors that hinder the progress of fuel cell vehicle in market are also discussed. Additionally, the prospects of a hydrogen economy are also discussed in detail. The arguments raised in this article are based on physics, economic analyses, and laws of thermodynamics. It clearly shows that an “electric economy” makes far greater sense than a “hydrogen economy.” The main objective of this analysis is to determine the energy efficacy of battery‐powered vehicles as compared to fuel cell–powered vehicles.     

Large-Eddy Simulations and Heat-Flux Modeling in a Turbulent Impinging Jet

This article documents the results of an investigation into aspects of the simulation and modeling of turbulent jets that impinge orthogonally on a target surface. The focus is on the case of a jet which issues from a circular pipe into stagnant surrounding at the relatively high value of Reynolds number of 23,000 (based on nozzle diameter and bulk velocity) for which experimental data are available. Large-eddy simulations were performed to obtain details of the mean flows and the turbulence fields including distributions of all components of the turbulent heat fluxes. The outcome of these simulations were used to assess three alternative models for the turbulent heat fluxes which differ from the conventional Fourier's Law by not being based on the assumption of proportionality between the eddy and thermal diffusivities via a constant Prandtl number. It was found that only one of the models considered succeeds in representing the effects on the heat fluxes of the complex strain field associated with the stagnation region and the subsequent development into the wall-jet region. The reasons for this outcome are discussed.     

Atmospheric pressure chemical vapor deposition of blanket tungsten films on silicon substrates for integrated circuit applications

Atmospheric pressure chemical vapor deposition (APCVD) of tungsten films using WF₆/H₂ chemistry has been studied. A statistical design of experiments approach and a surface response methodology were used to determine the most important process parameters and to obtain the best quality film possible in the parameter range studied. It was found that the deposition rate depends strongly on WF₆ flow rate, temperature, and the interaction between hydrogen flow rate and temperature. The resistivity was found to have a strong dependence on WF₆ and H₂ flow rates and temperature. An activation energy of 0.4 eV was calculated for the reaction rate limited growth regime. Empirical equations for predicting the deposition rate and resistivity were obtained. The resistivity decreases with both increasing film thickness and grain size. The films grown in the studied process parameter range indicate that (110) is the preferred orientation for films deposited with low WF₆/H₂ flow rate ratios at all deposition temperatures (350–450°C), whereas, the (222) orientation dominates at high WF₆/H₂ flow ratios and high deposition temperatures. Also, the grain size is larger for (222) oriented films than for (110) oriented films. The results of this study suggest that high-quality, thin film tungsten can be deposited using APCVD.     

Comparative binding and toxicity of saxitoxin and saxitoxinol in mice and in cultured cells

The binding characteristics of saxitoxin (STX), a known voltage-gated sodium channel blocker, and its analog saxitoxinol (STXOL), were studied in neuroblastoma, peritoneal macrophage, hepatocytes and PC-12 cell lines. 3H-STXOL bound to the cell-surface sites which appear to be the same as those occupied by 3H-STX and which can, therefore, be identified as STX receptors. The relative agreement of respective Kd obtained by saturation, competition, association and dissociation kinetics for STX and STXOL suggest the absence of any artifact in binding measurements. Unlike STX, STXOL was non-toxic to mice by intratracheal instillation. The major advantage of using 3H-STXOL is that the tritium label is not exchangeable. Data from this study suggest that 3H-STXOL can be used to identify STX receptors at 37 degrees C.     

Chlorine-doped CdS thin films from CdCl<Subscript>2</Subscript>-mixed CdS powder

The CdS:Cl thin films have been prepared using thermally evaporated, CdCl₂-mixed CdS powder at 200°C substrate temperature. The percentage of CdCl₂ in the mixture varied from 0% to 0.20%. The electrical properties and the grain size of the deposited films were investigated. The results show that light doping, resistivity, carrier concentration, and mobility follow Seto’s model for polycrystalline material. However, with heavy doping, these properties undergo a saturation trend. The saturation behavior can be understood in terms of the rapid formation of the A-center complexes in the films. The deposited films were annealed at 250°C and 300°C. The resistivity of pure and lightly doped CdS films increased with annealing temperature, whereas carrier concentration and mobility in these films decreased. However, for the higher doping concentrations, the resistivity decreased, whereas carrier concentration and mobility showed improvement. These changes in electrical properties of the deposited films with annealing and doping concentration are attributed to a reduction in the lattice defect sites in CdS upon annealing. The experimental results are interpreted in terms of a modified version of Seto’s model for polycrystalline materials.