Synthesis, structure, and field emission properties of sulfur-doped nanocrystalline diamond

The synthesis and properties of sulfur-doped nanocrystalline diamond films were investigated. The films were deposited by hot-filament chemical vapor deposition on Mo substrates using methane, hydrogen, and hydrogen disulfide. The nanocrystalline nature of the material arises from the induction of continuous secondary nucleation in the chemical vapor deposition environment. Complementary characterization tools were employed in order to obtain a comprehensive and coherent understanding of the correlations between the structural and electronic properties. In particular, sulfur-doped nanocrystalline diamond films show n-type Hall conductivity, enhanced field emission properties, and insensitivity to ion radiation. It was found that n-type doping of the tetragonally-bonded carbon matrix together with a nano network of trigonally-bonded carbon are crucial elements for enhanced field emission from nanocrystalline diamond. These conclusions and the corresponding supporting evidence are discussed.     

Patterns of international scientific co-operation in Puerto Rico

Scientific activity has been increasing in Puerto Rico in recent years, a development mirrored not only by the amount of papers published, but by the international links established for scientific co-operation. The purpose of the present study is to identify and discuss the patterns of such co-operation, along with the trends in scientific research conducted in that context at Puerto Rican institutions. The methodology includes an analysis of the main areas of research addressed, defined as the area of specialization of the journals publishing papers indexed in the Science Citation Index (CD-ROM version) from 1980 to 1999. A total of 7271 studies, appearing in 1240 scientific journals, were selected to study the co-operation established between Puerto Rican institutions and organizations in other countries. The findings showed a high rate of international co-operation: 46.07% of the papers published were co-authored by researchers from other countries. The country accounting for the highest percentage of joint research was the USA, followed by Germany, United Kingdom, Canada and Italy. The close relationship between the Puerto Rican and US scientific systems is not unusual, inasmuch as the economic and socio-political bonds between them play an essential role in Puerto Rican scientific activity. The results also revealed substantial differences between the nineteen eighties and the nineties in terms of the nature of the links established, as well as growing internationalization of scientific research conducted on the island over the twenty-year period studied.     

Thermophysical Analysis of Sandstone by Pulse Transient Method

Stones belong to porous materials where water in pores plays an important role during the freeze–thaw process. A thermophysical analysis based on the pulse transient method has been used to study an ageing cycle, namely the freeze–thaw cycle. Thermophysical analysis is based on measuring the thermophysical properties under specific thermodynamic conditions. The transient method determines the specific heat, thermal diffusivity, and thermal conductivity by a single measurement. A specimen of Sander sandstone was analyzed in both dry and water-saturated states. Typical anomalies of all thermophysical parameters at the freeze–thaw point as well as differences for the dry and saturated states were found. The changes of thermophysical parameters measured when using freeze–thaw cycles correspond to stone ageing. The freeze–thaw cycle can often be encountered in building physics, concrete construction, etcPaper presented at the Seventh Asian Thermophysical Properties Conference, August 23–28, 2004, Hefei and Huangshan, Anhui, P. R. China.     

Thermal-induced evolution of secondary phases in Cr–Mo–V low alloy steels

Four low alloy steels with different contents of molybdenum and vanadium were investigated. The steels were annealed at 773, 793, 853, 873, 933, 973, and 993 K for 500, 1000, 3000, and 10000 h. Techniques of transmission electron microscopy and thermodynamic calculations (ThermoCalc) were used to characterise influence of the steel bulk composition and the annealing conditions on evolution of carbides M₃C, M₂C, M₇C₃, M₂₃C₆, M₆C, and MC (M=metallic element). Changes in structure types and metal compositions of the carbides were characterised in detail. The work was done with the intention to obtain more information about the secondary phase evolution in low alloy steels used in energy industries.     

Modular proofs for key exchange: rigorous optimizations in the Canetti–Krawczyk model

Various optimizations in the Canetti–Krawczyk model for secure protocol design are proven to preserve security. In particular it is shown that multiple authenticators may be safely used together; that certain message components generated by authenticators may be reordered (to be sent at a different time) or replaced with other values with certain precautions; and that protocols may be defined in the ideal world with session identifiers constructed during protocol runs. Consequently protocol designers now have a set of clear rules to optimize and customize their designs without fear of breaking the security proof. In order to obtain the required proofs, we find it necessary to slightly revise the authenticated links part of the Canetti–Krawczyk model. Research funded by Australian Research Council through Discovery Project DP0345775     

Conductometric Study of Some Metal Halides in Glycerol + Water Mixtures

Electrolytic conductivities of potassium halides, KX (X = Cl⁻, Br⁻, I⁻) have been investigated in 10, 20, and 30 mass% glycerol + H₂O mixtures at 298.0, 308.0, and 318.0 K. The conductance data have been analyzed by the Fuoss-conductance–concentration equation in terms of the limiting molar conductance (Λ⁰), the association constant (K _A ), and the distance of closest approach of ion (R). The association constant (K _A ) tends to increase in the order: 10 mass% < 20 mass% < 30 mass% glycerol + water mixtures, while it decreases with temperature. Thermodynamic parameters ΔH ⁰, ΔG ⁰, and ΔS ⁰ are obtained and discussed. Also, Walden products (Λ⁰η) are reported. The results have been interpreted in terms of ion–solvent interactions and structural changes in the mixed solvents.     

Confined acoustic phonons in ultrathin SOI layers

We try to reproduce experimental mobility curves in ultrathin silicon-on-insulator inversion layers using a Monte Carlo simulator and a bulk model for the electron scattering with acoustic phonons. While it is possible to reproduce the experimental behavior for the thicker samples, the electron mobility is strongly overestimated when the thinnest samples are considered. The mobility curves for the thinnest samples can be reproduced using the same model if the deformation potential parameter increases as the silicon thickness decreases. This fact shows that acoustic phonons are also confined in ultrathin silicon on insulator layers. We then study confined phonons in single and three layer structures in order to give a physical motivation to the increase of acoustic phonon scattering rate for in ultrathin silicon layers.     

Second-Order Stiffness Matrix and Loading Vector of a Beam-Column with Semirigid Connections on an Elastic Foundation

The second-order stiffness matrix and corresponding loading vector of a prismatic beam–column subjected to a constant axial load and supported on a uniformly distributed elastic foundation (Winkler type) along its span with its ends connected to elastic supports are derived in a classical manner. The stiffness coefficients are expressed in terms of the ballast coefficient of the elastic foundation, applied axial load, support conditions, bending, and shear deformations. These individual parameters may be dropped when the appropriate effect is not considered; therefore, the proposed model captures all the different models of beams and beam–columns including those based on the theories of Bernoulli–Euler, Timoshenko, Rayleigh, and bending and shear.The expressions developed for the load vector are also general for any type or combinations of transverse loads including concentrated and partially nonuniform distributed loads. In addition, the transfer equations necessary to determine the transverse deflections, rotations, shear, and bending moments along the member are also developed and presented.     

A Comparative Study of the Use of Visual Communicative Signals in Interactions Between Dogs (Canis familiaris) and Humans and Cats (Felis catus) and Humans.

Dogs' (Canis familiaris) and cats' (Felis catus) interspecific communicative behavior toward humans was investigated. In Experiment 1, the ability of dogs and cats to use human pointing gestures in an object-choice task was compared using 4 types of pointing cues differing in distance between the signaled object and the end of the fingertip and in visibility duration of the given signal. Using these gestures, both dogs and cats were able to find the hidden food; there was no significant difference in their performance. In Experiment 2, the hidden food was made inaccessible to the subjects to determine whether they could indicate the place of the hidden food to a naive owner. Cats lacked some components of attention-getting behavior compared with dogs. The results suggest that individual familiarization with pointing gestures ensures high-level performance in the presence of such gestures; however, species-specific differences could cause differences in signaling toward the human. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

A Stress and Coping Model of Medication Adherence and Viral Load in HIV-Positive Men and Women on Highly Active Antiretroviral Therapy (HAART).

The authors tested a structural model that incorporated age, time since diagnosis, social support, coping, and negative mood as predictors of medication adherence and HIV viral load on 188 men and 134 women on highly active antiretroviral therapy (HAART). The authors used psychosocial latent factors formed from baseline measures to predict latent factors of adherence, as assessed by electronic monitoring and self-report, and viral load defined by indicators assessed over a 15-month period. Results from the model indicate that greater negative mood and lower social support are related to greater use of avoidance-oriented coping strategies. Use of these coping strategies by patients on HAART is related to poorer medication adherence and, subsequently, higher viral load. This model advances researchers' understanding of the contribution of psychosocial variables in predicting treatment adherence and disease progression in HIV-positive men and women. (PsycINFO Database Record (c) 2010 APA, all rights reserved)