Optimization of sensitizer concentration for upconversion photoluminescence of Yb3+/Er3+: La10W22O81 nanophosphor rods

Yb³⁺/Er³⁺codoped La₁₀W₂₂O₈₁ (LWO) nanophosphor rods have been successfully synthesized by a facile hydrothermal assisted solid state reaction method, and their upconversion photoluminescence properties were systematically studied. X-ray diffraction patterns revealed that the nanophosphors have an orthorhombic structure with space group Pbcn (60). A microflowers-like morphology with irregular hexagonal nanorods was observed using field emission scanning electron microscopy for the Yb³⁺(2 mol%)/Er³⁺(2 mol%):LWO nanophosphor. The shape and size of the nanophosphor and the elements along with their ionic states in the material were confirmed by TEM and XPS studies, respectively. A green upconversion emission was observed in the Er³⁺: LWO nanophosphors under 980 nm laser excitation. A significant improvement in upconversion emission has been observed in the Er³⁺: LWO nanophosphors by increasing the Er³⁺ ion concentration. A decrease in the upconversion emission occurred due to concentration quenching when the doping concentration of Er³⁺ ions was greater than 2 mol%. An optimized Er³⁺(2 mol%): LWO nanophosphor exhibited a strong near infrared emission at 1.53 μm by 980 nm excitation. The green upconversion emission of Er³⁺(2 mol%): LWO was remarkably enhanced by co-doping with Yb³⁺ ions under 980 nm excitation because of energy transfer from Yb³⁺ to Er³⁺. The naked eye observed this upconversion emission when co-doping with 2 mol% Yb³⁺. In order to obtain the high upconversion green emission, the optimized sensitizer concentration of Yb³⁺ ions was found to be 2 mol%. The upconversion emission trends were studied as a function of stimulating laser power for an optimized sample. Moreover, the NIR emission intensity has also been enhanced by co-doping with Yb³⁺ ions due to energy transfer from Yb³⁺ to Er³⁺. The energy transfer dynamics were systematically elucidated by energy level scheme. Colorimetric coordinates were determined for Er³⁺ and Yb³⁺/Er³⁺: LWO nanophosphors. The energy transfer mechanism was well explained and substantiated by several fluorescence dynamics of upconversion emission spectra and CIE coordinates. The results demonstrated that the co-doped Yb³⁺(2 mol%)/Er³⁺(2 mol%): LWO nanophosphor material is found to be a suitable candidate for the novel upconversion photonic devices.     

Storage and permeation of hydrogen molecule,atom and ions (H+ and H−) through silicon carbide nanotube; a DFT approach

The barriers for the encapsulation and decapsulation of hydrogen ions (cationic hydrogen and hydride), atom, and molecule through silicon carbide nanotube are thoroughly studied. DFT method is selected to measure the kinetic barriers for the passage of hydrogen atom, ions and molecule through nanotube via scanning potential energy surface. The kinetic barriers for the passage (encapsulation and decapsulation) of hydrogen are very important to understand the mechanism of hydrogen storage and release. The barriers for the permeation of H, H⁺ and H^? across SiC nanosheet are lower compared to hydrogen molecule (H₂). The exohedral and endohedral adsorption of hydrogen ions (cation and anion), atom and exohedral hydrogen molecule on silicon carbide are exothermic in nature. Whereas the encapsulation of hydrogen molecule in silicon carbide is endothermic. Electronic properties are analyzed through measurement of energy gap between highest occupied and lowest unoccupied molecular orbitals gap (G_H-L) and the density of state (DOS) spectra. The G_H-L analysis reveals that endohedral complexes have more pronounced effect on electronic properties compared to exohedral complexes. The SiC nanotube has highly favorable properties for storage and release of hydrogen ions, and atom.     

Wavelet-modified maximum average correlation height filter for rotation invariance that uses chirp encoding in a hybrid digital-optical correlator

We discuss and implement a wavelet-modified maximum average correlation height (MACH) filter for 0 degrees -360 degrees in-plane rotations in a hybrid digital-optical correlator. Use of a wavelet transform improves the performance of the MACH filter by reducing the number of filters that are required to identify a target rotated at any angle between 0 degrees and 360 degrees in-plane rotations and enhances the autocorrelation peak intensity significantly. The output of a hybrid digital-optical correlator contains two autocorrelation peaks and a strong dc. Using a chirp function with the wavelet-modified MACH filter, the correlation signals are focused in three different planes. Thus placing a peak-capturing CCD camera at a particular plane, only one autocorrelation peak is recorded, discarding the strong dc and other autocorrelation peaks. A signal-to-noise ratio has been calculated as a metric of goodness of the proposed wavelet-modified MACH filter.     

Scope and opportunities of using glycerol as an energy source

Biodiesel is a promising fuel for diesel engines in wake of its renewable nature and environmental benefits. Biodiesel can be produced by different pathways; however, glycerol (or glycerin, glycerin) is a valuable by-product which is formed during this process. As mandates are being enforced by different government worlds over, the demand of biodiesel is likely to go up. With increased demand and production of biodiesel, significant quantity of glycerol shall be available. There is an urgent need to find alternative application area of glycerol so that viability of biodiesel industry can be sustained.In the present study, the focus has been made on the various application areas of using surplus glycerol from biodiesel industries to make them more financially attractive. Amongst the different pathways of using glycerol as a source of energy; direct combustion, mixing with agricultural solid wastes and then burning, blending directly or indirectly with other fuels, hydrogen and hydrocarbon production from glycerol, etherification, etc. are prominent one. The requirement, advantages and limitations of each approach have also been evaluated in the study. Combustion of glycerol if not done properly would result in formation of acrolien which is highly toxic in nature and efforts should be made to use glycerol indirectly to produce energy (i.e. all the pathways expect the direct combustion and the solid fuel method). The production of hydrogen from glycerol via APR appears to be the best solution to the disposal problem since the hydrogen yield via APR is highest. Moreover the process occurs at lower pressure and temperature when compared to steam reforming, and it is a single step process. Etherification, tri-acetylisation, and blending have been found to be useful for improving the performance of automotives by facilitating proper and smooth combustion of fuel.     

Modeling of radiation hardening in ferritic/martensitic steel using multi-scale approach

Fe-Cr based ferritic/martensitic (FM) steels are the candidate structural materials for future fusion reactors. In this work, a multi-scale approach comprising atomistic and dislocation dynamic simulations are used to understand the hardening of these materials due to irradiation. At the atomic scale, molecular dynamics (MD) simulations are used to study the mobility of an edge dislocation and its interaction with irradiation induced voids and bubbles. The dislocation dynamics (DD) simulations are used to estimate the change in flow stress of the material as a result of irradiation hardening. The key input to the DD simulations are the friction stress and maximum shear stress for the edge dislocation to overcome the defects as determined from atomistic simulations. The results obtained from the MD and DD simulations are in qualitative agreement with experimental results of hardening behavior of irradiated FM steels.     

Examining the influence of aggressive driving behavior on driver injury severity in traffic crashes

In this paper, we capture the moderating effect of aggressive driving behavior while assessing the influence of a comprehensive set of variables on injury severity. In doing so, we are able to account for the indirect effects of variables on injury severity through their influence on aggressive driving behavior, as well as the direct effect of variables on injury severity. The methodology used in the paper to accommodate the moderating effect of aggressive driving behavior takes the form of two models – one for aggressive driving and another for injury severity. These are appropriately linked to obtain the indirect and direct effects of variables. The data for estimation is obtained from the National Motor Vehicle Crash Causation Study (NMVCCS). From an empirical standpoint, we consider a fine age categorization until 20 years of age when examining age effects on aggressive driving behavior and injury severity.There are several important results from the empirical analysis undertaken in the current paper based on post-crash data collection on aggressive behavior participation just prior to the crash and injury severity sustained in a crash. Young drivers (especially novice drivers between 16 and 17 years of age), drivers who are not wearing seat belt, under the influence of alcohol, not having a valid license, and driving a pick-up are found to be most likely to behave aggressively. Situational, vehicle, and roadway factors such as young drivers traveling with young passengers, young drivers driving an SUV or a pick-up truck, driving during the morning rush hour, and driving on roads with high speed limits are also found to trigger aggressive driving behavior. In terms of vehicle occupants, the safest situation from a driver injury standpoint is when there are two or more passengers in the vehicle, at least one of whom is above the age of 20 years. These and many other results are discussed, along with implications of the result for graduated driving licensing (GDL) programs.     

Electrical and thermo-mechanical analysis of beam recovery system for megawatt power gyrotron

The paper presents the electrical and thermo-mechanical design of single stage beam recovery system for 120 GHz, 1 MW gyrotron. The electrical study shows that the cylindrical shape single stage beam recovery system enhances the efficiency by 66.26%. The maximum power deposited to collector in depressed collector operation is 0.48 MW for electronic efficiency, 30% and 1.44 MW for DC electron beam. The thermo-mechanical analysis has been performed to evaluate the water cooling system. The cooling system has capability of accommodating a peak wall loading, 0.9 kW/cm² at flow rate of 1500 l/min for safe operating time, 60 ms. Further, a high voltage analysis is also carried out to appraise the electric field distribution in the collector.     

Fatty acid profile and sensory characteristics of table eggs from laying hens fed hempseed and hempseed oil

Hempseed (HS) is rich in omega-3 polyunsaturated fatty acids, with approximately 17% of total fatty acids as alpha-linolenic acid. As such, HS and its oil may be used in hen diet formulations to produce eggs enriched in essential fatty acids. Because omega-3 eggs have the potential for unpleasant aromas and flavors, the current study was designed to assess the fatty acid profile and sensory attributes of eggs procured from hens consuming diets containing hempseed oil (HO) or HS. A total of 48 individually caged White Bovan hens received 1 of 6 diets containing 4%, 8%, 12% HO, 10%, 20% HS or 0% hemp (w/w) for 12 wk. Total omega-3 polyunsaturated fatty acid content was highest in the 12% HO group (15.3 mg/g of yolk) compared to the control (2.4 mg/g of yolk). Trained panellists (n= 8) found no significant differences (P≥ 0.05) in aroma or flavor between cooked eggs from different dietary treatments, with the exception of sweet flavor. The 4% HO group yielded the least sweet eggs compared to the 20% HS group, which was highest. For yolk color, L*, a*, and b* values (Mean ± SEM) for control eggs were 61.2 ± 0.10, 1.1 ± 0.05, and 43.0 ± 0.22, respectively. Addition of hemp led to significant (P < 0.001) reductions in L*, and significant increases in a* and b*, with the largest changes observed in the 20% HS treatment (L*= 58.7 ± 0.10; a*= 5.8 ± 0.05; b*= 60.5 ± 0.22). The results show that hemp use in hen diets leads to increased omega-3 polyunsaturated fatty acid content and color intensity of egg yolks, but does not have adverse effects on the sensory profiles of the cooked eggs. PRACTICAL APPLICATION: This study provides evidence that HS and hempseed oil (HO) can safely be utilized as feed ingredients for laying hens to produce table eggs that are enriched in essential fatty acids. Additionally, the eggs procured from these hens had similar aroma and flavor compared to eggs from hens not fed any hemp. The greater the dietary hemp inclusion, the more pigmented the resulting yolks became in terms of darkness, redness, and yellowness.     

Proton Conductivity of SPEEK Membranes

Novel sulfonated poly(ether ether ketone) (PEEK) copolymers were prepared using a low-viscosity grade PEEK powder. The TGA studies indicated that SPEEK membranes with up to 75% DS have enough thermal stability. The highest conductivity of 2.176 × 10^?2 S cm^?1 has been observed at 100°C for SP96 (DS = 72%). Compared to Nafion-15, SP72 exhibits much higher conductivity at all the temperatures considered. The water sorption experiments indicated that the maximum water uptake was 3.92% for SP24 and it was 60% for SP120. It was observed that the increase in the water content in a membrane caused a decrease in the diffusion coefficient.