Fabrication and optimization of PES/PVP hollow fiber membranes using Box–Behnken model and CART algorithm

This study focuses on the optimization of polyethersulfone (PES) hollow fiber membranes fabricated with the phase inversion method. A Box–Behnken experimental design was employed with three different PES concentration ratios (11, 14, 17 wt.%), three polyvinylpyrrolidone (PVP) molecular weight ratios (K30/K90 ratios of 6:0, 3:3, 0:6 wt.%), three different bore fluid (BF) composition ratios (water/alcohol ratios of 20:80, 60:40, 100:0), and three different air gap values (24, 37, and 50 cm). The results were analyzed in terms of pure water permeability (PWP) and porosity as optimization parameters using response surface methodology and the classification and regression tree (CART) model. ANOVA results revealed significant effects of PES concentration, PVP molecular weight, and BF composition on the outcomes. After optimization, the maximum PWP and the maximum porosity were obtained as 360.15 L/m² h bar, 60.57%, respectively. The CART model achieved sufficient accuracy in classifying samples.     

The effect of infrared stabilized rice bran substitution on nutritional,sensory, and textural properties of cracker

The potential of infrared stabilized rice bran (SRB) as an ingredient in cracker formulation in terms of nutritional, sensory, and textural attributes was evaluated. Crackers were supplemented with infrared SRB at the rate of 2.5, 5, and 10 % based on flour weight. Crude fat, total ash, insoluble dietary fiber, and Zn, Fe, Ca, K, and P content of the crackers were significantly increased with increasing rice bran substitution (p < 0.05). Phytate content of the crackers that were substituted with 10 % of SRB was approximately three times higher than the control samples. Contribution of 10 % of SRB substitution to B vitamins of crackers was 46, 30, 317, and 121 % for thiamine, riboflavin, niacin, and pyridoxine, respectively. The effect on sensory scores of the panelists or textural attributes of the crackers of the replacement of refined wheat flour with SRB up to 10 % was insignificant (p > 0.05).     

Ambient Vibration Data Analysis for Structural Identification and Global Condition Assessment

System identification is an area which deals with developing mathematical models to characterize the input-output behavior of an unknown system by means of experimental data. Structural health monitoring (SHM) provides the tools and technologies to collect and analyze input and output data to track the structural behavior. One of the most commonly used SHM technologies is dynamic testing. Ambient vibration testing is a practical dynamic testing method especially for large civil structures where input excitation cannot be directly measured. This paper presents a conceptual and reliable methodology for system identification and structural condition assessment using ambient vibration data where input data are not available. The system identification methodology presented in this study is based on the use of complex mode indicator functions (CMIFs) coupled with the random decrement (RD) method to identify the modal parameters from the output only data sets. CMIF is employed for parameter identification from the unscaled multiple-input multiple-output data sets generated using the RD method. For condition assessment, unscaled flexibility and the deflection profiles obtained from the dynamic tests are presented as a conceptual indicator. Laboratory tests on a steel grid and field tests on a long-span bridge were conducted and the dynamic properties identified from these tests are presented. For demonstrating condition assessment, deflected shapes obtained from unscaled flexibility are compared for undamaged and damaged laboratory grid structures. It is shown that structural changes on the steel grid structure are identified by using the unscaled deflected shapes.     

Poly(ethylene glycol dimethacrylate-n-vinyl imidazole) beads for heavy metal removal

Poly(ethylene glycol dimethacrylate-n-vinyl imidazole) [poly(EGDMA-VIM)] hydrogel (average diameter 150-200 microm) was prepared by copolymerizing ethylene glycol dimethacrylate (EGDMA) with n-vinyl imidazole (VIM). The copolymer hydrogel bead composition was characterized by elemental analysis and found to contain 5 EGDMA monomer units each VIM monomer unit. Poly(EGDMA-VIM) beads had a specific surface area of 59.8 m2/g. Poly(EGDMA-VIM) beads were characterized by swelling studies and scanning electron microscopy (SEM). These poly(EGDMA-VIM) beads with a swelling ratio of 78% were used for the heavy metal removal studies. Chelation capacity of the beads for the selected metal ions, i.e., Cd(II), Hg(II) and Pb(II) were investigated in aqueous media containing different amounts of these ions (10-750 mg/l) and at different pH values (3.0-7.0). Chelation rate was very fast. The maximum chelation capacities of the poly(EGDMA-VIM) beads were 69.4 mg/g for Cd(II), 114.8 mg/g for Pb(II) and 163.5 mg/g for Hg(II). The affinity order on molar basis was observed as follows: Hg(II) > Cd(II) > Pb(II). Chelation behavior of heavy metal ions could be modelled using both the Langmuir and Freundlich isotherms. pH significantly affected the chelation capacity of VIM incorporated beads. Chelation of heavy metal ions from synthetic wastewater was also studied. The chelation capacities are 45.6 mg/g for Cd(II), 74.2 mg/g for Hg(II) and 92.5 mg/g for Pb(II) at 0.5 mmol/l initial metal concentration. Regeneration of the chelating-beads was easily performed with 0.1 M HNO3. These features make poly(EGDMA-VIM) beads potential candidate adsorbent for heavy metal removal.     

Rheological properties of extruded dispersions of flaxseed-maize blend

Rheological properties of the extruded pastes of various extrusion conditions were investigated by dynamic oscillation and creep-recovery tests. Temperature sweep test showed that the starch gelatinization of non-extruded pastes took place at about 67 °C and no gelatinization was observed for the extruded sample. Frequency sweep tests could be represented by a Power law model and the samples showed gel-like behavior since storage modulus was much larger than loss modulus. The creep-recovery data were modeled by the Burger’s model. With the addition of flaxseed, the viscoelastic modulii of pastes were increased due to the formation of starch–protein–fat network, however, with further increasing the flaxseed content the viscoelastic modulii of pastes were decreased due to excessive fat which lead to network weakening. The water holding capacity results indicated that the viscoelastic properties of pastes were depended on the swelled starch–protein complex granules and the formation of new cross-links in the network.     

Effect of High-Pressure Homogenization on the Structure of Cassava Starch

Cassava starch suspension was homogenized at different pressures (0, 20, 40, 60, 80, and 100 MPa) with a high-pressure homogenizer. To investigate the effect of high-pressure homogenization on the structure of cassava starch, the samples were characterized using microscopy, laser scattering, and X-ray diffraction techniques, with native and heat gelatinized cassava starches as controlled samples. The temperature of starch suspension increased linearly with applied pressure at a rate of 0.187°C/MPa. Microscopy studies showed that cassava starch was partly gelatinized after high-pressure homogenization, and the degree of gelatinization increased with homogenizing pressure. Results of laser scattering measurements suggested a considerable increase in particle size after homogenization at 100 MPa as a result of granule swelling. The X-ray diffraction pattern showed that there was no evident change after homogenization suggesting that the crystalline structure of starch granules was resistant to high-pressure homogenization.     

Depth sensing indentation analysis of electrochemically synthesized polythiophene

A depth sensing indentation (DSI) test with associated analyses was used to investigate some mechanical properties (reduced elastic modulus, hardness and creep) of electrochemically synthesized polythiophene (PT). Internal friction (IF) and energy absorption representing the degree of anelastic deformation of the material were also determined using cyclic and step-load/unload (SLU) test procedure, respectively. The indentation load–displacement (P–h) curves of the sample were obtained under different peak loads with two load holding time, 70 and 300 s. Elastic modulus values were determined by analyzing of these curves with Oliver–Pharr (O–P) and Feng–Ngan (F–N) procedures. The obtained results pointed out that both methods yielded comparable results for 300 s, while the corresponding values of 70 s were not well-matched with each other. These results were explained by the saturation of creep effects within 300 s holding period. Creep analysis exhibited that creep displacement increases at a declining rate with time and finally reaches a constant rate. Cyclic test results indicated that IF values approach saturation after several cycles and the saturation value of IF was found to be depending on loading rate. From SLU tests, an upper limit of the normalized dissipated energy was observed.