A general strategy to develop combined photochemical and biological system for biorecalcitrant wastewater treatment is proposed. For the development of this strategy, the following points were taken into account: the biodegradability of initial solutions, the operation mode of the coupled reactor, the chemical and biological characteristics of the phototreated solutions, the evaluation of different photoassisted advanced oxidation processes, the optimal conditions of both photochemical and biological processes, and the efficiency of the coupled reactor.
The strategy to couple photochemical and biological processes is illustrated by case studies of four different biorecalcitrant pollutants. Three kinds of combined systems were developed using either photo-Fenton, Fe3+/UV, or TiO2 supported on glass rings for the photocatalytic pretreatment and in all cases immobilized biomass for the biological step. The advantages of the each coupled system are discussed and beneficial effects of such two-step treatments were found. However this strategy is not a universal solution. Chemical, biological, and kinetic studies must be always carried out to ensure that the photochemical pretreatment increase the biocompatibility of the treated wastewater. Some field experiments using solar reactor indicated that a coupled photochemical–biological treatment system at pilot scale is a possible way to achieve the complete mineralization of the biorecalcitrant pollutants. 相似文献
The diffusion of water into solid poly(ditetrahydrofurfuryl itaconate) (PDTFI) films and in analogous polymer solutions was measured. Diffusion into solid PDTFI films on a glass support was measured in three solutions of different pH (4, 7 and 10) at 37 and 60 °C during a 90 day period. The uptake was high and was both pH and temperature dependent, ranging from 120 to 2000%. A Fickian mechanism is observed for the initial stages of uptake, whilst a non-Fickian mechanism is present when the equilibrium is approached. The pH 7 samples did not equilibrate at any temperature during the experiment. The FTIR investigations of the films indicated some deesterification took place during the uptake. The diffusion coefficients and diffusion exponents are calculated for the samples. The diffusion of water into PDTFI solution in acetone was measured by PGSE-NMR, showing the expected linear attenuation functions. The diffusion coefficient of water was calculated for polymer concentrations up to 10%. 相似文献
The ability to predict subsurface defect information in composite materials through a non-invasive, efficient inspection protocol is fast becoming a vital research area. In numerically modeling the thermographic process associated with an infrared (IR) technique we can afford inspectors the ability to predict subsurface defect information associated with a specific material configuration. The research involved in this study looks specifically at the finite element modeling (FEM) of delaminations in a composite flat plate setup. To date the modeling of delaminations has been restricted to only two dimensional (2D) numerical representations and associated primarily with rear faced detection. The results of this research, however, clearly show that the rear faced detection technique has limitations in defect depth prediction and the 2D approximation associated with this technique ignores a paramount effect in the form of lateral thermal diffusion. It is also made clear that the representation of experimental flat plate models with flat bottomed holes, under pulse phase thermographic inspection, in simulating delaminations is misguided. 相似文献
A dynamic model incorporating biomass growth and liquid hold-up evolution is developed to describe a fixed bed bioreactor operation with cocurrent upflow of water and air flows. The model permits to predict cycle time and optimal operation conditions for high substrate removal and long cycle times. Simulation results are compared with published experimental results and show good model accuracy. 相似文献
Insulin resistance is defined as a reduced ability of insulin to stimulate glucose utilization. C57BL/6 mice fed with a high-fat diet (HFD) are a model of insulin resistance. In skeletal muscle, hydrogen peroxide (H2O2) produced by NADPH oxidase 2 (NOX2) is involved in signaling pathways triggered by insulin. We evaluated oxidative status in skeletal muscle fibers from insulin-resistant and control mice by determining H2O2 generation (HyPer probe), reduced-to-oxidized glutathione ratio and NOX2 expression. After eight weeks of HFD, insulin-dependent glucose uptake was impaired in skeletal muscle fibers when compared with control muscle fibers. Insulin-resistant mice showed increased insulin-stimulated H2O2 release and decreased reduced-to-oxidized glutathione ratio (GSH/GSSG). In addition, p47phox and gp91phox (NOX2 subunits) mRNA levels were also high (~3-fold in HFD mice compared to controls), while protein levels were 6.8- and 1.6-fold higher, respectively. Using apocynin (NOX2 inhibitor) during the HFD feeding period, the oxidative intracellular environment was diminished and skeletal muscle insulin-dependent glucose uptake restored. Our results indicate that insulin-resistant mice have increased H2O2 release upon insulin stimulation when compared with control animals, which appears to be mediated by an increase in NOX2 expression. 相似文献
pH sensitive, nontoxic, and biocompatible poly(methacrylic) acid (PMAA) based soft networks have been extensively used in the design of systems for targeted drug delivery. Still, their highly hydrophilic nature limits their potential to be used as a carrier of poorly water-soluble substances. With the aim to overcome this limitation, the present study details a new approach for modification of PMAA based carriers using two amphiphilic components: casein and liposomes. The FTIR analysis revealed structural features of each component as well as the synergetic effect that originated from the formation of specific interactions. Namely, hydrophobic interactions between the poorly water-soluble model drug (caffeine) and casein enabled caffeine encapsulation and controlled release, while addition of liposomes ensured better control of the release rate. The morphological properties of the carriers, swelling behavior, and release kinetics of caffeine were investigated depending on the variable synthesis parameters (neutralization degree of methacrylic acid, concentration of caffeine, presence/absence of liposomes) in two different media simulating the pH environment of human intestines and stomach. The data obtained from in vitro caffeine release were correlated and analyzed in detail using several mathematical models, indicating significant potential of investigated carriers for targeted delivery and controlled release of poorly water-soluble substances. 相似文献
The effect of a surface coating on the response of a metallic substrate to pulsed thermal excitation is examined with the view to assessing its impact on the efficacy of quantitative thermographic evaluation as applied to the problem of material loss evaluation. An analytical model describing the response of a layered structure to a surface thermal excitation has been developed and its predictions are shown to be in excellent qualitative agreement with experimental observations. The results indicate that for materials with high thermal diffusivity, a surface paint layer bears important influence on the development of the surface thermal response and should be taken into account when undertaking quantitative assessments of thermographic data. 相似文献
This paper discusses the development of the Grohovo landslide on the north-eastern slope of the Rječina valley, the largest
active landslide along the Croatian part of the Adriatic Sea coast. This complex retrogressive landslide was reactivated in
December 1996. Thirteen separate slide bodies have been identified. The slide surface is considered to be on the upper flysch
bedrock. Monitoring indicated that the magnitude of displacements was very different in time and space. The maximum movements
were recorded on the upper part of the slope. The limestone mega-block and separated rocky blocks on top of the slope have
also moved, which is not a typical phenomenon of the flysch slopes in the area of Rijeka.
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