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181.
Terpolymers based on N‐isopropylacrylamide, sodium 2‐acrylamido‐2‐methyl‐propanesulfonate, and N‐tert‐butylacrylamide were synthesized by free‐radical copolymerization with 2,2′‐azobisisobutyronitrile as an initiator. The lower critical solution temperatures (LCSTs) of the linear polymer aqueous solutions were determined by the measurement of the transmittance on UV at different temperatures. The influence of the polymer concentration, polymer composition, and ionic strength on the LCSTs of the linear polymers was investigated. The LCST decreased with increases in the hydrophobic monomer N‐tert‐butylacrylamide, polymer concentration, and ionic strength. The phase transition became sharp when the polymer concentration and ionic strength increased. Meanwhile, the crosslinked hydrogels were prepared with the same recipe used for the linear terpolymers, but a crosslinker was added to the reaction system. The swelling ratios of the hydrogels at various temperatures and salt solutions were determined. The hydrogels possessed both high swelling ratios and thermosensitivity. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
182.
HS-900有机硅密封抗渗防水剂是一种新型的有机硅改性硅酸盐防水材料。具有良好的抗渗性能和耐酸碱腐蚀能力。将其涂于低标号混凝土材料上,效果尤其明显。 相似文献
183.
The adsorption of dyes from aqueous solution using diatomite 总被引:2,自引:0,他引:2
Raw diatomite was calcined at 450 °C for dyes removal from aqueous solution. SEM and FTIR analysis show that the raw diatomite
contains organic impurities, which are removed after the calcination. The impurities removal decreases the specific surface
area and increases the average pore diameter of raw diatomite, while improves its adsorption capability of dyes. The adsorption
isotherm and kinetics experiments of methylene blue onto calcined diatomite were then carried out to investigate the adsorption
property. It shows that the adsorption capacity of methylene blue is about 50 mg/g. The adsorption isotherm was fitted by
the Langmuir, Freundlich and Redlich-Peterson models, which reveals that the Redlich-Peterson isotherm is the best one. Two
kinetic models, pseudo-first order and pseudo-second order, were rearranged for expediently investigating the adsortpion mechanisms.
Fitting results show that the pseudo-first-order model is better in describing the adsorption process. 相似文献
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This paper addresses a multi-supplier, multi-affected area, multi-relief, and multi-vehicle relief allocation problem in disaster relief logistics. A multi-objective optimisation model based on disaster scenario information updates is proposed in an attempt to coordinate efficiency and equity through timely and appropriate decisions regarding issues such as vehicle routing and relief allocation. An optimal stopping rule is also proposed to determine the optimum period of delay before responding to disaster, because decision making requires accurate disaster information. The main contribution of this paper is solving relief allocation problem in a novel way by correlating operational research with statistical decision making and Bayesian sequential analysis. Finally, a case is presented based on the post-disaster rescue in Eastern China after supertyphoon Saomai to test the applicability and show the potential advantages of the proposed model. 相似文献
189.
本文主要介绍了用微波等离子体化学气相沉积法(以下简称MP CVD法)以甲醇-氢气混合气和丙酮-氢气混合气为源气体,分别以单晶硅的(111)面和人造金刚石的(100)面为衬底材料,制备出了面积为20mm×20mm厚为10μm的多晶金刚石膜和面积为1.0mm×1.0mm厚为5μm的单晶金刚石膜。通过试验发现,源气体配比和衬底温度对薄膜质量起决定性作用。另外,衬底在反应腔中的位置对薄膜的生成也有很大影响。单晶金刚石膜制备过程中衬底金刚石的晶体取向与金刚石薄膜的生长及质量有密切的关系。在金刚石的(100),(110)和(111)面上分别获得了单晶金刚石膜和金刚石多晶粒子。选用扫描电镜、显微激光拉曼、反射电子衍射对多晶金刚石膜及单晶金刚石膜的性能进行了测试。 相似文献
190.