Kinetics of hydrogen peroxide bleaching of ALCELL® derived pulp

In this study, a kinetic model of the final bleaching stage with hydrogen peroxide in a totally chlorine free (TCF) bleaching sequence for ALCELL® processed pulp was developed. The model was based on the rate of chromophore destruction characterized by the decrease in the light absorption coefficient of bleached pulp at 457 nm, C_K. Based on the fact that the chromophore destruction proceeds rapidly in an initial phase followed by a much slower reaction during which a “floor-level” chromophore concentration is approached asymptotically, we propose that the hydrogen peroxide stage of the ALCELL® derived pulp in the studied TCF sequence consists of two distinct phases. The initial phase is a very fast reaction. The rate equation of the second phase was determined as: which is valid in a pH range of 10.5 to 11.5 and a temperature range of 60 to 92.5°C.     

An FAR-SW based approach for webpage information extraction

Automatically identifying and extracting the target information of a webpage, especially main text, is a critical task in many web content analysis applications, such as information retrieval and automated screen reading. However, compared with typical plain texts, the structures of information on the web are extremely complex and have no single fixed template or layout. On the other hand, the amount of presentation elements on web pages, such as dynamic navigational menus, flashing logos, and a multitude of ad blocks, has increased rapidly in the past decade. In this paper, we have proposed a statistics-based approach that integrates the concept of fuzzy association rules (FAR) with that of sliding window (SW) to efficiently extract the main text content from web pages. Our approach involves two separate stages. In Stage 1, the original HTML source is pre-processed and features are extracted for every line of text; then, a supervised learning is performed to detect fuzzy association rules in training web pages. In Stage 2, necessary HTML source preprocessing and text line feature extraction are conducted the same way as that of Stage 1, after which each text line is tested whether it belongs to the main text by extracted fuzzy association rules. Next, a sliding window is applied to segment the web page into several potential topical blocks. Finally, a simple selection algorithm is utilized to select those important blocks that are then united as the detected topical region (main texts). Experimental results on real world data show that the efficiency and accuracy of our approach are better than existing Document Object Model (DOM)-based and Vision-based approaches.     

铜陵一冶环保治理工程的设计

介绍冶炼烟气制本系统环保治理工程的工艺设计及生产运行情况。污水处理系统采用中和曝气加铁盐除砷工艺，引进了戈尔膜过滤器。尾气处理系统，采用石灰中和法，引进动波洗涤技术和关键设备。环保治理工程投产后，废气均达标排放。     

Integrated size and topology optimization of skeletal structures with exact frequency constraints

The present paper studies the integrated size and topology optimization of skeletal structures under natural frequency constraints. It is found that, unlike the conventional compliance-oriented topology optimization problems, the considered problem may be strongly singular in the sense that the corresponding feasible domain may be disconnected and the global optimal solutions are often located at the tips of some separated low dimensional sub-domains when the cross-sectional areas of the structural components are used as design variables. As in the case of stress-constrained topology optimization, this unpleasant behavior may prevent the gradient-based numerical optimization algorithms from finding the true optimal topologies. To overcome the difficulties posed by the strongly singular optima, some particular forms of area/moment of inertia-density interpolation schemes, which can restore the connectedness of the feasible domain, are proposed. Based on the proposed optimization model, the probability of finding the strongly singular optimum with gradient-based algorithms can be increased. Numerical examples demonstrate the effectiveness of the proposed approach.     

需求依赖于价格情境下基于Copula-CVaR 的报童决策

探讨价格不确定下,需求-价格相关性与风险态度对决策行为的影响.建立随机需求与随机价格相关情境下基于Copula-CVaR的报童决策模型,Copula函数描述相关性,条件风险价值(CVaR)反映风险态度,证明了模型解的存在性和惟一性.蒙特卡罗模拟发现,需求与价格的相关性与风险态度对决策的交互作用使决策行为发生规律性变化,决策者对价格波动有一定容忍度,需求与价格相关性趋于不相关与完全负相关时市场趋于同质性.     

新型不锈钢化学抛光剂工艺研究

叙述了一般不锈钢化学抛光溶液的基本类型和在实际应用中存在的问题。着重论述MW－6不锈钢化学抛光剂的工艺研究过程、工艺条件、质量指标及检测方法，同时介绍了它与传统不锈钢化学抛光剂的比较，经验价值，表面质量控制，应用领域及应用前景。     

Study on esterification of acrylic phenolic resin by maleic anhydride and photocrosslinking properties of the alkali‐soluble product

An alkali‐soluble, photocrosslinkable polymer was synthesized by esterification of OH groups of acrylic phenolic resin with maleic anhydride. The OH groups were formed by the ring‐opening reaction of epoxy groups of epoxy phenolic resin with acrylic acid. The esterification conditions were studied. The results showed that it is better to use tetramethyl ammonium bromide as catalyst than N,N‐dimethylbenzylamine. The conversion of maleic anhydride in acetone can reach about 80% at 56°C for 4 h. The purified product was characterized by IR, DSC, and TGA. The product containing acrylate and maleic acid monoester groups, above a certain content, can be dissolved in 1% Na₂CO₃ solution. The photocrosslinkable properties of the product were investigated through selection of photoinitiator, accelarator, crosslinkable diluent monomer, etc. The acrylate and maleic acid monoester group‐containing phenolic resin exhibited very good photocrosslinking behavior, since it contains double bonds from both acrylate groups and maleic acid monoester groups. The activity of photoinitiator decreases in the order: isopropylthioanthraquinone > benzoin ethyl ether (BE) > anthraquinone (AQ) > benzophenone > Michel ketone (MK) > 2,2‐diethoxyacetophenone. The combination of some photoinitiators showed synergistic effects. The order of increasing activity for the accelerator is as follows: MK > ethyl p‐(dimethylamino)benzoate > N,N‐dimethylaniline > triethanolamine. The optimum diluent monomer is trimethylolpropane trimethacrylate. The gel content of the mixture of the resin and trimethylolpropane trimethacrylate could reach 85% using the combined photoinitiators of BE and AQ under UV exposure for 120 s. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 1607–1614, 2005     

提高φ5m×11.5m生料磨产量的措施

针对粘土资源枯竭问题,江苏巨龙水泥集团实施了以粉煤灰和硅石代替粘土的技改工程。但改造后因原料的变更,导致入房物料易磨性变差而影响了φ5m×11.5m生料磨的产质量,并进一步影响察系统的运行。因此该厂在工艺分析的基础上,采取了调整钢球级配、用高铬球替代合金刚球、改造选粉机、加强石灰石二破的管理和减少系统是否是“漏风”等技术措施,效果显著。改造后的生料磨台时产量比调整前提高了12t/h,且节电效果显著。     

秋季太湖叶绿素a浓度荧光反演研究

基于2007年11~12月太湖全湖实测水质参数和光谱数据,首先利用高斯方程对遥感反射率进行过滤分解,找出叶绿素a(chl\|a)吸收峰675 nm以后的荧光反射峰(Fluorescence Peak:FP),再以662 nm处的反射率为基准,采用归一化荧光高度法进行叶绿素a浓度(C chl-a)反演,得到chl-a反演模型。基于高斯分解获取的chl-a的荧光反射峰值R(FP)与662 nm处的反射率R (662)比值［R(FP)/R(662)］与C chl-a之间存在显著的相关性,该模型为秋季太湖水体C chl-a的最佳反演模型。在高悬浮泥沙条件下,该模型能够较好地表示出叶绿素荧光高度与叶绿素浓度之间的关系,为C chl-a反演提供新的方法和依据,并为传感器敏感波段的选取和设置提供参考。     

Identification of organochlorines and organobromines in coals

Four Chinese bituminous coals were extracted with CS₂, n-hexane, benzene, methanol, acetone, tetrahydrofuran (THF) and THF/methanol (1: 3 vol/vol) mixed solvent sequentially. The resulting 28 extracts were analyzed with GC/MS. Six organochlorines (OCs) and two organobromines (OBs) were identified in eight extracts from the coals. Our experiments provide, for the first time, the information on the molecular structure of OCs and OBs in coals.