Luminescent properties of Sr2ZnSi2O7: Eu2+ phosphors prepared by combustion-assisted synthesis method

A blue-emitting phosphor Sr₂ZnSi₂O₇: Eu²⁺ was prepared by combustion-assisted synthesis method and an efficient blue emission under from ultraviolet to visible light was observed. The emission spectrum shows a single intensive band centered at 475?nm, which corresponds to the 4f⁶5d¹??4f⁷ transitions of Eu²⁺. The excitation spectrum is a broad band extending from 250 to 450?nm, which matches the emission of ultraviolet light-emitting diodes (UV-LEDs). The effect of doped Eu²⁺ concentration on the emission intensity of Sr₂ZnSi₂O₇: Eu²⁺ was also investigated and the corresponding concentration quenching mechanism is verified to be an electric multipole-multipole interaction.     

非平衡磁控溅射La-Ti/WS2 自润滑薄膜的摩擦磨损行为

要满足航天器机械转动部件在恶劣工况下的工作,需研制高硬度、低摩擦系数的固体润滑薄膜。采用非平衡磁控溅射法分别制备了纯WS₂薄膜、Ti掺杂WS₂复合薄膜和La-Ti掺杂WS₂复合薄膜。分析了薄膜的微观形貌、成分、硬度和摩擦学性能。结果表明,与纯WS₂薄膜和Ti/WS₂复合薄膜相比,La-Ti/WS₂复合薄膜的微观结构更加致密。La-Ti/WS₂复合薄膜的硬度H和弹性模量E也显著提高。此外,La-Ti/WS₂复合薄膜的摩擦系数减小,并且H/E比值增大,La-Ti/WS₂复合薄膜的磨损率降低。结果表明,La的掺杂有助于在摩擦接触表面形成稳定的转移膜,提高La-Ti/WS₂复合薄膜的耐磨性和承载能力。     

40Cr钢表面包埋渗Mo涂层组织及摩擦性能

热扩散渗钼(Mo)是钢材表面化学成分的改性方式之一,其可提高钢的淬透性,与碳作用形成高熔点的碳化物,能够提高钢铁材料表面的耐磨性。为探索热扩散渗钼工艺,分别采用箱式炉加热和感应加热对40Cr钢进行1 000～1 300℃不同温度下包埋扩散渗处理,利用场发射扫描电子显微镜(FEG-SEM)、X射线衍射技术(XRD)和摩擦磨损试验研究了渗Mo试样的微观组织、元素分布、物相构成以及摩擦磨损性能,并对感应加热渗Mo微观结构的演变机理进行了阐述。结果表明:在1 100℃下箱式炉加热未观察到明显的Mo渗层,而感应加热在不同温度下形成了30～70μm厚的Mo渗层;感应加热后试样截面组织由Mo渗层、过渡层、受影响层、基体组成,其中Mo渗层主要由Fe-Mo固溶体(Fe-Mo SS)和碳化物相组成,过渡层由合金珠光体组成,受影响层为贫碳区;研究表明感应加热Mo渗层的最高硬度为560 HV_(0.2),约为原始试样的两倍,IHM-1200试样的的摩擦因数为0.73,比原始试样低0.12,磨损质量略低于原始试样,Mo渗层显著提高40Cr钢的摩擦性能。     

Synthesis of Metal Oxides@C (Metal =Ni,Fe) Based Prussian Blue Analogs as a High-performance Anode Material for Lithium-ion Battery

Ni3[Fe(CN)6]2 nano-cubic precursors were prepared by chemical coprecipitation at room temperature with nickel acetate and potassium ferricyanide as raw materials.The corresponding NiFe2O4-NiO@C composites with excellent crystallization were prepared by two-stage oxidation at low temperature.The microstructure and electrochemical behavior of the materials showed that the Prussian blue analog was transformed into metal oxide while the carbon coating was maintained in the two-stage oxidation at low temperature.The existence of the carbon coating reduces the charge transfer impedance to 31.5 Ω.At the current density of 500 mA/g,the reversible capacity of 632.7 mAh/g is maintained after 500 cycles.At the same time,carbon cladding can also enhance the role of pseudocapacitance in the material.At the scanning rate of 0.1 mV/s,the pseudocapacitance account for 54.4％ of the total discharge capacity,which is significantly higher than that of uncoated materials.     

基于BP-PID的选择性激光烧结温度控制系统设计

为消除纯滞后系统的超调、改善温度因素对制件质量和强度的影响,设计一种基于BP-PID算法的选择性激光烧结温度控制系统.该系统采用层次化架构和模块化的设计方案,以STM32控制器作为主控模块,并利用BP神经网络改进传统比例-积分-微分(PID)算法,提高了控制系统的稳定性且效果显著.通过MATLAB进行仿真模拟,与传统PID控制进行对比并进行实验.结果表明:BP-PID算法能迅速整定最优参数,且超调量小,达到稳态所用时间更短;在设定预热温度为90℃且采用BP-PID算法控制时,系统稳态误差在±1℃之内,超调量小于3％.     

Fabrication of AgAu alloy-TiO2 core-shell nanoparticles and their photocatalytic properties

In this paper, for improving the photocatalytic efficiency of titania(TiO2) nanoparticles(NPs), Ag Au alloy-TiO2 core-shell NPs are fabricated via a sol-gel(SG) process in the presence of Ag Au alloy NPs with block copolymer shells as templates. The photocatalytic activities of the Ag Au-TiO2 NPs on the photodecomposition of methylene blue(MB) are investigated. The Ag Au-TiO2 composite NPs coated with 5.0% titania related to block copolymers show higher photocatalytic activity than the other samples in which the titania contents are larger than 5.0%. The results indicate that the increase of the thickness of the TiO2 shell leads to the decrease of the photocatalytic activity.     

一款高性能时钟驱动器电路的设计

时钟器件芯片可以实现通信网定时同步、时钟产生、时钟恢复和抖动滤除、频率合成和转换、时钟分发和驱动等功能。在系统设计中,选用好的时钟驱动芯片,可以省去系统时钟树设计,既节省空间,又提高系统性能。介绍一款高性能时钟驱动器的集成电路设计方法,主要性能要求有:低传播延时、低输出偏斜、低输出抖动、抗电磁干扰能力、抗ESD能力,一一详述了达到各项要求的设计。     

双馈感应发电机Crowbar电路的投切控制策略优化研究

研究了Crowbar投入、退出时间对双馈感应风力发电机低电压穿越性能的影响,并在Matlab/Simulink仿真平台上搭建了含Crowbar保护电路的DFIG模型,验证了Crowbar投切时间对DFIG低电压穿越的影响,保证故障发生时,Crowbar电路按设定的投切时间工作,短路电流能根据电流的变化规律快速衰减,转子电阻电压不超过直流母线电压;采用阈值投入延时切出的方案,防止Crowbar保护在电网故障时多次投切。仿真结果表明,经过适当的延时切除Crowbar电路可以避免Crowbar电路多次动作和转子再次过电流,能很好地保护风电机组,提高其低电压穿越能力。结果显示,低电压穿越效果很大程度上受退出时间影响。