Molecular Heterojunctions of Oligo(phenylene ethynylene)s with Linear to Cruciform Framework

Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO–LUMO energy gaps. OPE3, OPE3–DTF, and OPE3–tetrathiafulvalene (TTF) can form good self‐assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe–atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3–TTF > OPE3–DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero‐bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.     

Effect of dietary fat on phospholipid class distribution and fatty acid composition in rat fat cell plasma membrane

The effect of dietary fats on phospholipid class distribution and fatty acid composition was studied in rat fat cell plasma membrane. Three groups of male Wistar weanling rats were fed for 8 wk three diets differing in the amount and nature of the fats: 1.5% sunflower oil (low fat control; LFC), 10% sunflower oil (high fat, unsaturated; HFU), 1.5% sunflower oil+8.5% cocoa butter (high fat, saturated; HFS). Plasma membranes were prepared from epididymal adipocytes. The amount and type of dietary fat significantly altered membrane phospholipid distribution. Phospholipid content was lowered with HFU as compared to LFC or HFS diets, but no changes were observed for cholesterol. Phosphatidylinositol (PI) and phosphatidylserine (PS) were less affected by dietary changes than were other phospholipid classes. Major changes were detected for phosphatidylcholine (PC), phosphatidylethanolamine (PE) and sphingomyelin (SM) contents. No large changes in PC and PE fatty acid compositions were observed between the LFC and HFS groups, but the HFU diet induced several changes. Correlations with plasma membrane 5′-nucleotidase activities are discussed.     

The impact of alkali elements on the degradation of CIGS solar cells

Unencapsulated CIGS solar cells with high and low contents of sodium (Na) and potassium (K) were simultaneously exposed to damp heat and illumination. The solar cells with a high alkali (Na, K) content exhibited higher initial conversion efficiencies, but degraded severely within 100 h, while the alkali poor samples kept relatively stable performance under damp heat and illumination. The degradation of the samples with a high alkali content resulted in the formation of sodium rich spots on the top ZnO:Al surface of the samples. This is likely caused by light‐induced Na⁺ migration via the grain boundaries in the absorber to the depletion region, where the Na⁺ accumulated. This allowed subsequent Na⁺ transport through the depletion region due to the lowering of the internal electric field caused both by the Na⁺ accumulation and illumination. The migration resulted in the formation of shunt paths, which reduced the shunt resistance and open circuit voltage. Furthermore, ingression of water into the ZnO:Al is expected to be responsible for a slow but steady increase in series resistance for both high and low alkali solar cells. Additionally, sodium migration led to a severe increase of the series resistance in case of alkali rich samples. Copyright © 2015 John Wiley & Sons, Ltd.     

Clinical evaluation of respiratory motion compensation for anatomical roadmap guided cardiac electrophysiology procedures

X-ray fluoroscopically guided cardiac electrophysiological procedures are routinely carried out for diagnosis and treatment of cardiac arrhythmias. X-ray images have poor soft tissue contrast and, for this reason, overlay of static 3-D roadmaps derived from preprocedural volumetric data can be used to add anatomical information. However, the registration between the 3-D roadmap and the 2-D X-ray image can be compromised by patient respiratory motion. Three methods were designed and evaluated to correct for respiratory motion using features in the 2-D X-ray images. The first method is based on tracking either the diaphragm or the heart border using the image intensity in a region of interest. The second method detects the tracheal bifurcation using the generalized Hough transform and a 3-D model derived from 3-D preoperative volumetric data. The third method is based on tracking the coronary sinus (CS) catheter. This method uses blob detection to find all possible catheter electrodes in the X-ray image. A cost function is applied to select one CS catheter from all catheter-like objects. All three methods were applied to X-ray images from 18 patients undergoing radiofrequency ablation for the treatment of atrial fibrillation. The 2-D target registration errors (TRE) at the pulmonary veins were calculated to validate the methods. A TRE of 1.6 mm ± 0.8 mm was achieved for the diaphragm tracking; 1.7 mm ± 0.9 mm for heart border tracking, 1.9 mm ± 1.0 mm for trachea tracking, and 1.8 mm ± 0.9 mm for CS catheter tracking. We present a comprehensive comparison between the techniques in terms of robustness, as computed by tracking errors, and accuracy, as computed by TRE using two independent approaches.     

A meshless method for solving the EEG forward problem

We present a numerical method to solve the quasistatic Maxwell equations and compute the electroencephalography (EEG) forward problem solution. More generally, we develop a computationally efficient method to obtain the electric potential distribution generated by a source of electric activity inside a three-dimensional body of arbitrary shape and layers of different electric conductivities. The method needs only a set of nodes on the surface and inside the head, but not a mesh connecting the nodes. This represents an advantage over traditional methods like boundary elements or finite elements since the generation of the mesh is typically computationally intensive. The performance of the proposed method is compared with the boundary element method (BEM) by numerically solving some EEG forward problems examples. For a large number of nodes and the same precision, our method has lower computational load than BEM due to a faster convergence rate and to the sparsity of the linear system to be solved.     

A Cross-Layer Approach to Enhance QoS for Multimedia Applications Over Satellite

The need for on-demand QoS support for communications over satellite is of primary importance for distributed multimedia applications. This is particularly true for the return link which is often a bottleneck due to the large set of end-users accessing a very limited uplink resource. Facing this need, Demand Assignment Multiple Access (DAMA) is a classical technique that allows satellite operators to offer various types of services, while managing the resources of the satellite system efficiently. Tackling the quality degradation and delay accumulation issues that can result from the use of these techniques, this paper proposes an instantiation of the Application Layer Framing (ALF) approach, using a cross-layer interpreter (xQoS-Interpreter). The information provided by this interpreter is used to manage the resource provided to a terminal by the satellite system in order to improve the quality of multimedia presentations from the end user’s point of view. Several experiments are carried out for different loads on the return link. Their impact on QoS is measured through different application as well as network level metrics.

Catalyst Design by NH4OH Treatment of USY Zeolite

Hierarchical zeolites are a class of superior catalysts which couples the intrinsic zeolitic properties to enhanced accessibility and intracrystalline mass transport to and from the active sites. The design of hierarchical USY (Ultra‐Stable Y) catalysts is achieved using a sustainable postsynthetic room temperature treatment with mildly alkaline NH₄OH (0.02 m ) solutions. Starting from a commercial dealuminated USY zeolite (Si/Al = 47), a hierarchical material is obtained by selective and tuneable creation of interconnected and accessible small mesopores (2–6 nm). In addition, the treatment immediately yields the NH₄⁺ form without the need for additional ion exchange. After NH₄OH modification, the crystal morphology is retained, whereas the microporosity and relative crystallinity are decreased. The gradual formation of dense amorphous phases throughout the crystal without significant framework atom leaching rationalizes the very high material yields (>90%). The superior catalytic performance of the developed hierarchical zeolites is demonstrated in the acid‐catalyzed isomerization of α‐pinene and the metal‐catalyzed conjugation of safflower oil. Significant improvements in activity and selectivity are attained, as well as a lowered susceptibility to deactivation. The catalytic performance is intimately related to the introduced mesopores, hence enhanced mass transport capacity, and the retained intrinsic zeolitic properties.     

Recovering missing slices of the discrete fourier transform using ghosts

The discrete Fourier transform (DFT) underpins the solution to many inverse problems commonly possessing missing or unmeasured frequency information. This incomplete coverage of the Fourier space always produces systematic artifacts called Ghosts. In this paper, a fast and exact method for deconvolving cyclic artifacts caused by missing slices of the DFT using redundant image regions is presented. The slices discussed here originate from the exact partitioning of the Discrete Fourier Transform (DFT) space, under the projective Discrete Radon Transform, called the discrete Fourier slice theorem. The method has a computational complexity of O(nlog(2)n) (for an n=N×N image) and is constructed from a new cyclic theory of Ghosts. This theory is also shown to unify several aspects of work done on Ghosts over the past three decades. This paper concludes with an application to fast, exact, non-iterative image reconstruction from a highly asymmetric set of rational angle projections that give rise to sets of sparse slices within the DFT.     

Complex permittivity characterization of benzocyclobutene for terahertz applications

High-quality polymers such as the benzocyclobutene polymer (BCB) provide interesting dielectric feature for terahertz applications. Already used in silicon integrated circuit technologies, this material could become one of the most promising candidates for the realization of future THz waveguides and interconnections on a silicon substrate but also after active devices process on the top of any other technology (GaAs, InP, GaN…). A frequency-dependent complex permittivity of spin-coated thick layers of this low-k dielectric is obtained from transmittance spectra measured with Fourier transform spectroscopy in the frequency range of 0.5-5.4 THz. The dielectric constant and the loss tangent are discussed according to curing conditions of the photosensitive resin used. A low loss tangent value of 7 − 9 × 10^-3 at 1 THz is obtained with polymerisation in oxygen-free atmosphere. An incomplete curing and a high dose UV exposure have a weak impact on losses. These results associated with the high compatibility of this polymer with silicon and metals make BCB layers well suited for the design of microelectronic THz devices and circuits.     

Incumbency Bonus in Election News Coverage Explained: The Logics of Political Power and the Media Market

This article investigates the determinants of the incumbency bonuses in news coverage. Two main factors are identified: the distribution of political power and changes in the media market. To test these assumptions, a content analysis of the news coverage of 5 national election campaigns in Denmark was conducted (4,592 news stories). First, the more unevenly political power is distributed, the more visible the government is. Second, results suggest a trade‐off between the incumbency bonus and the coverage of nonsubstantive issues. Third, changes in news coverage seem to be more driven by changes in the political system than by changes in the media market. Finally, it is discussed how future research can further our understanding of political imbalances in news coverage.