Modelling a circulating fluidized bed riser reactor with gas—solids downflow at the wall

A predictive model was developed for the fully developed zone of a circulating fluidized bed (CFB) riser reactor operating in the fast fluidization regime that overcomes limitations of existing models. The model accounts for the upward flow of gas and solids in the core and downward flow of the two phases in the annulus. Additionally, a numerical solution methodology for the simulation of a riser reactor employing the hydrodynamic model was devised. A simulation was performed using the fast, main Claus reaction to demonstrate the effects of backmixing in the fast fluidization regime. It was found that the molar flow rates of the reactants leaving a fast fluidized CFB riser reactor were significantly higher than those leaving an identical reactor operating in the pneumatic transport regime.     

A genetic tango attack against the David–Prasad RFID ultra‐lightweight authentication protocol

Radio frequency identification (RFID) is a powerful technology that enables wireless information storage and control in an economical way. These properties have generated a wide range of applications in different areas. Due to economic and technological constrains, RFID devices are seriously limited, having small or even tiny computational capabilities. This issue is particularly challenging from the security point of view. Security protocols in RFID environments have to deal with strong computational limitations, and classical protocols cannot be used in this context. There have been several attempts to overcome these limitations in the form of new lightweight security protocols designed to be used in very constrained (sometimes called ultra‐lightweight) RFID environments. One of these proposals is the David–Prasad ultra‐lightweight authentication protocol. This protocol was successfully attacked using a cryptanalysis technique named Tango attack. The capacity of the attack depends on a set of boolean approximations. In this paper, we present an enhanced version of the Tango attack, named Genetic Tango attack, that uses Genetic Programming to design those approximations, easing the generation of automatic cryptanalysis and improving its power compared to a manually designed attack. Experimental results are given to illustrate the effectiveness of this new attack.     

The Shape Boltzmann Machine: A Strong Model of Object Shape

A good model of object shape is essential in applications such as segmentation, detection, inpainting and graphics. For example, when performing segmentation, local constraints on the shapes can help where object boundaries are noisy or unclear, and global constraints can resolve ambiguities where background clutter looks similar to parts of the objects. In general, the stronger the model of shape, the more performance is improved. In this paper, we use a type of deep Boltzmann machine (Salakhutdinov and Hinton, International Conference on Artificial Intelligence and Statistics, 2009) that we call a Shape Boltzmann Machine (SBM) for the task of modeling foreground/background (binary) and parts-based (categorical) shape images. We show that the SBM characterizes a strong model of shape, in that samples from the model look realistic and it can generalize to generate samples that differ from training examples. We find that the SBM learns distributions that are qualitatively and quantitatively better than existing models for this task.     

Characterisation of the adsorption sites of hydrogen on Pt/C fuel cell catalysts

A key component of a hydrogen fuel cell is a catalyst to dissociate dihydrogen to hydrogen atoms. In the present study, the adsorption of hydrogen on Pt/C fuel cell catalysts has been investigated by inelastic neutron scattering spectroscopy.

Monitoring a clean Pt(50%)/C catalyst with low energy neutron spectroscopy, after exposure to dihydrogen at 20 K, as it was heated to room temperature, showed three distinct temperature regimes: (i) a decrease in intensity from 10 to 60 K, (ii) a rise to a maximum between 60 and 120 K and then (iii) a slow fall-off towards room temperature. We assign the three regions as: (i) desorption of physisorbed dihydrogen, (ii) dissociation of dihydrogen to give an adsorbed layer and (iii) damping of the response by an increasing Debye–Waller factor.

The vibrational INS spectra of a series of Pt/C catalysts prepared under varying conditions were similar indicating that the same types of site are common to all the catalysts, although the relative proportions of each site are sample dependent. Features at 520, 950 and part of the intensity at 1300 cm⁻¹ are assigned to hydrogen on (1 1 1) faces, in good agreement with single crystal data. The mode at 640 cm⁻¹ is assigned as the doubly degenerate asymmetric stretch of Pt(1 0 0) faces with the symmetric stretch near 550 cm⁻¹.

We assign the bending mode of the on-top site to the feature at 470 cm⁻¹. The Pt–H stretch mode was observed at 2079 cm⁻¹. This is a significant result: this is the first time that hydrogen on the on-top sites has been observed on nanosized platinum particles supported on high surface area carbon black. The width of the INS peak is surprisingly large and may give additional information on the type and relative proportions of the crystallographic faces present on the catalyst particles.     

SORPTION EQUILIBRIUM OF COPPER BY PARTIALLY-COAGULATED CALCIUM ALGINATE GEL

The sorption equilibrium of dissolved copper by spherical partially-coagulated gels of calcium alginate was investigated in this work. The gels were formed by dispensing a viscous algin (food grade sodium alginate from kelp) solution with a multi-tip dispenser into 0.05 M CaCl₂ solution in a loop fluidized bed reactor. The resultant semi-rigid spherical gels were then transferred to another reactor operated batch wise to absorb dissolved copper at low concentrations (10-40 ppm). When the concentration of the inert neutral salt NaNO₃, added to the reactor fluid was 0.01 M, the amount of copper absorbed was found to be substantially higher than that at 0.1 MNaN0₃. The conventional Langmuir's model based on the concentration of copper in solution yielded different values of conditional stability constant at different ionic strengths in the reactor fluid. However, by defining the copper-binding stability constant on the basis of copper activity in the gel phase with the competition from calcium for metal binding sites taken into account, a unique copper-binding stability constant and a unique calcium-binding stability constant were obtained. The numerical procedure for estimating the activity of copper in the gel fluid was modified from Jang et al. Water Research, 1990, in press).     

Vectorising Bitmaps into Semi‐Transparent Gradient Layers

We present an interactive approach for decompositing bitmap drawings and studio photographs into opaque and semi‐transparent vector layers. Semi‐transparent layers are especially challenging to extract, since they require the inversion of the non‐linear compositing equation. We make this problem tractable by exploiting the parametric nature of vector gradients, jointly separating and vectorising semi‐transparent regions. Specifically, we constrain the foreground colours to vary according to linear or radial parametric gradients, restricting the number of unknowns and allowing our system to efficiently solve for an editable semi‐transparent foreground. We propose a progressive workflow, where the user successively selects a semi‐transparent or opaque region in the bitmap, which our algorithm separates as a foreground vector gradient and a background bitmap layer. The user can choose to decompose the background further or vectorise it as an opaque layer. The resulting layered vector representation allows a variety of edits, such as modifying the shape of highlights, adding texture to an object or changing its diffuse colour.     

Parallelised production of fine and calibrated emulsions by coupling flow-focusing technique and partial wetting phenomenon

The capacity of microfluidic technology to fabricate monodisperse emulsion droplets is well established. Parallelisation of droplet production is a prerequisite for using such an approach for making high-quality materials for either fundamental or industrial applications where product quantity matters. Here, we investigate the emulsification efficiency of parallelised drop generators based on a flow-focusing geometry when incorporating the role of partial wetting in order to make emulsion droplets with a diameter below 10 μm. Confinement intrinsically encountered in microsystems intensifies the role played by interfaces between liquids and solids. We thus take advantage of partial wetting to enhance the maximum confinement accessible due to liquid flow focusing. We compare the performances brought by partial wetting to more established routes such as step emulsification. We show that the step configuration and the partial wetting regime are both well suited for being parallelised and thus open the way to the production of fine and calibrated emulsions for further applications. Finally, this new route of emulsification that exploits partial wetting between the fluids and the channel walls opens possibilities to the formation of substantially smaller droplets, as required in many fields of application.     

Mobile digcovery: discovering and interacting with the world through the Internet of things

The application of Internet-enabled devices in the real world for the development of Smart Cities, environmental monitoring, bus tracking, and parking requires scalability, extensibility, and integration of emerging resources to reach a suitable ecosystem for data acquisition and interaction with citizens. Internet of things needs to offer efficient support for global communications and access to services and information. It needs to enable homogeneous and seamless machine-to-machine communication for different solutions and applications. This work presents an homogeneous and suitable mechanism for global resource discovery, device access for deployed smart objects in different scenarios, and sensors and devices from end users (participative sensing). The integration of legacy and sensors already available from smart buildings and smart objects is presented. For this purpose, a resolution infrastructure called “digcovery” is defined for maximizing efficiency and sustainability of deployments. Digcovery architecture offers the framework to allow users to register/include their own sensors into a common infrastructure and access/discover the available resources through mobile digcovery. Mobile digcovery exploits the context-awareness, geo-location, and identification technologies available in mobile platforms such as smartphones to discover, interact, and access the resources through its ElasticSearch engine.     

The Yuma Desalting Plant

The 96 million gallon per day Yuma desalting plant is part of a complex project intended to solve a long standing water quality problem between the United States and Mexico. Designed to treat up to 129,000 acre-feet of 3200 mg/l irrigation return flows, the plant will deliver 283 mg/l product water to maintain a 115 mg/l differential between water delivered to U.S. users and to Mexico .

Design of the plant was preceded by an extensive research program to determine pretreatment requirements, membrane performance, plant capacity and equipment and instrumentation performance. Two pretreatment systems were tested. Partial lime softening followed by multi-media filtration was chosen for the final design. Nine membrane systems (both reverse osmosis and electrodialysis) were tested. Two spiral wound reverse osmosis systems were chosen as most efficient from physical and economic viewpoint, and contracts for site preparation and construction of the intakes and sedimentation basin is scheduled for award summer 1979 with construction of the main plant and installation of desalting equipment scheduled for award summer of 1980.

Based on January 1979 prices, total cost of the desalting complex is approximately $190 million (including interest during construction). The investment cost per daily gallon of installed capacity is approximately $2. per 1000 gallons of desalted water (capital amortization plus operation and maintenance) is $0.77.     

Preparation of optically active poly β-propiolactones

Racemic -methyl--n-propyl--propiolactone is readily polymerized with zinc and cadmium chiral glycolates leading to optically active polyesters. The stereoelectivities observed are lower than for oxiranes and thiiranes with the same initiator system. A value of rotatory power for pure enantiomer _o, is deduced from NMR measurements in the presence of chiral solvent. The structure of polymers is discussed on the basis of NMR results.