Relation between microstructure and glass transition temperature of poly[(methyl methacrylate)‐co‐(ethyl acrylate)]

The glass transition temperature of a series of samples of the poly[(methyl methacrylate)‐co‐(ethyl acrylate)] copolymer, synthesized at low conversion, were calculated theoretically using the equations of Barton and Johnston. The values obtained are more precise when the probabilities of the compositional diads are derived from the ¹³C NMR data instead of the classical method utilizing reactivity ratios. This can be observed more clearly when the copolymer samples are synthesized at high conversion. Introduction of configuration (tacticity) at the diad level confirms the above observations and slightly improves the calculated values of T_g compared to the initial formulae which were only taking into account the compositional sequences of the copolymer. © 2001 Society of Chemical Industry     

Compression de données brutes et d’images de radar à synthèse d’ouverture

This paper draws a state of the art of synthetic aperture radar (sar) data compression. Both raw data and synthesized image compression have been investigated. Compression of radar raw signal and sar image are considered separately since those two cases are specific. Also, Radar raw/image compression remains different from optical image compression and has to be considered with specific strategies that are adapted to the context.     

Polyvinylidene fluoride nanofibers obtained by electrospinning and blowspinning: Electrospinning enhances the piezoelectric β-phase – myth or reality?

Considerable effort has been devoted to improving the properties of PVDF (polyvinylidene fluoride), arguably the most technologically important piezoelectric polymer. Electrospinning has been found to be a particularly effective method of producing PVDF nanofibers with superior piezoelectric properties due to the resulting exceptionally high fraction of the piezoelectrically active crystalline β-phase. It is typically assumed that the high external electric fields applied during electrospinning enhance the formation of this β-phase, with the confused literature offering various unsatisfactory mechanistic explanations. However, by comparing PVDF nanofibers produced by two different processes (electrospinning and blowspinning), we show that the electric field is entirely unnecessary; indeed, the crystallization dynamics are principally driven by the applied mechanical stress, as evidenced by structurally identical 200 nm diameter PVDF fibers produced with and without external electric fields.     

Digital narrative conventions in heritage trail mobile apps

ABSTRACT

Galleries, libraries, archives and museums (GLAMs) are increasingly using digital technologies for storytelling and creating mobile applications (apps) for cultural heritage content, but how apps are used in practice to communicate information to users has not been widely studied. A team of people from a heritage organisation, a university, and mobile app development group plan to create a bespoke heritage trail app for Ireland, but to date design conventions/recommendations for this genre are lacking. This article applies a systematic approach to digital narrative content analysis to better understand how apps are being used specifically for heritage trails with the aim of identifying what the common features are, which modalities and narrative techniques are used. The selected corpus included 55 apps downloaded from the Google Play Store. The results of this content analysis—based on the App Walkthrough Method (Light, B., Burgess, J., & Duguay, S. (2018). The walkthrough method: An approach to the study of apps. New Media & Society, 20(3), 881–900)—show that there is a gap between academic research themes/trends and how digital narrative is actually being communicated in the current market, and it aims to inform the future development of heritage trail apps by including a list of design and content features common to this genre.     

Fluorescent Nanodiamonds Embedded in Biocompatible Translucent Shells

High pressure high temperature (HPHT) nanodiamonds (NDs) represent extremely promising materials for construction of fluorescent nanoprobes and nanosensors. However, some properties of bare NDs limit their direct use in these applications: they precipitate in biological solutions, only a limited set of bio‐orthogonal conjugation techniques is available and the accessible material is greatly polydisperse in shape. In this work, we encapsulate bright 30‐nm fluorescent nanodiamonds (FNDs) in 10–20‐nm thick translucent (i.e., not altering FND fluorescence) silica shells, yielding monodisperse near‐spherical particles of mean diameter 66 nm. High yield modification of the shells with PEG chains stabilizes the particles in ionic solutions, making them applicable in biological environments. We further modify the opposite ends of PEG chains with fluorescent dyes or vectoring peptide using click chemistry. High conversion of this bio‐orthogonal coupling yielded circa 2000 dye or peptide molecules on a single FND. We demonstrate the superior properties of these particles by in vitro interaction with human prostate cancer cells: while bare nanodiamonds strongly aggregate in the buffer and adsorb onto the cell membrane, the shell encapsulated NDs do not adsorb nonspecifically and they penetrate inside the cells.     

Morphology,mechanical properties and electromagnetic shielding effectiveness of poly(styrene‐b‐ethylene‐ran‐butylene‐b‐styrene)/carbon nanotube nanocomposites: effects of maleic anhydride,carbon nanotube loading and processing method

Nanocomposites based on poly(styrene‐b‐ethylene‐ran‐butylene‐b‐styrene) (SEBS) and carbon nanotubes (CNTs) (SEBS/CNT) as well as SEBS grafted with maleic anhydride (SEBS‐MA)/CNT were successfully prepared for electromagnetic shielding applications. Both SEBS/CNT and SEBS‐MA/CNT nanocomposites were prepared by melt compounding and were post‐processed using two different techniques: tape extrusion and compression moulding. The different nanocomposites were characterized by Raman spectroscopy and rheological analysis. Their mechanical properties, electrical properties (10^-2–10⁵ Hz) and electromagnetic shielding effectiveness (8.2–12.4 GHz) were also evaluated. The results showed that the CNT loading amount, the presence of MA in the matrix and the shaping technique used strongly influence the final morphologies and properties of the nanocomposites. Whilst the nanocomposite containing 8 wt% CNTs prepared by compression moulding presented the highest electromagnetic shielding effectiveness (with a value of 56.73 dB, which corresponds to an attenuation of 99.9996% of the incident radiation), the nanocomposite containing 5 wt% CNTs prepared by tape extrusion presented the best balance between electromagnetic and mechanical properties and was a good candidate to be used as an efficient flexible electromagnetic interference shielding material. © 2018 Society of Chemical Industry     

Lotka's law reconsidered: The evolution of publication and citation distributions in scientific fields

This paper reports early steps in research that seeks to clarify how publications of scientists interact dynamically with citations and reputation in shaping the evolution of scientific fields. We assume that Lotka's modified law holds for scientific fields. A primary approach to model publication productivity was published by Yablonsky. In contrast to Yablonsky's unfinished mathematical approach, our simulation approach is not predominantly driven by insight into the formal generation mechanisms of certain processes but more theory driven. It considers the evolution of publication and citation distributions over the histories of scientific fields using both simulated and real historical data.     

Examining infants' preferences for tempo in lullabies and playsongs.

Caregivers around the world sing to their infants. Infants not only prefer to listen to infant-directed singing over adult-directed singing, but infant-directed singing also serves a function, communicating affective information to preverbal infants to aid in adjusting arousal levels. Pitch variation has previously been identified as one performance feature that may help to convey the message. Earlier research has indicated that infants' pitch preferences are context dependent, suggesting that infants are tuned in to the communicative intent of infant-directed singing. However, there are several other performance-based features present in infant-directed singing that may also contribute to the affective message. The current study examined the role of context on infants' tempo preferences in sung playsongs and lullabies. Using a head-turn preference procedure, we measured 24 preverbal infants' natural preferences for foreign language playsongs and lullabies as a function of tempo. Infants showed a preference for fast over slow tempo playsongs, but no such context dependent preference was found within lullabies. Results partially support the role of tempo as a communicative feature of infant directed singing. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Das Payback-Urteil des BGH

Der BGH hat am 16.07.2008 (DuD 2008, 751) die Einwilligungsl?sung für die Zusendung von Werbung per Post, SMS oder E-Mail von Unternehmen an Kunden im Zusammenhang mit der Kundenkarte Payback bewertet. Als Konsequenz ist nun der Gesetzgeber gefordert, einen einheitlichen Einwilligungsstandard festzulegen.