Leak-before-break analysis of Prototype Fast Breeder Reactor main vessel

In Prototype Fast Breeder Reactor, the core is immersed in a sodium pool contained within the main vessel (MV). There is an argon cover gas space over the sodium. Top Shield supports the control plug which houses important components such as Control and Safety Rod Driving Mechanism. A core support structure welded to the bottom of MV carries the Grid plate which in turn supports the fuel subassemblies. MV is a cylindrical shell with a bottom dished end and supported at the top. Double ended guillotine rupture of MV will lead to downward movement of the core, which is in effect equivalent to withdrawal of control and safety rod and thus causing a series safety concern. It is essential to demonstrate Leak Before Break (LBB) argument for MV. LBB argument is justified if leak detection is ensured with adequate margin on critical crack length corresponding to failure by tearing instability. The material of construction of MV is SS316 LN. Towards assuring the justification of LBB argument, an isolated 5 mm deep X 200 mm long semi elliptical flaw is taken as the initial flaw and analysed under fatigue loading. A through wall crack in the argon space can be detected by sampling the nitrogen in the annular space between MV and safety vessel surrounding it. Accordingly the detectable crack length is arrived at. The critical crack length is obtained considering stable tearing. More details of the analysis and justification of LBB argument as per RCC-MR Appendix A16 are presented in the paper.     

Shock deformation of coarse grain alumina above Hugoniot elastic limit

Symmetric shock experiments were conducted on a 10 μm grain size coarse alumina ceramic with a gas gun to identify its Hugoniot elastic limit (HEL). To understand the damage initiation and their subsequent growth mechanisms in coarse grain alumina subjected to shock impact at levels much above the HEL, additional asymmetric shock recovery experiments with the same gas gun were then deliberately conducted on the same alumina at shock pressure levels more than three times as high as the HEL and the fragments collected by a dedicated catcher system. Detailed characterization of the shock recovered alumina fragments by X-ray diffraction, nanoindentation, scanning electron microscopy, field emission scanning electron microscopy and transmission electron microscopy were utilized to understand the nature and process of failure initiation, incubational growth, coalescence and propagation leading to fragmentation. Based on these data a new qualitative damage model was developed to explain the deformation mechanism.     

Effect of amount, size, and spatial distribution of intermetallics on incipient localization during plastic deformation

Virtual microstructures having a systematic variation of amount, mean size, standard deviation of size, and spatial arrangement of intermetallics have been synthesized, and their deformation behavior in uniaxial tension has been evaluated using finite element analysis. Four spatial arrangements of intermetallics have been considered in this work, namely: random, clustered, and two-ordered structures. Various mathematical quantities have been developed to quantify the severity of deformation including plastic work density distribution (PWDD), percentile work-density volume criterion (PWC), and percentile stress volume criterion (PSC). This approach eliminates the need for an external trigger in FEA to achieve localization. The method developed has led to a better understanding of the effect of different microstructural attributes on the process of deformation. This has resulted in guidelines for optimizing the microstructure to minimize material damage and thereby maximize ductility.     

Health and wellness monitoring through wearable and ambient sensors: exemplars from home-based care of elderly with mild dementia

Monitoring and timely intervention are extremely important in the continuous management of health and wellness among all segments of the population, but particularly among those with mild dementia. In relation to this, we prescribe three design principles for the construction of services and applications. These are ambient intelligence, service continuity, and micro-context. In this paper, we provide three exemplars from our research and development activities that illustrate the use of these design principles in the construction of services and applications. All the applications are drawn from the field of care for mild dementia patients in their living quarters.     

Design and performance study of phase‐locked loop using fractional‐order loop filter

The present work reports the realization of an analog fractional‐order phase‐locked loop (FPLL) using a fractional capacitor. The expressions for bandwidth, capture range, and lock range of the FPLL have been derived analytically and then compared with the experimental observations using LM565 IC. It has been observed that bandwidth and capture range can be extended by using FPLL. It has also been found that FPLL can provide faster response and lower phase error at the time of switching compared to its integer‐order counterpart. Copyright © 2014 John Wiley & Sons, Ltd.     

Elucidation of the Clustered Nano-Architecture of Radiation-Induced DNA Damage Sites and Surrounding Chromatin in Cancer Cells: A Single Molecule Localization Microscopy Approach

In cancer therapy, the application of (fractionated) harsh radiation treatment is state of the art for many types of tumors. However, ionizing radiation is a “double-edged sword”—it can kill the tumor but can also promote the selection of radioresistant tumor cell clones or even initiate carcinogenesis in the normal irradiated tissue. Individualized radiotherapy would reduce these risks and boost the treatment, but its development requires a deep understanding of DNA damage and repair processes and the corresponding control mechanisms. DNA double strand breaks (DSBs) and their repair play a critical role in the cellular response to radiation. In previous years, it has become apparent that, beyond genetic and epigenetic determinants, the structural aspects of damaged chromatin (i.e., not only of DSBs themselves but also of the whole damage-surrounding chromatin domains) form another layer of complex DSB regulation. In the present article, we summarize the application of super-resolution single molecule localization microscopy (SMLM) for investigations of these structural aspects with emphasis on the relationship between the nano-architecture of radiation-induced repair foci (IRIFs), represented here by γH2AX foci, and their chromatin environment. Using irradiated HeLa cell cultures as an example, we show repair-dependent rearrangements of damaged chromatin and analyze the architecture of γH2AX repair clusters according to topological similarities. Although HeLa cells are known to have highly aberrant genomes, the topological similarity of γH2AX was high, indicating a functional, presumptively genome type-independent relevance of structural aspects in DSB repair. Remarkably, nano-scaled chromatin rearrangements during repair depended both on the chromatin domain type and the treatment. Based on these results, we demonstrate how the nano-architecture and topology of IRIFs and chromatin can be determined, point to the methodological relevance of SMLM, and discuss the consequences of the observed phenomena for the DSB repair network regulation or, for instance, radiation treatment outcomes.     

Three‐body abrasive wear behavior of short jute fiber reinforced epoxy composites

In present investigation, the three‐body abrasive wear behavior of short jute fiber reinforced epoxy composites was studied. The effect of various parameters such as fiber loading, sliding velocity, normal load, and abrasive size on the abrasive wear rate of composite has been analyzed. Abrasive wear study has been carried out using a dry sand/rubber wheel abrasion tester. The abrasive wear and friction characteristics of these composites are analyzed successfully using Taguchi orthogonal array and analysis of variance. The experimental study reveals that sliding velocity, fiber loading, and abrasive size have greater influence on the specific wear rate of the composites. The results show that the specific wear rate of the composites decreases with the increase in sliding velocity whereas, with the increase in normal load the specific wear rate increases. The study also revealed that the coefficient of friction of the composites increases up to a certain value than decreases with the increase in normal load as well as sliding velocity. The worn surfaces of the abraded specimens were examined using SEM to understand the mechanism involved in material removal. POLYM. COMPOS., 270–278, 2016. © 2014 Society of Plastics Engineers     

Synthesis and characterization of a novel Ca-alginate-biochar composite as efficient zinc (Zn2+) adsorbent: Thermodynamics,process design,mass transfer and isotherm modeling

In this present work, Ca-alginate-biochar adsorbent has been synthesized, characterized and tested its effectiveness in the removal of aqueous phase Zn²⁺ metal. The removal efficiency was studied under various physicochemical process parameters. External mass transfer model, intraparticle diffusion model and pseudo-first-order and pseudo-second-order models were used to fit the experimental Zn²⁺ adoption kinetic results and to identify the mechanism of adsorption. The desorption studies indicate the possibilities of ion-exchange and physical–chemical adsorption of Zn^2+. The adsorption was best described by Langmuir isotherm model. Thermodynamic parameters suggested that the adsorption process becomes spontaneous, endothermic and irreversible in nature.     

Gas holdup in tapered bubble column using pseudoplastic non-Newtonian liquids

Experimental studies on the gas holdup in two tapered bubble columns using non-Newtonian pseudoplastic liquid have been reported. The effects of different variables such as gas flow rate, liquid viscosity, bed height, and orifice diameter of sieve plate on gas holdup have been investigated. An empirical correlation has been developed for the prediction of the gas holdup as a function of various measurable parameters of the system. The correlation is statistically acceptable.     

Switching behavior of bulk,fast ion conducting,vitreous AgI-Ag2O-MoO3 solids with inert electrode

Developing efficient, fast performing and thermally stable Silver iodide-based fast ion conducting solids are of great interest for resistive switching applications, but still remain a challenge. Metallization in bulk, behavior of threshold voltage profile over composition, and corrosion reactions are few of the challenges. In this work, the switching behavior of bulk, fast ion conducting, vitreous (AgI)_x-(Ag₂O)₂₅-(MoO₃)_75-x, for 60 ≤ x ≤ 40 solids, has been investigated in order to understand the switching mechanism with the inert electrodes. By using inert electrodes, the switching becomes irreversible, memory type. The switching mechanism is the electrochemical metallization process. The inert electrodes restrain ionic mass transfer but exhibit low barrier to electron transfer allowing the cathodic metallization reaction to reach Nernst equilibrium faster. Cations involved in this process transport through the free volume within the solid structure and follows Mott-Gurney model for electric field-driven thermally activated ion hopping conductivity model. This model along with the thermal stability profile provides a narrow region within composition with better switching performance based on swiftness to reach threshold voltage and less power loss. Traces of anionic contribution to metallization are absent. Moreover, anodic oxidation involves reactions that cause bubble formation and corrosion.