Retarding Thermal Degradation in Hybrid Perovskites by Ionic Liquid Additives

Recent years have witnessed considerable progress in the development of solar cells based on lead halide perovskite materials. However, their intrinsic instability remains a limitation. In this context, the interplay between the thermal degradation and the hydrophobicity of perovskite materials is investigated. To this end, the salt 1‐(4‐ethenylbenzyl)‐3‐(3,3,4,4,5,5,6,6,7,7,8,8,8‐tridecafluorooctylimidazolium iodide (ETI), is employed as an additive in hybrid perovskites, endowing the photoactive materials with high thermal stability and hydrophobicity. The ETI additive inhibits methylammonium (MA) permeation in methylammonium lead triiodide (MAPbI₃) occurring due to intrinsic thermal degradation, by inhibiting out‐diffusion of the MA⁺ cation, preserving the pristine material and preventing decomposition. With this simple approach, high efficiency solar cells based on the unstable MAPbI₃ perovskite are markedly stabilized under maximum power point tracking, leading to greater than twice the preserved efficiency after 700 h of continuous light illumination and heating (60 °C). These results suggest a strategy to tackle the intrinsic thermal decomposition of MAI, an essential component in all state‐of‐the‐art perovskite compositions.     

A facile co-precipitation synthesis of heterostructured ZrO<Subscript>2</Subscript>|ZnO nanoparticles as efficient photocatalysts for wastewater treatment

ZrO₂-decorated ZnO (ZrO₂|ZnO) nanoparticles (NPs) have been synthesized by a facile co-precipitation method in the presence of cetyltrimethylammonium bromide (CTAB) surfactant. The ZrO₂ amount in the NPs has been varied from 1.0, 2.0, 4.9, to 9.3% by weight. The resulting NPs are heterostructured and consist of a crystalline ZnO core (wurtzite phase) surrounded by an amorphous ZrO₂ layer. X-ray diffraction analyses support this observation. The NPs show a narrow size distribution and are slightly elongated. Compared to pure ZnO NPs, the hybrid ZrO₂|ZnO ones show enhanced photocatalytic activity toward the degradation of Rhodamine B under UV–Vis light. Such enhancement has been partly attributed to the increased amount of oxygen vacancies when ZrO₂ is incorporated into the NPs, as shown by X-ray photoelectron spectroscopy analyses.     

Tunable Fano-Resonant Metasurfaces on a Disposable Plastic-Template for Multimodal and Multiplex Biosensing

Metasurfaces are engineered nanostructured interfaces that extend the photonic behavior of natural materials, and they spur many breakthroughs in multiple fields, including quantum optics, optoelectronics, and biosensing. Recent advances in metasurface nanofabrication enable precise manipulation of light–matter interactions at subwavelength scales. However, current fabrication methods are costly and time-consuming and have a small active area with low reproducibility due to limitations in lithography, where sensing nanosized rare biotargets requires a wide active surface area for efficient binding and detection. Here, a plastic-templated tunable metasurface with a large active area and periodic metal–dielectric layers to excite plasmonic Fano resonance transitions providing multimodal and multiplex sensing of small biotargets, such as proteins and viruses, is introduced. The tunable Fano resonance feature of the metasurface is enabled via chemical etching steps to manage nanoperiodicity of the plastic template decorated with plasmonic layers and surrounding dielectric medium. This metasurface integrated with microfluidics further enhances the light–matter interactions over a wide sensing area, extending data collection from 3D to 4D by tracking real-time biomolecular binding events. Overall, this work resolves cost- and complexity-related large-scale fabrication challenges and improves multilayer sensitivity of detection in biosensing applications.     

Elastic Gallium Phosphide Nanowire Optical Waveguides—Versatile Subwavelength Platform for Integrated Photonics

Emerging technologies for integrated optical circuits demand novel approaches and materials. This includes a search for nanoscale waveguides that should satisfy criteria of high optical density, small cross-section, technological feasibility and structural perfection. All these criteria are met with self-assembled gallium phosphide (GaP) epitaxial nanowires. In this work, the effects of the nanowire geometry on their waveguiding properties are studied both experimentally and numerically. Cut-off wavelength dependence on the nanowire diameter is analyzed to demonstrate the pathways for fabrication of low-loss and subwavelength cross-section waveguides for visible and near-infrared (IR) ranges. Probing the waveguides with a supercontinuum laser unveils the filtering properties of the nanowires due to their resonant action. The nanowires exhibit perfect elasticity allowing fabrication of curved waveguides. It is demonstrated that for the nanowire diameters exceeding the cut-off value, the bending does not sufficiently reduce the field confinement promoting applicability of the approach for the development of nanoscale waveguides with a preassigned geometry. Optical X-coupler made of two GaP nanowires allowing for spectral separation of the signal is fabricated. The results of this work open new ways for the utilization of GaP nanowires as elements of advanced photonic logic circuits and nanoscale interferometers.     

Countermeasures for Primary User Emulation Attack: A Comprehensive Review

Wireless Personal Communications - Cognitive radio (CR) is a flexible wireless network that can solve the scarcity and underutilization problem of the spectrum by permitting unlicensed users to...     

模拟引潮力作用下岩石破坏前兆的实验研究 --加卸载响应比(LURR)理论和能量加速释放(AER)

大地震前加卸载响应比升高和能量加速释放这2种现象可以用来对地震进行中期预报。同时,加卸载响应比升高和能量加速释放有相同的物理机制。实验对于揭示地壳岩石的变形和破坏规律是非常重要的。在三轴应力条件下进行了岩石破坏声发射实验,声发射技术是研究岩石变形破坏微观机理的重要手段。为了模拟日月引潮力对地球的加载和卸载作用,在一常数加载率的轴向压力作用下,叠加上微小的正弦扰动,力求能够模拟地下岩石复杂的受力状态。实验过程中记录到大量的声发射信息,声发射记录包括声发射发生的时间、空间坐标和振幅,它能够反映岩石试件内部每一个损伤(微裂纹)发生的时间、地点和强度。利用声发射记录系统地分析了岩石试件破坏前能量释放及加卸载响应比的演化情况,结果显示,岩石试件宏观破坏前出现了能量加速释放及加卸载响应比剧增这2种前兆现象,从而对地震临界点理论给予了实验支持,同时也为地震预测提供了实验依据。     

Magnetic properties of Ni-NiO (ferromagnetic-antiferromagnetic) nanocomposites obtained from a partial mechanochemical reduction of NiO

The magnetic properties of ferromagnetic (FM)-antiferromagnetic (AFM), Ni-NiO, nanocomposites obtained from a reactive ball milling reduction of NiO in H2 atmosphere have been studied. The formation of ferromagnetic Ni from antiferromagnetic NiO can be accurately followed by the increase of the saturation magnetization. The microstructure of the nanocomposite, consisting of FM Ni nanoparticles embedded in an AFM NiO matrix leads to exchange bias effects, i.e., loop shifts and coercivity enhancement, after field cooling from above the Néel temperature of NiO.     

Ultrasound-induced destruction of low levels of estrogen hormones in aqueous solutions

The removal of estrogen hormones from water and wastewater is of importance due to their adverse effects toward ecosystems and potential risks to human health. The ultrasound-induced destruction of estrogen compounds in aqueous solutions is studied in a batch reactor using a 1.1 W/mL sonication unit and in a continuous flow reactor using a 2.1 W/mL sonication unit. The estrogen compounds of interest are 17alpha-estradiol, 17beta-estradiol, ethinyl estradiol, estrone, equilin, gestodene, levonorgestrel, and norgestrel. Effects of process variables such as temperature, pH, and pressure are examined. The degradation of estrogens follows pseudo first-order kinetics. The reaction likely takes place in the interfacial region where supercritical environment is produced upon cavity implosion and in the bulk solution with radical species. Low solution pH is more favorable for destruction of estrogens. A kinetic degradation model is developed to predict the destruction of estrogen compounds. Low solution temperature shows favorable destruction of estrogens. Increasing the fluid pressure is detrimental to reaction efficiency.     

The bioavailability of raspberry anthocyanins and ellagitannins in rats

The fate of anthocyanins and ellagitannins in rats was monitored following ingestion of raspberry juice. After 1 h low nM concentrations of unmetabolised anthocyanins were present in plasma but these declined by 2 h and after 4 h they were no longer detectable. For the first 2 h there was an almost full recovery of anthocyanins as they passed from the stomach through the duodenum/jejunum and into the ileum. After 3 h less than 50% were recovered, and the levels declined rapidly thereafter. Excretion of raspberry anthocyanins in urine over a 24 h period was equivalent to 1.2% of the amount ingested. Trace quantities of anthocyanins were detected in the caecum, colon and faeces and they were absent in extracts of liver, kidneys and brain. Urine also contained a number of phenolic acids but most were present in quantities well in excess of the 918 nmol of anthocyanins present in the ingested juice. These findings indicate that raspberry anthocyanins per se are poorly absorbed, probably prior to reaching the ileum, and that substantial amounts pass from the small to the large intestine where they are degraded by colonic bacteria. Ellagitannins disappeared in the stomach without accumulation of ellagic acid.