A higher-order unsplit-field perfectly matched layer for the reflectionless truncation of 3-D spherical FDTD lattices

An enhanced higher-order finite-difference time-domain (FDTD) method for the systematic implementation of 3-D reflectionless perfectly matched layers (PML) in spherical coordinates is presented. By establishing a topologically unsplit-field formulation, the novel technique introduces accurate nonstandard schemes that eliminate the notably intricate lattice dispersion errors. Moreover, the wider spatial increments are treated via self-adaptive compact operators, while a mesh expansion process yields a significant reduction of the absorber's depth. For the temporal variable, the proposed method employs a multistage leapfrog integration that guarantees stability and excitation universality. Hence, because of the optimal configuration of the new PML, it attains a critical annihilation of both propagating and spurious wave families, even for complicated domains. Numerical investigation verifies the superiority of the higher-order algorithm via several unbounded radiation and scattering spherical problems.     

Heuristic collision-free path planning for an autonomous platform

In this paper, a heuristic and learning, algorithmic scheme for collision-free navigation is presented. This scheme determines an optimum collision-free navigation path of an autonomous platform by using a trial and error process, past navigation knowledge and current information extracted from the generated surrounding environment.     

Steady state multiplicity depending on coalescence in liquid—liquid continuous stirred reactors with reaction in the dispersed phase

The influence of drop coalescence and breakup on the existence of multiple steady states is studied for a two-phase stirred isothermal reactor where the chemical reaction in the d?ispersed phase obeys the rate expression ? r = kC/(1 + KC)². The random coalescence model developed by Curl was simulated using a modified Spielman and Levenspiel Monte Carlo technique.For certain range of the coalescence rate, Damköhler number, and dimensionless feed concentration, multiple steady states have been investigated.A special case has also been considered wherein the existence of multiple steady states for finite values of the coalescence rate is contrasted to the unique steady state solution for an infinite coalescence rate.     

The impact of computer self-efficacy,situational interest and academic self-concept in virtual communities of inquiry during the distance learning procedures through Second Life

The current study investigates a case where the online learning procedure in three-dimensional (3D) technologically-advanced environments of the Web 2.0 is growing at an exponential rate. In this occasion it is highly imperative need to understand students’ interactions in this innovative mode of e-Education that requires from educators and scholars not only analysis conceptually, but also an empirically-driven optimization. The community of inquiry (CoI) model (or framework) consists to be as one of the most prominent multi-dimensional constructs that it is widely used to represent several distinct dimensions of social presence, teaching presence and cognitive presence, as a unique and fundamental theoretical concept to measure students’ interactions in contemporary electronic environments. Although, the effectiveness of these multi-dimensional constructs creates a dilemma to researchers who want the breadth and comprehensiveness of this model for the precision and clarity of users’ (instructors and students) dimensions with other motivational and learning variables. To address this dilemma, the current empirical study presents statistical analyses from the “trinity” constructs of the CoI model by utilizing correlation and hierarchical regression analyses with two fundamental motivational (computer self-efficacy and situational interest) and another one learning (academic self-concept) variables. This study goes one step further and introduces the conspicuously indisputable intervention of a virtual (V)CoI and its utilization in multi-user virtual worlds, like Second Life (SL). The study findings of one hundred thirty-five (135) participants who enrolled in several online sessions unveiled that the situational interest was the only significant predictor of social presence. The computer self-efficacy was not a significant predictor of the CoI model, while on the other hand academic self-concept was a significant predictor in a revamped attempt to validate the strong relationship among constructs within it. According to the aforementioned reasons, it can be surmised that the successful combination of the VCoI in Second Life, surpassing irrefutable and inherent shortcomings to a future-driven sustainable use and growth.     

Highly-Efficient Wait-Free Synchronization

We study a simple technique, originally presented by Herlihy (ACM Trans. Program. Lang. Syst. 15(5):745–770, 1993), for executing concurrently, in a wait-free manner, blocks of code that have been programmed for sequential execution and require significant synchronization in order to be performed in parallel. We first present an implementation of this technique, called Sim, which employs a collect object. We describe a simple implementation of a collect object from a single shared object that supports atomic Add (or XOR) in addition to read; this implementation has step complexity O(1). By plugging in to Sim this implementation, Sim exhibits constant step complexity as well. This allows us to derive lower bounds on the step complexity of implementations of several shared objects, like Add, XOR, collect, and snapshot objects, from LL/SC objects. We then present a practical version of Sim, called PSim, which is implemented in a real shared-memory machine. From a theoretical perspective, PSim has worse step complexity than Sim, its theoretical analog; in practice though, we experimentally show that PSim is highly-efficient: it outperforms several state-of-the-art lock-based and lock-free synchronization techniques, and this given that it is wait-free, i.e. that it satisfies a stronger progress condition than all the algorithms that it outperforms. We have used PSim to get highly-efficient wait-free implementations of stacks and queues.     

Enabling user interface developers to experience accessibility limitations through visual,hearing, physical and cognitive impairment simulation

His paper presents a tool facilitating developers of user interfaces (UIs) to experience accessibility limitations that can be posed from various disabilities during the interaction of impaired users with their developments. In this respect, various aspects of visual, hearing, physical and cognitive impairments have been modelled through filters providing approximate, yet, realistic simulations over them. These filters have formed the basis for the developed tool, which can be used either on its own (as a standalone application), or be embedded in the NetBeans Integrated Development Environment. The tool, named DIAS, allows for impairment simulations to be performed over Java, mobile and web applications. Moreover, it integrates two of the most common assistive technologies (ATs), namely a screen reader and a magnifier. As a result, developers of UIs can not only experience how interaction would be affected from various impairments, but they can also understand how their developments would be perceived by impaired users through an AT. This work aims to provide an integrated, practical solution for impairment simulation, which could be easily adopted by developers, thus realistically increasing the possibilities for the future development of interactive applications that are more accessible to users with disabilities.     

Solvent free liquid phase oxidation of benzyl alcohol using Au supported catalysts prepared using a sol immobilization technique

Solvent free oxidation of benzyl alcohol was investigated in the absence of a base using Au catalysts prepared by sol immobilization on titania and carbon supports. Comparison between the Au supported catalysts revealed that activity and distribution of products was dependent on the nature of support and heat treatment. Specifically, heat pre-treatment of the Au catalysts has a beneficial effect in terms of activity, but is detrimental in terms of selectivity to the benzaldehyde. We conclude that sol immobilization is a suitable technique for preparing gold catalysts with small particle size and narrow particle size distributions and very high activity and selectivity for benzyl alcohol oxidation.     

Observations on the estimation of scavenging activity of phenolic compounds using rapid 1,1-diphenyl-2-picrylhydrazyl (DPPH<Superscript>•</Superscript>) tests

Rapid 1,1-diphenyl-2-picrylhydrazyl (DPPH^•) tests are often applied to classify the scavenging activity of phenolic compounds (AH). Published analytical protocols differ in more than one experimental condition, and results for the relative order or magnitude of activity are often contradictory. In this work, parameters such as duration of test, [AH]/[DPPH^•] molar ratio, and solvent effects were examined and discussed. The test duration and the value of the [AH]/[DPPH^•] ratio did not influence the order of activity among tested antioxidants. Ethanol, commonly used as solvent in such tests, was compared with acetonitrile and tert-butyl alcohol. Solvent properties such as the ability to form hydrogen bonds with the AH seem to influence the level of the relative activity (%RSA). Higher %RSA values were observed in ethanol. The activity of the most polar compounds was affected the most, and in some cases (caffeic, dihydrocaffeic, and rosmarinic acids) the order of activity was changed owing to different kinetics. Standardization of the analytical protocol should include a 20-min reaction period and a molar ratio that permits attainment of a 60–80% RSA value for the most potent antioxidant. Solvent choice is critical for classifying activity. Safe classification can be based only on results from kinetic studies.