Numerical assessment for impact strength measurements in concrete materials

Measurement of dynamic strength of concrete at impact relevant strain rates and pressures is the purpose of the described study. Therefore, an experimental design of direct planar impact experiments with longitudinal and transverse strain gauges is analyzed in predictive hydrocode simulations using an elastic–plastic damage model for concrete. The calculations and first experimental results on mortar show decreasing phase velocities of stress waves both in longitudinal and lateral gauges. The model clearly associates it with the onset of damage, possibly interpreted as a failure wave. Numerical analysis is furthermore used to compare a monolithic target block to a thoroughly assembled concrete sample in order to include flat gauges in the material. The planned experimental procedure to derive wave speeds, particle velocities and strain rates from stress measurements is anticipated and validated on the basis of simulated gauge signals. The most important finding is the prediction and first experimental confirmation that concrete ultimate strength and damaged yield stress can be derived at strain rates in the order of 10⁴/s from the proposed type of experiments. This technique promises new insight into the strength and failure processes of concrete in the challenging loading region around the characteristic minimum of the shock particle velocity relationship.     

Effect of oxygen plasma treatment on bonding states for columnar structured a-CNx thin films prepared by reactive sputtering

Amorphous carbon nitride (a-CN) thin films were deposited on silicon single crystal substrates by rf-reactive sputtering method using a graphite target and nitrogen gas. The substrate temperature was varied from room temperature (RT) to 853 K. After deposition, the effect of oxygen plasma treatment on bonding structures of the film surface has been studied by using an oxygen discharge at 16 Pa and rf power of 85 W. The chemical bonding states and film composition were analyzed by X-ray photoelectron spectroscopy (XPS), while film thickness was obtained from scanning electron microscopy (SEM) and ellipsometer. XPS study revealed that the films have NO₂ and NO₃ bonding structures when the films are deposited at temperatures higher than 673 K. After exposure to oxygen plasma, carbon in the film surface was etched selectively and this phenomenon was observed in all films. In contrast, the surface concentration of nitrogen was ket at constant values before and after oxygen plasma treatment. The NO₃ bonding state had dramatically increased after oxygen plasma treatment for films deposited at higher deposition temperatures. The film surfaces have been observed to change the function from hydrophobic to hydrophilic after oxygen plasma treatment.     

Surface Base Sites of MgO Covered with Al2O3: XANES Analysis of Al and Mg K-edges

Solid bases comprising MgO covered with Al₂O₃ were prepared by decomposition of Al(OCH(CH₃)₂)₃ over Mg(OH)₂ in ethyl acetate. Catalysts containing more than 10 mol% Al were insoluble in acetone. Aluminum occupied mainly octahedral sites in the low content range; tetrahedral structure being the principal one in the high range.     

Synthesis of Zeolite A from Aluminoborosilicate Glass Used in Glass Substrates of Liquid Crystal Display Panels and Evaluation of Its Cation Exchange Capacity

Synthesis of zeolite A from aluminoborosilicate glass used in liquid crystal display (LCD) panel glass substrate was attempted. Mixture of aluminoborosilicate glass and sodium aluminate was hydrothermally treated with sodium hydroxide solution for 10.8–345.6 ks at 368–423 K. Aluminoborosilicate glass was also acid treated with nitric acid before hydrothermal treatment. Obtained samples were characterized by X‐ray diffraction and scanning electron microscope observation. Zeolite A, hydroxysodalite, and zeolite P were synthesized, and with the specific conditions of hydrothermal treatment, a single phase of zeolite A was successfully obtained. Acid treatment was effective for synthesis of a single phase of zeolite A, because the components of aluminoborosilicate other than SiO₂ preferentially eluted for acid solution and during following hydrothermal treatment SiO₂ was supposed to elute for alkaline solution. Cation‐exchange capacities (CECs) were investigated for these products. It was clarified that CEC of the product with a single phase of zeolite A obtained from aluminoborosilicae glass was 4.2 mol/kg. CEC of the product consisted of zeolite A and hydroxysodalite was 3.9 mol/kg, and the one consisted of zeolite A, hydroxysodalite, and zeolite P was 2.6 mol/kg. This results shows that aluminoborosilicate glass could be expected to be recycled in zeolite A with good CEC by the appropriate process.     

Application of silicon polymer as positive photosensitive material

A new positive-working photosensitive system of silicon polymer, containing silylether groups in the main chain and a photo-induced acid precursor was investigated. The silicon polymer is hydrolized by a photogenerated acid and degraded to low molecular weight compounds. Thus the effect of solubility inhibition of the polymer is diminished. The higher photosensitivity of this system as compared with 1,2-quinone diazide compounds is due to the catalytic reaction of the acid on the hydrolysis of the silicon polymer. The chemical structure around silylether groups in the polymer, in particular more hydrophilic and less steric structures, affects the rate of hydrolysis and thus the photosensitivity. Among various types of photo-induced acid precursors examined, e.g., s-triazine and 1,3,4-oxadiazole compounds substituted by trihalomethyl groups were effective.     

A framework for simulation-optimization software

Research on the optimization of stochastic systems via simulation often centers on the development of algorithms for which global convergence can be guaranteed. On the other hand, commercial software applications that perform optimation via simulation typically employ search heuristics that have been successful in deterministic settings. Such search heuristics give up on global convergence in order to be more generally applicable and to yield rapid progress towards good solutions. Unfortunately, commercial applications do not always formally account for the randomness in simulation responses, meaning that their progress may be no better than a random search if the variability of the outputs is high. In addition, they do not provide statistical guarantees about the "goodness" of the final results. In practice, simulation studies often rely heavily on engineers who, in addition to developing the simulation model and generating the alternatives to be compared, must also perform the statistical analyses off-line. This is a time- and labor-consuming process. In this paper, we report on the work we have done to implement statistical error control within a heuristic search procedure, and on our automated procedure to deliver a statistical guarantee after the search procedure is finished. We describe how we implemented these techniques in software developed for JGC Corporation of Japan.     

Region-of-interest visualization by CAVE VR system with automatic control of level-of-detail

To specify the region of interest (ROI) is an effective approach to visualize large scale simulation data. We have developed a three-dimensional visualization software with ROI function for the CAVE virtual reality systems. This software enables the user to perform fully three-dimensional and interactive visualization of large scale computational fluid dynamics (CFD) data. The user specifies a ROI in the CAVE room by a three-dimensional “mouse-drag”. The data in the specified ROI is automatically extracted from the original CFD data. This ROI procedure can be repeated recursively. The resolution in each ROI is kept approximately constant. A data set of three vector fields and eight scalar fields whose size is about 1 GB each was successfully analyzed.     

Ultra-low-vibration pulse-tube cryocooler system – cooling capacity and vibration

This report describes the development of low-vibration cooling systems with pulse-tube (PT) cryocoolers. Generally, PT cryocoolers have the advantage of lower vibrations in comparison to those of GM cryocoolers. However, cooling systems for the cryogenic laser interferometer observatory (CLIO), which is a gravitational wave detector, require an operational vibration that is sufficiently lower than that of a commercial PT cryocooler. The required specification for the vibration amplitude in cold stages is less than ±1 μm. Therefore, during the development of low-vibration cooling systems for the CLIO, we introduced advanced countermeasures for commercial PT cryocoolers. The cooling performance and the vibration amplitude were evaluated. The results revealed that 4 K and 80 K PT cooling systems with a vibration amplitude of less than ±1 μm and cooling performance of 4.5 K and 70 K at heat loads of 0.5 W and 50 W, respectively, were developed successfully.     

XPS study of carbon nitride films deposited by hot filament chemical vapor deposition using carbon filament

Amorphous carbon nitride, a-CN_x, thin films were deposited by hot filament CVD using a carbon filament with dc negative bias voltage on the substrate. The effects of the negative bias and the filament components on the binding structure of the films are investigated by XPS. The composition ratio of graphite to amorphous carbon in the filaments affects the bonding structure of carbon and nitrogen in the films, although the nitrogen content in the films is almost same as 0.1. The nitrogen content in the films changes from 0.1 to 0.3 as the negative bias changes from 0 to − 300 V.     

Design of hybrid type’s optical pickup actuator for system stability in high density reading and recording

Recently, there has been a trend to have large capacity and high data transfer rate in optical disk drive. Pickup actuator also should have high performance for satisfying this trend. Since moving magnet type actuator has more simple and robust structure than moving coil type one, we designed moving magnet type to accomplish high flexible mode frequency. However, the driving sensitivity of moving magnet type actuator was low because of its characteristics as following. At first, moving parts including magnets are heavy and electromagnetic (EM) circuits are not closed-loop owing to yoke composed of paramagnetic materials. Therefore, in order to increase the driving sensitivity without the degradation of the other dynamic characteristics, EM circuits were redesigned by adding solenoid coils on existing mechanism. As a result, the hybrid type actuator composed of moving magnet type and moving coil type was suggested to obtain high sensitivities and high flexible mode frequency. Design variables of EM circuits and structure parts were decided through parametric study and design of experiments procedure. Optimization algorithm using variable metric method was used to improve performance. Based on these results, the final model was presented.