Heat Generation in Multilayer Piezoelectric Actuators

Multilayer piezoelectric actuators when driven under high frequency, generate significant heat, which influences the reliability and other piezoelectric properties. In this paper, heat generation in various types of multilayer PZT-based actuators was studied. Experimental results showed that heat generation is mainly caused by ferroelectric hysteresis loss in the stress-free state. A simplified analytic method was established to evaluate the temperature rise, which is useful for the design of multilayer and other high-power actuators.     

Intestinal absorption and biological effects of orally administered amorphous silica particles

Although amorphous silica nanoparticles are widely used in the production of food products (e.g., as anticaking agents), there is little information available about their absorption and biological effects after oral exposure. Here, we examined the in vitro intestinal absorption and in vivo biological effects in mice of orally administered amorphous silica particles with diameters of 70, 300, and 1,000 nm (nSP70, mSP300, and mSP1000, respectively) and of nSP70 that had been surface-modified with carboxyl or amine groups (nSP70-C and nSP70-N, respectively). Analysis of intestinal absorption by means of the everted gut sac method combined with an inductively coupled plasma optical emission spectrometer showed that the intestinal absorption of nSP70-C was significantly greater than that of nSP70. The absorption of nSP70-N tended to be greater than that of nSP70; however, the results were not statistically significant. Our results indicate that silica nanoparticles can be absorbed through the intestine and that particle diameter and surface properties are major determinants of the degree of absorption. We also examined the biological effects of the silica particles after 28-day oral exposure in mice. Hematological, histopathological, and biochemical analyses showed no significant differences between control mice and mice treated with the silica particles, suggesting that the silica nanoparticles evaluated in this study are safe for use in food production.     

Molecular dynamics of DNA and nucleosomes in solution studied by fast-scanning atomic force microscopy

Nucleosome is a fundamental structural unit of chromatin, and the exposure from or occlusion into chromatin of genomic DNA is closely related to the regulation of gene expression. In this study, we analyzed the molecular dynamics of poly-nucleosomal arrays in solution by fast-scanning atomic force microscopy (AFM) to obtain a visual glimpse of nucleosome dynamics on chromatin fiber at single molecule level. The influence of the high-speed scanning probe on nucleosome dynamics can be neglected since bending elastic energy of DNA molecule showed similar probability distributions at different scan rates. In the sequential images of poly-nucleosomal arrays, the sliding of the nucleosome core particle and the dissociation of histone particle were visualized. The sliding showed limited fluctuation within ∼50 nm along the DNA strand. The histone dissociation occurs by at least two distinct ways: a dissociation of histone octamer or sequential dissociations of tetramers. These observations help us to develop the molecular mechanisms of nucleosome dynamics and also demonstrate the ability of fast-scanning AFM for the analysis of dynamic protein–DNA interaction in sub-seconds time scale.     

Ultra-high-precision time control system over any long time delay for laser pump and synchrotron x-ray probe experiment

An ultra-high-precision clock system for long time delay has been developed for picosecond time-resolved x-ray diffraction measurements using synchrotron radiation (SR) pulses and synchronized femtosecond laser pulses. The time delay control between pump laser pulse and the probe SR pulse was achieved by combining an in-phase quadrature modulator and a synchronous counter. This method allowed us to change the delay time by a nearly infinite amount while maintaining the precision of +/-8.40 ps. Time-resolved diffraction measurements using the delay control system were demonstrated for precise measurement of an acoustic velocity in a single crystal of gallium arsenide.     

Carboxylated polysulfone membranes having a chiral recognition site induced by an alternative molecular imprinting technique

SUMMARY Molecularly imprinted polymeric membranes were prepared from carboxylated polysulfone. Membranes imprinted by Z-D-Glu recognize the D-isomer in preference to the corresponding L-isomer, and vice versa. The amino acid preferentially adsorbed by the membrane was also selectively permeated by electrodialysis. Received: 22 January 1998/Accepted: 20 February 1998     

New catalytic functions of Pd–Zn, Pd–Ga, Pd–In, Pt–Zn, Pt–Ga and Pt–In alloys in the conversions of methanol

Pd and Pt supported on ZnO, Ga₂O₃ and In₂O₃ exhibit high catalytic performance for the steam reforming of methanol, CH₃OH+H₂OCO₂+3HH₂, and the dehydrogenation of methanol to HCOOCH₃, 2CH₃OHHCOOCH₃+2HH₂. Combined results with temperature-programmed reduction (TPR) and XRD method revealed that Pd–Zn, Pd–Ga, Pd–In, Pt–Zn, Pt–Ga and Pt–In alloys were produced upon reduction. Over the catalysts having the alloy phase, the reactions proceeded selectively, whereas the catalysts having metallic phase exhibited poor selectivities.     

Adhesion properties of CVD diamond film on binder-less sintered tungsten carbide prepared by the spark sintering process

This paper describes the adhesion property of chemical-vapor-deposited (CVD) diamond film on tungsten carbide (WC) bodies prepared by spark sintering without a binder. WC bodies ranging from 70 to 95% of density ratio have been sintered under different sintering conditions, and their mechanical properties, such as hardness and bending strength, have been measured. High-quality diamond films with a higher nucleation density compared to that on WC–Co have been deposited on this WC substrate using the microwave plasma CVD method. A comparison study using indentation tests shows that the adhesive strength of diamond films on this binder-less sintered WC is remarkably superior to that on WC–Co, which is believed to result from the increase in diamond nucleation density, the enhanced mechanical bonding between the substrate and the diamond film and the well-matching of thermal expansion coefficients caused by the absence of the fatal obstacle of cobalt. Moreover, an increase in adhesive strength has occurred on the binder-less sintered WC with lower density ratios.     

Generation of multifrequency laser emission quasi equally spaced throughout the entire visible region

A circularly polarized, monochromatic laser beam is focused into a Raman cell, which contains hydrogen to generate rotational stimulated Raman emission. After linear polarization, this two-color (separated by 587 cm(-1)) laser beam is focused several times into a second Raman cell that is filled with hydrogen to generate a multifrequency laser emission. Many rotational and vibrational lines are generated efficiently by this multipass effect. Eighteen colors that are quasi equally spaced with a rather flat intensity distribution are generated throughout the entire visible region. The present multifrequency laser emission may be advantageously used for illumination in a higher-grade display, such as a laser light show.     

Inorganic-organic hybrid molecular architectures of cyanometalate host and organic guest systems: specific behavior of the guests

Molecular architectures built of inorganic cyanometalate building blocks provide variegated host structures with several organic guest molecules. The strategies to derive novel structures are presented briefly. The formation of a charge-transfer (CT) complex as the guest inside the cavity and the photochemistry of the CT complexes are discussed. The chemical pressure that the guest experiences inside the cavity is also discussed based on the vibrational spectroscopic results.