Accretion of titanium carbide by electrical discharge machining with powder suspended in working fluid

A surface modification method by electrical discharge machining (EDM) with a green compact electrode has been studied to make thick TiC or WC layer. Titanium alloy powder or tungsten powder is supplied from the green compact electrode and adheres on a workpiece by the heat caused by discharge. To avoid the production process of the green compact electrode, a surface modification method by EDM with powder suspended in working fluid is proposed in this paper. After considering flow of working fluid in EDM process, the use of a thin electrode and a rotating disk electrode are expected to keep powder concentration high in the gap between a workpiece and an electrode and to accrete powder material on the workpiece. The accretion machining is tried under various electrical conditions. Titanium powder is suspended in working oil like kerosene. TiC layer grows a thickness of 150 μm with a hardness of 1600 Hv on carbon steel with an electrode of 1 mm in diameter. When a disk placed near a plate rotates in viscous fluid, the disk drags the fluid into the gap between the disk and the plate. Therefore, the powder concentration in the gap between a workpiece and a rotational disk electrode can be kept high. A wider area of the accretion can be obtained by using the rotational electrode with a gear shape.     

Prostate specific antigen doubling time in prostate cancer before treatment and in refractory status]

Prostate-specific antigen(PSA) increases exponentially in prostate cancer patients before treatment and in refractory status. PSA increases in 68-86% of prostate cancer patients before treatment, and that of the remaining 14-32% of the patients is stable. Those patients with a higher pre-treatment PSA level are more likely to have a shorter PSA-doubling time(PSA-DT). The relationship between pre-treatment stage, grade and PSA-DT is controversial. PSA-DT in biochemical failure patients predicts the risk of clinical recurrence. PSA-DT was correlated well with time to clinical recurrence after biochemical failure. Distant recurrence was associated with short PSA-DT. Higher clinical stage and lower differentiation before treatment correlated with shorter PSA-DT in recurrent cancer patients. PSA-DT is an important parameter for judging malignant potential of each cancer.     

Exfoliation of non-swelling muscovite on dodecylammonium chloride intercalation between layers using wet-jet milling

The exfoliation of layered muscovite with non-swelling property has been performed by combining various processes, such as heating, intercalation, and wet-jet milling. The c axis of muscovite was expanded from 2004.0 to 2022.8 pm at 800 °C without the destruction of crystallinity of muscovite. The heating at 800 °C led to the weak attraction force between potassium ions and silicate layers by hydroxylation of muscovite. The muscovite heated at 800 °C progressed the intercalation of dodecylammonium chloride (DDAC) into the layers effectively. Furthermore, the DDAC molecules were inserted to the interlayer of muscovite effectively by suppressing the formation of micelle of DDAC. The sedimentation test of wet-jet milled muscovite slurry showed that the relative packing density of muscovite was decreasing with increasing the amount of the intercalated DDAC. As results, the aspect ratio of muscovite prepared with combining the heating, the intercalation and the wet-jet milling was increased by 253% as compared to the raw muscovite. The aspect ratio was calculated from laser particle size distribution and thickness size distribution which was estimated from field emission-scanning electron microscopic images. The expansion of the interlayer led to the effective exfoliation of muscovite with high aspect ratio.     

Passive measure for preventing recriticality of fuel debris dust for defueling at Fukushima Daiichi nuclear power station

The drilling or cutting of resolidified fuel debris required to defuel the Fukushima Daiichi nuclear power station is certain to generate debris dust. This paper focused on drilling resolidified fuel debris in water and conservatively confirmed by criticality calculations that neutron multiplication effect is higher if debris dust is suspended separately from the debris rather than if it is suspended closely around the debris. No use of vacuuming of debris dust, borated water, and active components was assumed in this study. Also, this paper confirmed that the use of a debris dust guide effectively and passively limited the increase in neutron multiplication by debris dust because the guide distributes dust particles so flatly that sufficient neutron leakage limits neutron multiplication even if the volume fraction of the particles in water reaches the optimum condition. In the actual defueling operation at the nuclear power station, the use of a flatter debris dust guide will be more effective to prevent local recriticality concurrently with the careful control of the mass of debris dust. The physics and ideas in this paper should be applicable to other defueling technologies such as laser cutting as long as debris dust is generated and suspended in water.     

Digital microscope observation of the initial stage of cutting monocrystalline silicon

Digital microscope (DM) for local zooming of finite element solutions has been proposed and applied to cutting simulation of monocrystalline silicon with no preexisting defect. The DM has revealed that cutting performance is strongly dependent on the size of a workpiece. The DM has also revealed that a microcrack appears instantaneously for any depth of cut around a cutting edge but its evolution to a macrocrack depends on the depth of cut. A critical depth of cut for macrocrack evolution can be estimated on the basis of data obtained using the DM.     

Evaluation of transition zone biopsy in systematic prostate biopsy

We evaluated the systematic biopsies performed on 83 patients suspected of having prostate cancer. In the systematic biopsy, 6 cores were from the peripheral zone and 2 cores from the transition zone. Cancer was detected in 25 patients (30.1%). The percentage of patients who had abnormal digital rectal examination and transrectal echo findings, average PSA and PSA density, and the number of examinations which suggested cancer were higher in the cancer group than in the non-cancer group, although the mean prostate volume was smaller. Cancer was more frequently detected in the peripheral zone than in the transition zone. Cancer was detected only in the transition zone in only 1 of the 25 cancer patients. We conclude that biopsy of the transition zone to all the patients is not always needed in systematic biopsy.     

Polymer optical fiber for near infrared use

Using the empirical simulation that we developed to estimate loss spectra of amorphous polymers, we predicted the intrinsic loss spectrum of fluorine-containing polyarylate (FPAr) that should have a small attenuation loss in the near infrared region. Loss of FPAr is smaller than that of poly (methyl methacrylate), which is a typical optical polymer used as a core material in polymer optical fiber (POF), above 720 nm. FPAr was synthesized by phase transfer catalyzed polycondensation of 2,2-bis (4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropane with isophthaloyl dichloride. Its glass-transition temperature (T_g) by DSC is 163°C. This indicates that FPAr has higher heat resistance than polycarbonate (PC) by about 10°C. A film of 100μm thick has over 85% transmittance from 330 to 900 nm. Values from a tension test are similar to those of PC. As a result, FPAr is expected to be a good core polymer for POF, because of its high T_g, good transparency, and good flexibility. Next, the POF made of FPAr was fabricated by a melt-flow spinning method. It had larger attenuation loss than predicted. The difference from the simulation was extrinsic loss caused by the fabricating process. Therefore, when a more suitable fabricating process is developed, loss of FPAr-POF can be decreased, so that it will be applicable to optical communications in the near infrared region. © 1993 John Wiley & Sons, Inc.     

Methanol synthesis from carbon dioxide at atmospheric pressure over Cu/ZnO catalyst. Role of methoxide species formed on ZnO support

Methanol synthesis from CO₂ and H₂ was carried out over a Cu/ZnO catalyst (Cu/Zn = 3/7) at atmospheric pressure, and the surface species formed were analyzed by diffuse reflectance FT-IR spectroscopy and temperature programmed desorption method. Two types of formate species and zinc methoxide were formed in the course of the reaction. Zinc methoxide was readily hydrolyzed to methanol. H₂O formed through the reverse water gas shift reaction was suggested to be involved in the hydrolysis of zinc methoxide.     

Topology optimization for designing strain-gauge load cells

Load cells are used extensively in engineering fields. This paper describes a novel structural optimization method for single- and multi-axis load cell structures. First, we briefly explain the topology optimization method that uses the solid isotropic material with penalization (SIMP) method. Next, we clarify the mechanical requirements and design specifications of the single- and multi-axis load cell structures, which are formulated as an objective function. In the case of multi-axis load cell structures, a methodology based on singular value decomposition is used. The sensitivities of the objective function with respect to the design variables are then formulated. On the basis of these formulations, an optimization algorithm is constructed using finite element methods and the method of moving asymptotes (MMA). Finally, we examine the characteristics of the optimization formulations and the resultant optimal configurations. We confirm the usefulness of our proposed methodology for the optimization of single- and multi-axis load cell structures.     

Geometrical design of thermoelectric generators based on topology optimization

This paper discusses an application of the topology optimization method for the design of thermoelectric generators. The proposed methodology provides the optimized geometry in accordance with various arbitrary conditions such as the types of materials, the volume of materials, and the temperature and shape of the installation position. By considering the coupled equations of state for the thermoelectric problem, we introduce an analytical model subject to these equations, which mimics the closed circuit composed of thermoelectric materials, electrodes, and a resistor. The total electric power applied to the resistor and the conversion efficiency are formulated as objective functions to be optimized. The proposed optimization method for thermoelectric generators is implemented as a geometrical optimization method using the solid isotropic material with penalization method used in topology optimizations. Simple relationships are formulated between the density function of the solid isotropic material with penalization method and the physical properties of the thermoelectric material. A sensitivity analysis for the objective functions is formulated with respect to the density function and the adjoint equations required for calculating it. Depending on the sensitivity, the density function is updated using the method of moving asymptotes. Finally, numerical examples are provided to demonstrate the validity of the proposed method. Copyright © 2012 John Wiley & Sons, Ltd.