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41.
Takuya Tamura Yuuki Maehara Naoki Omura Kenji Miwa 《Metallurgical and Materials Transactions A》2008,39(8):1917-1921
The method for producing Mg-Cu-Y and Fe-Co-B-Si-Nb bulk metallic glasses using electromagnetic vibrations is effective in
forming the metallic glass phase. Disappearance or decrement of clusters by the electromagnetic vibrations applied to the
liquid state is considered to cause suppression of crystal nucleation, because the electromagnetic vibrations vibrate the
clusters vigorously in the melt. The purpose of this study was to investigate motion of the crystal particles by the electromagnetic
vibrations in Mg-Cu-Y bulk metallic glasses. The electromagnetic vibration force vibrated the crystal particles or the clusters
that become crystal nuclei in the melt, because the electric current for the electromagnetic vibrations concentrates in those.
Thus, the electromagnetic vibrations were found to select vibration particles from the melt. Moreover, it was considered that
composites for which second phases or other compounds are dispersed into the metallic glass phase or a nanostructure phase
can be produced by the electromagnetic vibration process.
This article is based on a presentation given in the symposium entitled “Bulk Metallic Glasses IV,” which occurred February
25–March 1, 2007 during the TMS Annual Meeting in Orlando, Florida under the auspices of the TMS/ASM Mechanical Behavior of
Materials Committee. 相似文献
42.
Kinetic analyses for the solid-state reactions of reactant particles in an assemblage with a particle-size distribution (PSD) have been reexamined for the reactions that proceed by the advance of the reaction interfaces inward toward the center of the individual reactant particles. The experimental kinetic curves for a particle assemblage are influenced by the existing PSD. It has been demonstrated that, even if PSD exists, a reliable activation energy E can be obtained from such overall kinetic curves by the empirical isothermal analysis without accounting for the PSD. The isoconversion methods, which enable us to determine the E value from the data points at a given fractional reaction of a series of experimental kinetic curves, are methodologically independent of the PSD. It is neccessary to incorporate the PSD into the kinetic equation to select an appropriate kinetic model and to evaluate the preexponential factor A . The method of kinetic calculation accounting for the PSD can be generalized, for the kinetic data under any thermal profiles, by extrapolating all the analytical conditions to infinite temperature. For the reaction characterized by the well-defined PSD and kinetic model function, the meaningful A value is obtained by the kinetic analysis at infinite temperature. Although the ability to discriminate the contracting geometry of the reaction interface in a single particle from the overall kinetic curve decreases with increasing PSD, the rate-controlling steps for the advance of the reaction interface, i.e., chemical reaction controlled or diffusion controlled, can be distinguised from each other even for the reactions with a fairly large PSD. 相似文献
43.
以废木材生物质的有效利用为目的,使用粉粒流化床反应器,对3种木材进行了催化热分解实验,以4种催化效果不同的粒子作为流化床内的流化介质来考察催化热分解过程中介质颗粒、反应气体和热分解温度对产物分布的影响.木材的挥发性物质在700K时就已几乎分解出来,挥发性物质中的轻质芳香烃碳氢化合物(苯、甲苯、二甲苯和萘:BTXN)的收率随着热分解温度的升高而增加,1173K下达到3.1%(质量分数),daf.在氢气气氛下,当作为流化介质颗粒Zn(3%,质量分数)/HZSM-5催化剂对木材进行催化热分解时,853K下可得到6.1%, daf的轻质芳香烃碳氢化合物的收率(BTX 5.5%,daf、萘0.6%,daf).而在活性很高的NiMo-A加氢催化剂下,在863K时,催化热分解产物几乎全为甲烷. 相似文献
44.
The need for visual landscape assessment in large-scale projects for the evaluation of the effects of a particular project on the surrounding landscape has grown in recent years. Augmented reality (AR) has been considered for use as a landscape simulation system in which a landscape assessment object created by 3D models is included in the present surroundings. With the use of this system, the time and the cost needed to perform a 3DCG modeling of present surroundings, which is a major issue in virtual reality, are drastically reduced. This research presents the development of a 3D map-oriented handheld AR system that achieves geometric consistency using a 3D map to obtain position data instead of GPS, which has low position information accuracy, particularly in urban areas. The new system also features a gyroscope sensor to obtain posture data and a video camera to capture live video of the present surroundings. All these components are mounted in a smartphone and can be used for urban landscape assessment. Registration accuracy is evaluated to simulate an urban landscape from a short- to a long-range scale. The latter involves a distance of approximately 2000 m. The developed AR system enables users to simulate a landscape from multiple and long-distance viewpoints simultaneously and to walk around the viewpoint fields using only a smartphone. This result is the tolerance level of landscape assessment. In conclusion, the proposed method is evaluated as feasible and effective. 相似文献
45.
The pressure–viscosity coefficient is an important parameter in tribology. Experimentally, it is calculated using the high‐pressure viscosity measurement. Also, the adiabatic bulk modulus is calculated using the sound velocity in the lubricating oil. Several lubricating oils are considered on the group basis such as traction oil, mineral oil, polyalphaolefin oil, perfluoropolyether oil and glycerol, depending on their molecular structure. Experimental pressure–viscosity coefficient is compared with the adiabatic bulk modulus. It is found that the pressure–viscosity coefficient increases exponentially with the adiabatic bulk modulus, and the relationship depends on the molecular structure of the lubricating oils. This study proposes two equations to predict the pressure–viscosity coefficient from the adiabatic bulk modulus based on sound velocity, one for the traction oil, and another for the paraffinic mineral oil and the polyalphaolefin oil. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
46.
Zakaria MB Suzuki N Shimasaki K Miyamoto N Huang YT Yamauchi Y 《Journal of nanoscience and nanotechnology》2012,12(6):4502-4507
In this research paper, we synthesize various types of mesoporous titania nanoparticles (MTNs) with suitable surface area and pore size while creating anatase frameworks by applying hydrothermal treatment or calcination at different temperatures. Wide-angle XRD patterns and N2 adsorption-desorption isotherms reveal that the MTNs with crystallized anatase frameworks can be synthesized after an optimized hydrothermal treatment. In contrast, calcination of MTNs at high temperature caused the collapse of mesoporous structure, resulted in drastic reduction of the surface area of the MTNs. In addition, we investigate the photocatalytic activity of the prepared MTNs by measuring the degradation of methylene blue (MB). The results show that the reaction rates of the photocatalytic MB decomposition strongly depend on the degree of crystallinity in the MTNs frameworks and on the surface area of MTNs. 相似文献
47.
Delayed fracture properties of AISI 4135 high strength steels with 1490 and 1310 MPa of tensile strength, represented as B15 and B13, respectively, have been studied by means of slow strain rate test (SSRT) of notched bar specimens after outdoor exposure at rural and coastal areas. The exposed specimens were kept at humid medium before SSRT to reproduce active hydrogen entry influenced by the rust layer and to homogenize hydrogen distribution. The influences of exposure site and exposure time on fracture stress have been investigated. The susceptibility of B15 to delayed fracture was obviously higher than that of B13. 相似文献
48.
Masahiko Tachibana Kazushige Ishida Yoichi Wada Ryosuke Shimizu Nobuyuki Ota Nobuyoshi Hara 《Journal of Nuclear Science and Technology》2013,50(2):253-262
In order to examine the anodic polarization characteristics of typical structural materials of boiling water reactors (BWRs), the anodic polarization curves of type 316L stainless steel (316L SS) and Alloy 182 were measured in deaerated high purity water at 553 K using the previously reported measurement method which was confirmed suitable for high temperature – high purity water. In order to specify which constituent element determines the dissolution characteristics of these materials, the anodic polarization curves of pure iron, pure nickel, and pure chromium were also surveyed. The anodic polarization curve of 316L SS was determined to have active, passive, and transpassive states which were the same as type 304 SS (304 SS) showed. But, Alloy 182 had different polarization characteristics especially near the corrosion potential as it had no active state. From comparison results of the polarization characteristics of these materials and their constituent elements, the corrosion characteristics of these materials were concluded to be mainly determined by the corrosion characteristics of chromium. 相似文献
49.
We present a three-dimensional (3D) measurement and imaging based on a multicamera system. In the presented system, projected images of 3D objects are taken by cameras located at random positions on a circumference, and then the 3D objects can be reconstructed numerically. We introduce an angle correction function to improve the quality of the reconstructed object. The angle correction function can correct the angle error caused by the position errors in the projected images due to the finite pixel size of the image sensor. The numerical results show that the point source was reconstructed successfully by introducing the angle correction function. We also demonstrate experiments: the two objects are located on a rotary stage controlled by a computer, the projected images are taken by a single camera, and by using 33 projected images, the two objects are reconstructed successfully. 相似文献
50.
ET Sayed Y Saito T Tsujiguchi N Nakagawa 《Journal of Bioscience and Bioengineering》2012,114(5):521-525
It was revealed that the dry powder yeast extract (YE) has the ability to act as a biocatalyst as well as a mediator in a biofuel cell. The yeast extract, from Nihon Pharmaceutical Co., Ltd., was used as a biocatalyst in an open air cathode biofuel cell containing phosphate buffer for glucose oxidation. The anode medium with only the YE showed an immediate activity by producing a current and delivering power depending on its concentration. By adding glucose to the anode medium, the anode potential decreased with time to -0.2?V vs. normal hydrogen electrode (NHE), and produced a higher power compared to that without glucose. The biofuel cell produced an open circuit voltage (OCV) as high as 1?V. 相似文献