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排序方式: 共有752条查询结果,搜索用时 15 毫秒
21.
Yan Liu Shigenori Mitsushima Ken-ichiro Ota Nobuyuki Kamiya 《Electrochimica acta》2006,51(28):6503-6509
The electro-oxidation of dimethyl ether (DME) on PtMe/Cs (Me = Ru, Sn, Mo, Cr, Ni, Co, and W) and Pt/C electro-catalysts were investigated in an aqueous half-cell, and compared to the methanol oxidation. The addition of a second metal enhanced the tolerance of Pt to the poisonous species during the DME oxidation reaction (DOR). The PtRu/C electro-catalyst showed the best electro-catalytic activity and the highest tolerance to the poisonous species in the low over-potential range (<0.55 V, 50 °C) among the binary electro-catalysts and the Pt/C, but at the higher potential (>ca. 0.55 V, 50 °C), the Pt/C behaved better than PtRu/C. The apparent activation energy for the DOR decreased in the order: PtRu/C (57 kJ mol−1) > Pt3Sn/C (48 kJ mol−1) ≈ Pt/C (46 kJ mol−1). On the other hand, the activation energy for the MOR showed a different turn, decreased in the following order: Pt/C (43 kJ mol−1) > Pt3Sn/C (35 kJ mol−1) ≈ PtRu/C (34 kJ mol−1). The temperature dependence of the DOR was greater than that of the oxidation of methanol (MOR) on the PtRu/C. 相似文献
22.
Md Tasyrif Abdul Rahman Nobuyuki KawaharaKazuya Tsuboi Eiji Tomita 《International Journal of Hydrogen Energy》2014
In this work, spark-induced breakdown spectroscopy (SIBS) was employed to investigate the mixing process of a hydrogen jet in a constant-volume vessel. The local fuel concentration of the hydrogen jet was measured at several locations, using a SIBS sensor. A high-speed camera was used to visualize spark discharge fluctuations, and hydrogen jet concentration measurements were conducted simultaneously. Spectrally resolved atomic emissions from the plasma generated by the spark plug were examined to determine the local equivalence ratio. Direct visualization of the spark discharge provided useful information about the influence of spark discharge characteristics related to the spark timing. Using the developed SIBS sensor, atomic emission spectra were obtained from hydrogen Hα at 656 nm and nitrogen N (I) at 501 nm. Comparison of the intensity peaks of atomic emissions from hydrogen and nitrogen allows the local hydrogen concentration in a measured volume to be determined, and hence also the local equivalence ratio. The measurement results demonstrate the local variation in the equivalence ratio throughout the jet and along its axis. From the results, the spatial structure of the hydrogen jet affects the hydrogen/nitrogen mixing and could be clarified with SIBS technique when the spark is discharged. 相似文献
23.
Mary Ann O. Torio Takafumi Itoh Roberta N. Garcia Nobuyuki Maruyama Shigeru Utsumi Evelyn Mae Tecson-Mendoza 《Food research international (Ottawa, Ont.)》2012,45(1):277-282
Sulfhydryl groups and disulfide bond were introduced in mungbean's major storage protein, 8Sα globulin, by protein engineering to improve structural stability and functional properties. Five modified proteins or mutants (F59C, I99C, A213C, one free sulfhydryl group; I99C/A213, one disulfide bridge; F59C/I99C/A213C, one free sulfhydryl group and one disulfide linkage) were expressed in Escherichia coli at a yield similar to that of the unmodified protein or wild type (WT) in soluble form (38%). The number of introduced groups in the mutants was confirmed by Ellman analysis. Mutant and WT proteins exhibited similar elution patterns on gel filtration indicating their trimeric native conformation. Mutants had 2 to 3.8 °C higher Tm values than WT and were digested by chymotrypsin at 52–58% in 60 min but exhibited different digestion patterns. All mutants showed greater hardness of heat-induced gels than WT, especially I99C/A213C and F59C/I99C/A213C. Results indicate the improved structural stability of the modified 8Sα globulin. 相似文献
24.
Kazushige Ishida Yoichi Wada Masahiko Tachibana Nobuyuki Ota Motohiro Aizawa 《Journal of Nuclear Science and Technology》2013,50(11):1071-1082
The effects of water chemistry distribution on the potential of a reference electrode and of the potential distribution on the measured potential should be known qualitatively to obtain accurate electrochemical corrosion potential (ECP) data in BWRs. First, the effects of oxygen on a platinum reference electrode were studied in 553 K pure water containing dissolved hydrogen (DH) concentration of 26–105 μg kg?1 (ppb). The platinum electrode worked in the same way as the theoretical hydrogen electrode under the condition that the molar ratio of DH to dissolved oxygen (DO) was more than 10 and that DO was less than 100 ppb. Second, the effects of potential distribution on the measured potential were studied by using the ECP measurement part without platinum deposition on the surfaces connected to another ECP measurement part with platinum deposition on the surfaces in 553 K pure water containing 100–130 ppb of DH or 100–130 ppb of DH plus 400 ppb of hydrogen peroxide. Measured potentials for each ECP measurement part were in good agreement with literature data for each surface condition. The lead wire connecting point did not affect the measured potential. Potential should be measured at the nearest point from the reference electrode in which case it will be not affected by either the potential distribution or the connection point of the lead wire in pure water. 相似文献
25.
Ryuta Shigefuku Hideaki Takahashi Hiroyasu Nakano Tsunamasa Watanabe Kotaro Matsunaga Nobuyuki Matsumoto Masaki Kato Ryo Morita Yousuke Michikawa Tomohiro Tamura Tetsuya Hiraishi Nobuhiro Hattori Yohei Noguchi Kazunari Nakahara Hiroki Ikeda Toshiya Ishii Chiaki Okuse Shigeru Sase Fumio Itoh Michihiro Suzuki 《International journal of molecular sciences》2016,17(9)
The progression of chronic liver disease differs by etiology. The aim of this study was to elucidate the difference in disease progression between chronic hepatitis C (CHC) and nonalcoholic fatty liver disease (NAFLD) by means of fibrosis markers, liver function, and hepatic tissue blood flow (TBF). Xenon computed tomography (Xe-CT) was performed in 139 patients with NAFLD and 152 patients with CHC (including liver cirrhosis (LC)). The cutoff values for fibrosis markers were compared between NAFLD and CHC, and correlations between hepatic TBF and liver function tests were examined at each fibrosis stage. The cutoff values for detection of the advanced fibrosis stage were lower in NAFLD than in CHC. Although portal venous TBF (PVTBF) correlated with liver function tests, PVTBF in initial LC caused by nonalcoholic steatohepatitis (NASH-LC) was significantly lower than that in hepatitis C virus (C-LC) (p = 0.014). Conversely, the liver function tests in NASH-LC were higher than those in C-LC (p < 0.05). It is important to recognize the difference between NAFLD and CHC. We concluded that changes in hepatic blood flow occurred during the earliest stage of hepatic fibrosis in patients with NAFLD; therefore, patients with NAFLD need to be followed carefully. 相似文献
26.
We prepared relatively uniform supported Ru catalysts by ion‐exchange and CVD methods, using an NaY zeolite and a mesoporous
FSM‐16 as substrates, and carried out CO2 hydrogenation. They showed high activity for CO2 hydrogenation. A Ru‐ion‐exchanged catalyst showed high activity for methanol production. Co addition promoted methanol formation.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
27.
Kotaro Hama Yuko Fujiwara Masashi Morita Fumiyoshi Yamazaki Yuko Nakashima Shiro Takei Shigeo Takashima Mitsutoshi Setou Nobuyuki Shimozawa Tsuneo Imanaka Kazuaki Yokoyama 《Lipids》2018,53(1):85-102
ABCD1 is a gene responsible for X‐linked adrenoleukodystrophy (X‐ALD), and is critical for the transport of very long‐chain fatty acids (VLCFA) into peroxisomes and subsequent β‐oxidation. VLCFA‐containing lipids accumulate in X‐ALD patients, although the effect of ABCD1‐deficiency on each lipid species in the central nervous system has not been fully characterized. In this study, each phospholipid and lysophospholipid species in Abcd1‐deficient mice brains were profiled by liquid chromatography‐mass spectrometry. Among the phospholipid and lysophospholipid species that are significantly more enriched in Abcd1‐deficient mice brains, VLCFA were present in 75, 15, 5, 4, and 1 species of phosphatidylcholine, phosphatidylethanolamine, sphingomyelin, lysophosphatidylcholine, and lysophosphatidylethanolamine, respectively. Most VLCFA were incorporated at the sn‐1 position of phosphatidylcholine and phosphatidylethanolamine. Among the phospholipid species that are significantly less enriched in Abcd1‐deficient mice brains, odd‐numbered saturated or mono‐unsaturated fatty acyl moieties are contained in all phosphatidylcholine species. In addition, a number of phosphatidylglycerol, phosphatidylinositol, and phosphatidylserine species contained highly unsaturated fatty acyl moieties. Intriguingly, 44:1 phosphatidylcholine with VLCFA was mainly distributed in the gray matter, such as the cortex, but not in the white matter in the cerebrum and cerebellum. These results show that ABCD1‐deficiency causes metabolic alternation of long‐chain fatty acids and VLCFA. Moreover, our results imply a molecular mechanism for the incorporation of saturated or monounsaturated VLCFA into the sn‐1 position of phospholipids, and also indicate that the distribution of phospholipids with VLCFA may correlate with the development of X‐ALD. 相似文献
28.
Feng Ren Shingo Ishida Nobuyuki Takeuchi 《Journal of the American Ceramic Society》1993,76(7):1825-1831
The distribution and chemical states of vanadium in V-doped ZrO2 were studied to clarify the origin of the color of vanadium-zirconium yellow pigment in comparison with vanadium-tin yellow pigment. ESCA data and measurements of lattice constants of V-doped ZrO2 revealed that vanadium was dissolved mainly as V4+ substituting for Zr in ZrO2 lattice, and its solubility limit was 0.5 wt% as V2 O5 . It was found that the yellow color of vanadium-zirconium yellow was produced predominantly by the dissolved vanadium and that the contribution of vanadium oxide on ZrO2 grains to the yellow color was about 1/30 of that of the dissolved vanadium when compared on the basis of equimolar quantity of vanadium. Most of the undissolved vanadium oxide was in an amorphous or a poorly crystallized state. 相似文献
29.
Nobuyuki Gokon Yusuke Osawa Daisuke Nakazawa Tatsuya Kodama 《International Journal of Hydrogen Energy》2009
Ni–Cr–Al metallic foam absorber with high porosity was catalytically activated using a Ru/γ-Al2O3 catalyst, and was subsequently tested with respect to CO2 reforming of methane in a small-scale volumetric receiver-reactor by using a sun-simulator. A chemical storage efficiency of 37% was obtained for a mean light flux of 325 kW m−2. Furthermore, the activity and the stability of the metallic foam absorber were compared with those of a SiC foam absorber activated with the same Ru/γ-Al2O3 catalyst for 50 h of light irradiation, and it was found that the metallic foam absorber has superior catalytic stability in comparison to the SiC form absorber. In addition, unlike ceramic foams such as SiC, metallic foams feature superior plasticity, which prevents the emergence of cracks caused by mechanical or thermal shock. 相似文献
30.
Masafumi Yamamoto Makoto Iwasaki Kazuaki Ito Nobuyuki Matsui 《Electrical Engineering in Japan》2010,171(2):31-39
This paper presents a modeling methodology for unknown disturbances in mechatronics systems, based on disturbance estimation using an iterative learning process. In disturbance modeling, nonlinear frictions are specially handled as disturbances in the mechanisms, which mainly degrade trajectory control performance. Friction can be mathematically modeled by using learned estimation data as a function of the displacement, velocity. acceleration, and jerk of the actuator. This model has the distinctive feature that friction compensation can be achieved with a generalization capability for different conditions. The proposed positioning control approach with disturbance modeling and compensation has been verified by experiments using a table drive system on a machine stand. © 2010 Wiley Periodicals, Inc. Electr Eng Jpn, 171(2): 31–39, 2010; Published online in Wiley InterScience ( www. interscience.wiley.com ). DOI 10.1002/eej.20928 相似文献