Application of MIKE SHE modelling system to set up a detailed water balance computation

Estimation of total water balance is a substantial issue for watershed modelling in order to simulate the major components of the hydrological cycle to determine the stress of different anthropogenic activities on the available water resources within a catchment. In this context, the fully distributed physically based MIKE SHE modelling system was used to simulate the individual hydrological components of the total water balance for the Paya Indah Wetlands (PIW) watershed in the west of Peninsular Malaysia. Results reveal that the overall water balance is predominantly controlled by climate variables. Application of the model to the PIW watershed provides detailed estimation of the total water balance for a first‐order catchment in which actual evapotranspiration (ET) represents approximately 65 and 58%, while overland flow (OL) to the PIW lake system represents 12.38 and 12.3% of the total rainfall during the calibration and validation periods, respectively. The difference of the inflow and outflow was taken as storage in depth. Overall, the model gives a reasonable output of total error of less than 1% of the total rainfall, which in turn indicates that the interaction among components is satisfactorily sustained.     

Comparison Between Anode‐Supported and Electrolyte‐Supported Ni‐CGO‐LSCF Micro‐tubular Solid Oxide Fuel Cells

Two types of micro‐tubular hollow fiber SOFCs (MT‐HF‐SOFCs) were prepared using phase inversion and sintering; electrolyte‐supported, based on highly asymmetric Ce_0.9Gd_0.1O_1.95(CGO) HFs and anode‐supported based on co‐extruded NiO‐CGO(CGO)/CGO HFs. Electroless plating was used to deposit Ni onto the inner surfaces of the electrolyte‐supported MT‐HF‐SOFCs to form Ni‐CGO anodes. LSCF‐CGO cathodes were deposited on the outer surface of both these MT‐HF‐SOFCs before their electrochemical performances were compared at similar operating conditions. The performance of the anode‐supported MT‐HF‐SOFCs which delivered ca. 480 mW cm^–2 at 600 °C was superior to the electrolyte‐supported MT‐HF‐SOFCs which delivered ca. six times lower power. The contribution of ohmic and electrode polarization losses of both FCs was investigated using electrochemical impedance spectroscopy. The electrolyte‐supported MT‐HF‐SOFCs had significantly higher ohmic and electrode polarization ASR values; this has been attributed to the thicker electrolyte and the difficulties associated with forming quality anodes inside the small (<1 mm) lumen of the electrolyte tubes. Further development on co‐extruded anode‐supported MT‐HF‐SOFCs led to the fabrication of a thinner electrolyte layer and improved electrode microstructures which delivered a world leading 2,400 mW cm^–2. The newly made cell was investigated at different H₂ flow rates and the effect of fuel utilization on current densities was analyzed.     

Thiol-functionalised mesoporous silica-coated magnetite nanoparticles for high efficiency removal and recovery of Hg from water

The preparation and testing of thiol-functionalised silica-coated magnetite nanoparticles (TF-SCMNPs) is described. The characteristics of these particles are assessed at different stages in the production process using X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier Transform Infrared Spectroscopy (FTIR), and a magnetometer. The particles were found to be almost spherical with a uniform mesoporous structure with a pore size of ∼2.1 nm. The particles were strongly responsive to an external magnetic field making separation from solution possible in less than 1 min. The adsorption characteristics of the particles were quantified in a series of isotherm experiments using Hg(II) solution concentrations between 40 and 1000 μg l⁻¹ at adsorbent concentrations of 4 and 8 mg l⁻¹. The adsorption capacity was higher than for other commonly used adsorbents with 90% of Hg(II) removed during the first 5 min and equilibrium in less than 15 min. Both the Langmuir and Freundlich isotherm models were applied to the isotherm data and the maximum adsorption capacity was achieved when the ratio of adsorbent to adsorbate was low. Both temperature and pH had an effect on adsorption but when the TF-SCMNPs were used for removal of Hg(II) from tap water and bottled water, which contained other ions, there appeared to be no interference. Hg(II) could be successfully desorbed using thiourea in a 3 M HCl solution; this did not result in the destruction of the nanoparticles and they could subsequently be reused without loss of their activity in repetitive adsorption tests.     

Estimation of optimum binder content of recycled asphalt incorporating a wax warm additive using response surface method

This paper presents a new approach to estimate the optimum binder content (OBC) of recycled asphalts (RAs) incorporating a warm mix additive based on the interaction effects of compaction temperature, RA content and binder content using volumetric and strength characterisation. The experimental design was developed using response surface method (RSM) based on central composite design for various compaction temperatures (130–160 °C), RA contents (30–50%) and binder contents (4.9–6.0%). Laboratory tests were performed and analysed to meet the desired volumetric and strength properties according to the Malaysian specifications for the design of dense asphalt mixtures. Statistical analysis and mathematical models proposed by RSM were used to determine the OBC. The results showed that compaction temperature is the most significant factor in determining the OBC. There are minimum differences in the OBC variation of samples incorporating different dosage of RA. The developed model can be used for quick estimation of OBC for various levels of compaction temperature and RA content.     

Cut‐off Frequencies Induced by the Length of Strain Gauges Measuring Impact Events

Abstract: The finite length of strain gauges may induce filtering effects when measuring impact events. In this study, we are interested in quantifying these effects. Precisely, we determined the cut‐off frequencies of strain gauges cemented on visco‐elastic bars and measuring impact‐induced strain waves. This study shows that the cut‐off frequencies increase with the bar’s wave velocity and decrease with the bar’s diameter. The asymptotic value, corresponding to an infinite bar diameter, is reached rapidly (bar diameter ≈ 15 mm). Moreover, we showed that the mode cut‐off frequencies are more severe (lower) than the gauge length cut‐off frequencies for bar diameters greater than 8 mm.     

Plane Waves of a Fiber-Reinforcement Magneto-thermoelastic Comparison of Three Different Theories

In this article, the coupled theory, Lord–Shulman theory, and Green–Lindsay (GL) theory are used to study the influence of a magnetic field on a fiber-reinforced thermoelastic half-space. Normal mode analysis is used to solve a thermal shock problem. Numerical results for the temperature, displacement components, and stress components are given and illustrated graphically. A comparison is made between the coupled and GL theories in the absence and presence of a magnetic field and reinforcement.     

Plane Waves in Generalized Thermo-microstretch Elastic Solid with Thermal Relaxation Using Finite Element Method

The propagation of plane waves in a thermo-microstretch elastic solid half-space as proposed by Lord?CShulman as well as the classical dynamical coupled theory are discussed. The problem has been solved numerically using a finite element method. Numerical results for the displacement components, force stresses, temperature, couple stresses, and microstress distribution are obtained. The variations of the considered variables through the horizontal distance are given and illustrated graphically. Comparisons are made with the results predicted by the theory of generalized thermoelasticity for different values of the relaxation time.     

Transition to turbulence in rotating-disk boundary layers—convective and absolute instabilities

This work is an experimental study of mechanisms for transition to turbulence in the boundary layer on a rotating disk. In one case, the focus was on a triad resonance between pairs of traveling cross-flow modes and a stationary cross-flow mode. The other was on the temporal growth of traveling modes through a linear absolute instability mechanism first discovered by Lingwood (1995, J Fluid Mech 314:373–405). Both research directions made use of methods for introducing controlled initial disturbances. One used a distributed array of ink dots placed on the disk surface to enhance a narrow band of azimuthal and radial wave numbers of both stationary and traveling modes. The size of the dots was small so that the disturbances they produce were linear. Another approach introduced temporal disturbances by a short-duration air pulse from a hypodermic tube located above the disk and outside the boundary layer. Hot-wire sensors primarily sensitive to the azimuthal velocity component, were positioned at different spatial (r,θ) locations on the disk to document the growth of disturbances. Spatial correlation measurements were used with two simultaneous sensors to obtain wavenumber vectors. Cross-bicoherence was used to identify three-frequency phase locking. Ensemble averages conditioned on the air pulses revealed wave packets that evolved in time and space. The space–time evolution of the leading and trailing edges of the wave packets were followed past the critical radius for the absolute instability, r _{c A} . With documented linear amplitudes, the spreading of the disturbance wave packets did not continue to grow in time as r _{c A} was approached. Rather, the spreading of the trailing edge of the wave packet decelerated and asymptotically approached a constant. This result supports the linear DNS simulations of Davies and Carpenter (2003, J Fluid Mech 486:287–329) who concluded that the absolute instability mechanism does not result in a global mode, and that linear-disturbance wave packets are dominated by the convective instability. In contrast, wave-number matching between traveling cross-flow modes confirmed a triad resonance that lead to the growth of a low azimuthal number (n = 4) stationary mode. At transition, this mode had the largest amplitude. Signs of this mechanism can be found in past flow visualization of transition to turbulence in rotating disk flows.     

Pretreatment of palm oil mill effluent (POME) using Moringa oleifera seeds as natural coagulant

Moringa oleifera seeds, an environmental friendly and natural coagulant are reported for the pretreatment of palm oil mill effluent (POME). In coagulation-flocculation process, the M. oleifera seeds after oil extraction (MOAE) are an effective coagulant with the removal of 95% suspended solids and 52.2% reduction in the chemical oxygen demand (COD). The combination of MOAE with flocculant (NALCO 7751), the suspended solids removal increased to 99.3% and COD reduction was 52.5%. The coagulation-flocculation process at the temperature of 30 degrees C resulted in better suspended solids removal and COD reduction compared to the temperature of 40, 55 and 70 degrees C. The MOAE combined with flocculant (NALCO 7751) reduced the sludge volume index (SVI) to 210mL/g with higher recovery of dry mass of sludge (87.25%) and water (50.3%).