Spectroscopic studies and evanescent optical fibre wave sensing of Cu<Superscript>2+</Superscript> based on activated mesostructured silica matrix

This paper report on the synthesis and test of eriochrome cyanine R (ECR) doped mesostructured silica films as Cu²⁺ sensing without prior removal of the surfactant. ECR activated mesostructured silica (via sol-gel technique) coated optical fibre core were used to Cu²⁺ sensing by evanescent wave method. The sol was prepared via acidic hydrolysis-condensation of tetraethoxysilane (TEOS) in the presence of cetyltrimethylammonium bromide (CTAB:C₁₆H₃₃NCH₃Br) as the structure-directing agent. Spectrophotometric investigations using doped sol-gel thin films dip-coated on glass slides were reported. Heat treatment temperature effect (optimum temperature 150°C), absorption dependence on the pH of the aqueous phase (pH = 8 seems to be the optimal absorption pH), sensitivity, reversibility and response range (0.05 mmol/l) were reported.     

Plane Waves in Generalized Thermo-microstretch Elastic Solid with Thermal Relaxation Using Finite Element Method

The propagation of plane waves in a thermo-microstretch elastic solid half-space as proposed by Lord?CShulman as well as the classical dynamical coupled theory are discussed. The problem has been solved numerically using a finite element method. Numerical results for the displacement components, force stresses, temperature, couple stresses, and microstress distribution are obtained. The variations of the considered variables through the horizontal distance are given and illustrated graphically. Comparisons are made with the results predicted by the theory of generalized thermoelasticity for different values of the relaxation time.     

Tryptophan-containing mutant of human (group IIa) secreted phospholipase A2 has a dramatically increased ability to hydrolyze phosphatidylcholine vesicles and cell membranes

Human nonpancreatic (group IIa) secreted phospholipase A2 (human sPLA2) is associated with a number of inflammatory disorders in which the extracellular concentrations of this enzyme can become highly elevated. It is probable that the enzyme normally acts as an acute-phase protein whose function is to facilitate the removal of infectious organisms or damaged host cells as part of the normal inflammatory response. The enzyme shows negligible activity with phosphatidylcholine (PC) vesicles and cell membranes, presumably reflecting the enzyme's lack of ability to bind productively to such condensed neutral interfaces. Mammalian pancreatic enzymes show modest activity with such interfaces and contain a unique tryptophan at position 3, which is part of the presumptive interfacial binding surface of these enzymes. Human sPLA2 does not contain tryptophan. The amphiphilic indole side chain of tryptophan is noted for its ability to penetrate the lipid interface of membranes, and tryptophan residues appear to be associated with the ability of lipases and phospholipases A2 to bind to and hydrolyze such interfaces. We have investigated in detail the properties of a V3W mutant of human sPLA2, which has a unique tryptophan on the interfacial binding surface of this enzyme. Although this enzyme shows a modest ( approximately 50%) reduction in activity when anionic substrates are used under standard assay conditions, the activity of the enzyme on phosphatidylcholine vesicles and cell membranes is dramatically increased compared with human sPLA2. This is particularly the case with small unilamellar vesicles of PC, where activity is enhanced over 250-fold compared to the almost zero activity expressed by human sPLA2. This enhanced activity is best explained by increased interfacial binding and activation of the V3W mutant and is not due to enhanced active-site binding and hydrolysis. The results highlight the important role that tryptophan residues can play in interfacial binding, particularly to condensed zwitterionic interfaces. The interfacial characteristics of the mutant human enzyme now resemble more closely the mammalian pancreatic enzymes that already have a tryptophan at position 3.     

Delay Mitigation in the Malaysian Construction Industry

This paper describes the importance of applying proper management in dealing with delays in construction for a growing economy. The main objective of this paper is to identify the management tools that are practiced in the local construction industry in mitigating delay. It also aims to identify the main factors that lead to project delays and to suggest recommendations on how to overcome or mitigate effects of the problem. Data is gathered from responses from questionnaire survey and interviews with those involved in construction project. The surveys and research findings indicate that delay incidents occur mainly during the construction phase of a project and one or more parties usually contribute to delay. This paper highlights the importance of having more experienced and capable construction managers as well as skilled laborers to enable the industry to develop at a faster rate either nationally or internationally.     

Unglazed Fiberglass Reinforced Polyester Solar Water Heater with Integrated Storage System

Theoretical and experimental investigations on an unglazed solar hot water heater with integrated storage system were conducted. The system was comprised of a collector and storage tank which was integrated into one unit. All parts of the system have been fabricated from fiberglass reinforced polyester (GFRP). The absorber plate has water tubes of semielliptical shape. The width and length of the absorber plate were 1.4 and 1.8?m, respectively. The absorber plate was fabricated from GFPR using a special resin composition that provides good thermal conductivity and absorptivity. The storage tank has a capacity of 496?L. The storage tank is of sandwich construction with a core material made of polyurethane foam that combines stiffness and lightness of the structure with very good thermal insulation properties. An average tank temperature of 53°C was achieved at an average solar radiation level of 700?W/m2 and ambient temperature of 28°C. The thermal efficiencies of the system were evaluated at 48 and 57% for cloudy and clear days, respectively. Transient performance of the system was predicted by solving the mathematical models consisting of energy balance equations of the system that have been converted to finite difference form and solved by a personal computer. The experimental results were in close agreement as has been found with the theoretical predictions.     

SRA-MSDU: Enhanced A-MSDU frame aggregation with selective retransmission in 802.11n wireless networks

The main goal of the IEEE 802.11n standard is to achieve more than 100 Mbps of throughput at the MAC service access point. This high throughput has been achieved via many enhancements in both the physical and MAC layers. One of the MAC enhancements is the frame aggregation in which multiple frames are concatenated into a single large frame before being transmitted. The 802.11n MAC layer defines two types of aggregation, aggregate MAC service data unit (A-MSDU) and aggregate MAC protocol data unit (A-MPDU). The A-MPDU outperforms A-MSDU due to its large aggregation size and the subframes retransmission in erroneous channels. However, in error free channels and under the same aggregation size the A-MSDU performs better than the A-MPDU due to its smaller headers. Thus, adding a selective retransmission capability to the A-MSDU would improve the system performance. In this paper, we have proposed an MSDU frame aggregation scheme that enables selective retransmission at the MSDU level without altering the original MAC header. In this proposed scheme an implicit sequence control mechanism has been introduced in order to keep the frames in sequence and preserve their correct order at the receiver side. The results show that the proposed scheme improves the system performance in terms of throughput and delay even under highly erroneous channels.     

Effect of Te additions on the glass transition and crystallization kinetics of (Sb15As30Se55)100−xTex amorphous solids

Differential scanning calorimetry results under non-isothermal conditions of chalcogenide (Sb₁₅As₃₀Se₅₅)_100?xTe_x (where 0 ≤ x ≤ 10 at.%) glasses are reported and discussed. The dependence of the characteristic temperatures “glass transition temperature (T_g), the crystallization onset temperature (T_c) and the crystallization temperature (T_p)” on the heating rate (β) utilized in the determination of the activation energy for the glass transition (E_g), the activation energy for crystallization (E_c), the glass thermal stability (ΔT = T_c ? T_g) and the Avrami exponent (n). The composition dependence of the T_g, E_g, and E_c were discussed in terms of the chemical bond approach, the average heats of atomization and the cohesive energy (CE). The diffractogram of the transformed material shows the presence of some crystallites of AsSb, Sb₄Te₆, As₂Se₃ and Sb₂Se₃ in the residual amorphous matrix.     

Benefits valuation of potable water quality improvement in Malaysia: the case of Kajang Municipality

This article estimates the benefits of potable water quality improvements in Kajang Municipality in the state of Selangor, Malaysia, using the avertive cost method. Households were willing to pay MYR 322 annually to improve potable water quality. This represents about 80% of their average annual water bill. The present value of aggregate benefits over a period of 30 years at various social discount rates ranged from MYR 301 million to MYR 768 million. These estimates can be used as a reference for public investment criteria. The findings suggest that there is merit in an upward revision of water tariffs if they provide improvements in water quality.     

Robust control design of power system stabilizers using multivariable frequency domain techniques

H_∞ and structured singular value optimization techniques are used to design robust power system stabilizers (PSS) for a single-machine and a two-machine system with varying operating conditions. Realistic uncertainty models to represent the possible operating conditions as perturbations from a nominal operating condition are developed. System experience is used to select weighting functions to provide adequate damping and shape the controller frequency response. Computer simulations show that the PSS designed using the proposed technique provides improved damping compared to a conventional PSS.