全文获取类型
收费全文 | 1983篇 |
免费 | 30篇 |
国内免费 | 6篇 |
专业分类
电工技术 | 79篇 |
综合类 | 2篇 |
化学工业 | 507篇 |
金属工艺 | 48篇 |
机械仪表 | 51篇 |
建筑科学 | 19篇 |
能源动力 | 61篇 |
轻工业 | 121篇 |
水利工程 | 11篇 |
无线电 | 261篇 |
一般工业技术 | 330篇 |
冶金工业 | 318篇 |
原子能技术 | 49篇 |
自动化技术 | 162篇 |
出版年
2022年 | 12篇 |
2021年 | 20篇 |
2020年 | 14篇 |
2019年 | 12篇 |
2018年 | 22篇 |
2017年 | 12篇 |
2016年 | 25篇 |
2015年 | 30篇 |
2014年 | 30篇 |
2013年 | 71篇 |
2012年 | 57篇 |
2011年 | 91篇 |
2010年 | 70篇 |
2009年 | 81篇 |
2008年 | 79篇 |
2007年 | 74篇 |
2006年 | 68篇 |
2005年 | 60篇 |
2004年 | 68篇 |
2003年 | 84篇 |
2002年 | 61篇 |
2001年 | 45篇 |
2000年 | 40篇 |
1999年 | 52篇 |
1998年 | 143篇 |
1997年 | 78篇 |
1996年 | 83篇 |
1995年 | 67篇 |
1994年 | 48篇 |
1993年 | 50篇 |
1992年 | 38篇 |
1991年 | 25篇 |
1990年 | 18篇 |
1989年 | 29篇 |
1988年 | 22篇 |
1987年 | 16篇 |
1986年 | 22篇 |
1985年 | 26篇 |
1984年 | 30篇 |
1983年 | 20篇 |
1982年 | 15篇 |
1981年 | 21篇 |
1980年 | 14篇 |
1979年 | 9篇 |
1978年 | 13篇 |
1977年 | 19篇 |
1976年 | 11篇 |
1973年 | 4篇 |
1972年 | 5篇 |
1967年 | 3篇 |
排序方式: 共有2019条查询结果,搜索用时 15 毫秒
31.
Makoto Ishiguro Katsufumi Ohmuro Yukito Saitoh Yuuta Takahashi Jun Watanabe Tsutomu Arai Yoji Ito Keiji Mihayashi 《Journal of the Society for Information Display》2012,20(11):598-603
We have successfully developed a quarter‐wave retardation film (QWF) for wide viewing angle 3D liquid crystal displays (3D‐LCDs) that provides high luminance, low crosstalk, low color change, and low head‐tilt‐angle dependency. It was found that the out‐of‐plane retardation (Rth) of the QWF in the LCD needs to be close to 0 nm in order to improve the 3D display properties at an off‐axis position and that the in‐plane retardation (Re) needs to be adjusted from 120 to 130 nm to achieve low color change with head tilting. We adopted a coating process for making our QWF because of its potential for retardation control. 3D‐LCDs with this QWF whose Rth was nearly zero had high performance and allowed off‐axis other than on‐axis. 相似文献
32.
Electrical conductivity of two types of lanthanum-doped barium titanote ceramics with different dopant levels was measured at temperatures between 900 and 1250° C andP
O
2from 10–5 to 1 atm. The activation energies of the conduction for the two are interpreted in terms of the formation energy of ionized oxygen vacancies even in such a highP
O
2region. This fact is in contrast with a well -known controlled -valency model proposed for rare- earth -doped semi-conducting perovskites. In a lightly lanthanum-doped specimen, semiconduction achieved at elevated temperatures is retained on cooling the specimen to room temperature, whereas in a heavily doped specimen, the resultant high-temperature semiconduction changed to insulation on cooling. The former behaviour on cooling is successfully explained by a metastabilization of oxygen vacancies accompanied by electrons formed at elevated temperatures. 相似文献
33.
Fe-30Ni alloy specimens were oxidized for 10–240 min at 433–473 K in pure oxygen at a pressure of 1.33×104 Pa. The thickness of oxide films was measured by a multiple-angle-of-incidence ellipsometer. The kinetics of film growth were found to obey a parabolic rate law. The depth-profiling of oxidized surfaces, performed with simultaneous use of Auger electron spectroscopy (AES) and argon-ion sputter-etching technique, reveals that iron component is selectively oxidized and an iron-depeletion zone is formed in the underlying alloy. The thickness of the iron depletion zone increases with increasing oxidation time or oxidation temperature. During surface oxidation of the alloy, the transport rate of iron component in the film is almost equal to the interdiffusion rate in the underlying alloy, indicating the establishment of a steady state. The values of the interdiffusion coefficient,
, of the underlying alloy estimated from the depth-composition profiles are more than 10 orders of magnitude as large as the values extrapolated from the lattice diffusion data of the corresponding alloy obtained at high temperature. The enormously large values of
may be explained in terms of the vacancy (monovacancy or divacancy)-enhanced lattice diffusion mechanism. 相似文献
34.
Silk fibers and membranes were acylated with octadecenylsuccinic anhydride (ODSA) at 75°C for different times. Swelling [N,N‐dimethylformamide (DMF) and dimethyl sulfoxide (DMSO)] and nonswelling (xylene) solvent media were used for the reaction. Silk membranes that reacted in DMF or DMSO displayed faster reaction kinetics and attained higher weight‐gain values than fibers. The effect of the solvent on the reaction yield was in the following order: DMSO > DMF ? xylene. The Fourier transform infrared spectra of acylated silk samples showed the characteristic absorption bands of the anhydride at 2990, 2852, 1780–1700, and 1170 cm?1. The intensity of the latter band, which increased linearly with the weight gain, was used as a marker for evaluating the reaction kinetics of the samples acylated in the nonswelling medium. The moisture regain and water retention of silk fibers acylated with ODSA decreased significantly, regardless of the solvent system used. Accordingly, the water repellency increased. Acylation induced an increase in the thermal stability of the silk fibers and membranes. Fine particles adhering to the surfaces of the silk fibers acylated in xylene were detected by scanning electron microscopy. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 324–332, 2003 相似文献
35.
Masuhiro Tsukada Hiroshi Katoh Donna Wilson Bong‐Seob Shin Takayuki Arai Ritsuko Murakami Giuliano Freddi 《应用聚合物科学杂志》2002,86(5):1181-1188
The work presented here discusses a new technique for preparing silk fibers and films with persistent antimicrobial activity through use of metallic dyestuffs during the fiber dyeing process. The length of the silk fibers investigated contracted when the fibers were immersed in concentrated neutral salt solutions, such as calcium or potassium nitrate, at elevated temperature levels. The birefringence and molecular orientation of the silk fibroin molecules became less ordered by the action of the neutral salt solutions, resulting in increased dyestuff absorption. Subsequently, contracted silk fibers were dyed with metallic dyestuffs containing Cr or Cu for the purpose of obtaining silk fibers with antimicrobial activity. Silk fibers dyed with metallic dyestuffs showed significant antimicrobial activity against the plant pathogen Cornebacterium and the human pathogen Coli bacillus. Tensile strength of the silk fibers after the salt shrinking and dyeing processes did not show a significant change, whereas the elongation at break was increased slightly. The techniques described here for preparing significantly active antimicrobial silk fibers are effective and economic ways of providing new materials for industrial and biomedical applications. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1181–1188, 2002 相似文献
36.
Amr Almaddah Sadi Vural Yasushi Mae Kenichi Ohara Tatsuo Arai 《Machine Vision and Applications》2014,25(4):845-857
As part of the face recognition task in a robust security system, we propose a novel approach for the illumination recovery of faces with cast shadows and specularities. Given a single 2D face image, we relight the face object by extracting the nine spherical harmonic bases and the face spherical illumination coefficients by using the face spherical spaces properties. First, an illumination training database is generated by computing the properties of the spherical spaces out of face albedo and normal values estimated from 2D training images. The training database is then discriminately divided into two directions in terms of the illumination quality and light direction of each image. Based on the generated multi-level illumination discriminative training space, we analyze the target face pixels and compare them with the appropriate training subspace using pre-generated tiles. When designing the framework, practical real-time processing speed and small image size were considered. In contrast to other approaches, our technique requires neither 3D face models nor restricted illumination conditions for the training process. Furthermore, the proposed approach uses one single face image to estimate the face albedo and face spherical spaces. In this work, we also provide the results of a series of experiments performed on publicly available databases to show the significant improvements in the face recognition rates. 相似文献
37.
Novel nanocomposite films of TiO2 nanoparticles and hydrophobic polymers having polar groups, poly (bisphenol‐A and epichlorohydrin) or copolymer of styrene and maleic anhydride, with high refractive indices, high transparency, no color, solvent‐resistance, good thermal stability, and mechanical properties were prepared by incorporating surface‐modified TiO2 nanoparticles into polymer matrices. In the process of preparing colloidal solution of TiO2 nanoparticles, severe aggregation of particles can be reduced by surface modification using carboxylic acids and long‐chain alkyl amines. These TiO2 nanoparticles dispersed in solvents were found not to aggregate after mixing with polymer solutions. Transparent colorless free‐standing films were obtained by drying a mixture of TiO2 nanoparticles colloidal solution and polymer solutions in vacuum. Transmission electronic microscopic studies of the films suggest that the TiO2 nanoparticles of 3–6 nm in diameter were dispersed in polymer matrices while maintaining their original size. Thermogravimetric analysis results indicate that the nanocomposite film has good thermal stability and the weight fraction of observed TiO2 nanoparticles in the film is in good accordance with that of theoretical calculations. The refractive index of nanocomposite films of TiO2 and poly(bisphenol‐A and epichlorohydrin) was in the range of 1.58–1.81 at 589 nm, which linearly increased with the content of TiO2 nanoparticles from 0 to 80 wt %. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
38.
39.
Efficient usage of highly dispersed Pt on carbon nanotubes for electrode catalysts of polymer electrolyte fuel cells 总被引:2,自引:0,他引:2
T. Matsumoto T. Komatsu H. Nakano K. Arai Y. Nagashima E. Yoo T. Yamazaki M. Kijima H. Shimizu Y. Takasawa J. Nakamura 《Catalysis Today》2004,90(3-4):277-281
A Pt-deposited carbon nanotube (CNT) shows higher performance than a commercial Pt-deposited carbon black (CB) with reducing 60% Pt load per electrode area in polymer electrolyte fuel cells (PEFCs) below 500 mA/cm2. K2PtCl4 and H2PtCl6·6(H2O) are used for the Pt deposition onto multi-walled CNTs (MWCNTs), which are produced by the catalytic decomposition of hydrocarbons. The electric power densities produced using the Pt/CNT electrodes are greater than that of the Pt/CB by a factor of two to four on the basis of the Pt load per power. CNTs are thus found to be a good support of Pt particles for PEFC electrodes. TEM images show 2–4-nm Pt nanoparticles dispersed on the CNT surfaces. These high performances are considered to be due to the efficient formation of the triple-phase boundaries of gas–electrode–electrolyte. The mechanisms of Pt deposition are discussed for these Pt-deposited CNTs. 相似文献
40.
Arai Kazuhito; Hishida Atsushi; Ishiyama Mariko; Kamata Takeo; Uchikoba Hiroyuki; Fushinobu Shinya; Matsuzawa Hiroshi; Taguchi Hayao 《Protein engineering, design & selection : PEDS》2002,15(1):35-41
Lactobacillus casei allosteric L-lactate dehydrogenase (L-LDH)absolutely requires fructose 1,6-bisphosphate [Fru(1,6)P2] forits catalytic activity under neutral conditions, but exhibitsmarked catalytic activity in the absence of Fru(1,6)P2 underacidic conditions through the homotropic activation effect ofsubstrate pyruvate. In this enzyme, a single amino acid replacement,i.e. that of His205 conserved in the Fru(1,6)P2-binding siteof certain allosteric L-LDHs of lactic acid bacteria with Thr,did not induce a marked loss of the activation effect of Fru(1,6)P2or divalent metal ions, which are potent activators that improvethe activation function of Fru(1,6)P2 under neutral conditions.However, this replacement induced a great loss of the Fru(1,6)P2-independentactivation effect of pyruvate or pyruvate analogs under acidicconditions, consequently indicating an absolute Fru(1,6)P2 requirementfor the enzyme activity. The replacement also induced a significantreduction in the pH-dependent sensitivity of the enzyme to Fru(1,6)P2,through a slight decrease and increase of the Fru(1,6)P2 sensitivityunder acidic and neutral conditions, respectively, indicatingthat His205 is also largely involved in the pH-dependent sensitivityof L.casei L-LDH to Fru(1,6)P2. The role of His205 in the allostericregulation of the enzyme is discussed on the basis of the knowncrystal structures of L-LDHs. 相似文献