Photoactive chitosan–titania multilayer assembly for oxidative dye degradation

This study highlights the highly efficient adsorption, photocatalytic properties, and stability of synthesized titanium dioxide (TiO₂) photocatalyst incorporated into Chitosan (Cs) and supported onto the glass as substrate toward photodegradation of methyl orange (MO) pollutants. TiO₂ was produced using a sol–gel technique, then ex situ synthesized with Cs solution and immobilized on a glass substrate at various weight ratios. The percentages and concentrations of the sorption in dark ambient are calculated in addition to photodegradation of MO under UV light irradiation. At acidic conditions, the photocatalyst with a 2:2 weight ratio of Cs-TiO₂ had the optimum dye removal activity (91%). As a result, the work adds to the knowledge of adsorption and photodegradation in the green mitigation of persistent pollutants.

     

Influence of powder characteristics on cold sintering of nano-sized ZnO with density above 99 %

Cold sintering parameters such as, temperature, pressure, aqueous phase, heating rate and dwelling time has been widely discussed in the literature but the role of starting powder with respective microstructure development is mostly overlooked. There is a need for understanding the effect of powder agglomerates and the role of inter particle friction on the densification behavior during cold sintering process. Present study encompasses investigation and optimization of these parameters for ZnO which enabled > 99 % of relative density with grain sizes below 200 nm. Additionally, role of external atmosphere was also studied to investigate its impact on densification during the process. All cold sintering experiments were carried out in a FAST/SPS device for studying aqueous phase evaporation and ensuring the reproducibility of process parameters. Microstructure characterization (scanning and transmission electron microscopy) showed – without any post heat treatment– defect free grain boundary structure opposite to what documented by previous studies.     

SA-Mediated Regulation and Control of Abiotic Stress Tolerance in Rice

Environmental or abiotic stresses are a common threat that remains a constant and common challenge to all plants. These threats whether singular or in combination can have devastating effects on plants. As a semiaquatic plant, rice succumbs to the same threats. Here we systematically look into the involvement of salicylic acid (SA) in the regulation of abiotic stress in rice. Studies have shown that the level of endogenous salicylic acid (SA) is high in rice compared to any other plant species. The reason behind this elevated level and the contribution of this molecule towards abiotic stress management and other underlying mechanisms remains poorly understood in rice. In this review we will address various abiotic stresses that affect the biochemistry and physiology of rice and the role played by SA in its regulation. Further, this review will elucidate the potential mechanisms that control SA-mediated stress tolerance in rice, leading to future prospects and direction for investigation.     

Wide-bandgap HfO2-V2O5 nanowires heterostructure for visible light-driven photocatalytic degradation

A novel HfO₂/V₂O₅ nanocomposite has been fabricated for use as photocatalyst. HfO₂ nanoparticles (NPs) were deposited on V₂O₅ using a precipitation method. Both commercial V₂O₅ particles and microwave-assisted hydrothermal (MAH)-synthesized V₂O₅ nanowires (NWs) were used. We demonstrate that the HfO₂/V₂O₅ nanocomposite exhibits better photodegradation efficiency than the V₂O₅. The photodegradation reaction constant of the HfO₂/V₂O₅ nanocomposite is more than 66% higher than that of the V₂O₅. The wide-bandgap, transparent HfO₂ effectively reduces the electron-hole recombination by proving defect levels to quench the recombination. A plausible band structure is proposed to support the existence of these defect levels.     

Role of Mn/Al2O3 catalyst in deep oxidative desulfurization of diesel

Abstract

In this work, a series of supported manganese catalyst has been synthesized and utilized in oxidative desulfurization to remove 4,6-dimethyldibenzothiophene (4,6-DMDBT), dibenzothiophene (DBT) and thiophene. The influences of catalyst parameters were investigated including manganese precursors, manganese loading and calcination temperature in details. The synthesized catalyst was characterized by scanning electron microscopy (SEM), N₂ adsorption/desorption and X-ray diffraction (XRD) techniques. 90.2% of 4,6-DMDBT, 98.5% of DBT and 95.5% of thiophene conversion were achieved under mild operational conditions using 3Mn(NO₃)₂/Al₂O₃ at 500?°C calcination temperature. A slight decrease in desulfurization activity was observed after Mn/Al₂O₃ catalyst being used in five cycles ODS.     

Biovanillin from agro wastes as an alternative food flavour

This review provides an overview of biovanillin production from agro wastes as an alternative food flavour. Biovanillin is one of the widely used flavour compounds in the foods, beverages and pharmaceutical industries. An alternative production approach for biovanillin as a food flavour is hoped for due to the high and variable cost of natural vanillin as well as the limited availability of vanilla pods in the market. Natural vanillin refers to the main organic compound that is extracted from the vanilla bean, as compared to biovanillin, which is produced biologically by microorganisms from a natural precursor such as ferulic acid. Biovanillin is also reviewed as a potential bioflavour produced by microbial fermentation in an economically feasible way in the near future. In fact, we briefly discuss natural, synthetic and biovanillin and the types of agro wastes that are useful as sources for bioconversion of ferulic acid into biovanillin. The subsequent part of the review emphasizes the current application of vanillin as well as the utilization of biovanillin as an alternative food flavour. The final part summarizes biovanillin production from agro wastes that could be of benefit as a food flavour derived from potential natural precursors.© 2012 Society of Chemical Industry     

The Role of Extracellular Carbonic Anhydrase in Biogeochemical Cycling: Recent Advances and Climate Change Responses

Climate change has been predicted to influence the marine phytoplankton community and its carbon acquisition strategy. Extracellular carbonic anhydrase (eCA) is a zinc metalloenzyme that catalyses the relatively slow interconversion between HCO₃⁻ and CO₂. Early results indicated that sub-nanomolar levels of eCA at the sea surface were sufficient to enhance the oceanic uptake rate of CO₂ on a global scale by 15%, an addition of 0.37 Pg C year⁻¹. Despite its central role in the marine carbon cycle, only in recent years have new analytical techniques allowed the first quantifications of eCA and its activity in the oceans. This opens up new research areas in the field of marine biogeochemistry and climate change. Light and suitable pH conditions, as well as growth stage, are crucial factors in eCA expression. Previous studies showed that phytoplankton eCA activity and concentrations are affected by environmental stressors such as ocean acidification and UV radiation as well as changing light conditions. For this reason, eCA is suggested as a biochemical indicator in biomonitoring programmes and could be used for future response prediction studies in changing oceans. This review aims to identify the current knowledge and gaps where new research efforts should be focused to better determine the potential feedback of phytoplankton via eCA in the marine carbon cycle in changing oceans.     

Multi-wavelength Q-switched Erbium-doped fiber laser with photonic crystal fiber and multi-walled carbon nanotubes

A simple multi-wavelength passively Q-switched Erbium-doped fiber laser (EDFL) is demonstrated using low-cost multi-walled carbon nanotubes (MWCNTs)-based saturable absorber, which is prepared using polyvinyl alcohol as a host polymer. The multi-wavelength operation is achieved based on non-linear polarization rotation effect by incorporating 50?m long photonic crystal fiber in the ring cavity. The EDFL produces a stable multi-wavelength comb spectrum for more than 14 lines with a fixed spacing of 0.48?nm. The laser also demonstrates a stable pulse train with the repetition rate increasing from 14.9 to 25.4?kHz as the pump power increases from the threshold power of 69.0?mW to the maximum pump power of 133.8?mW. The minimum pulse width of 4.4?μs was obtained at the maximum pump power of 133.8?mW while the highest energy of 0.74 nJ was obtained at the pump power of 69.0?mW.