Screening of Catalysts for Acrylonitrile Decomposition

The catalytic decomposition of acrylonitrile over various metal components (Mg, Ca, Mn, Fe, Co, Ni, Cu, Zn, Ga, Pd, Ag, and Pt) supported on several metal oxides (Al₂O₃, SiO₂, TiO₂, ZrO₂, and MgO) and ZSM-5 was studied. The most promising catalyst was Cu-ZSM-5, which exhibited 100% conversion and at least 80% N₂ selectivity above 350 °C.     

Faults and Claims about Thermal Environments in Relation to Energy Saving Measures in Smaller Office Buildings

Building equipment, energy-saving systems, and claims of inappropriate indoor thermal environments were analyzed in relation to the floor area using responses to a questionnaire survey of service managers of 157 buildings built in Osaka, Kyoto and Hyogo prefectures in Kinki area of Japan. Results show the following： （1） In smaller buildings （〈 5,000 m2）, setting temperatures are higher in summer and lower in winter, effects of ＂uncomfortable radiation from windows＂ are greater, energy-saving systems decrease indoor thermal comfort, but claims of ＂hot＂ and ＂cold＂ are fewer; （2） Claims of ＂hot＂ and ＂cold＂ are unrelated to the setting temperature and whether the air-conditioning control system is central or local; （3） The adoption rates of mitigation of dress codes （＂COOL-BIZ＂ and ＂WARM-BIZ＂） are higher than those of temperature mitigation of air conditioning.     

Oxidative Decomposition of N,N'-Dimethylformamide over Pt Catalysts with H2 Addition to the Feed

Catalysis of decomposition of dilute N, N'-dimethylformamide was explored. Among the catalysts investigated, Pt displayed the highest activity at low temperatures (~200 °C) and DMF conversion was promoted by H₂ addition to the feed. As the Pt support material, H-ZSM-5 exhibited the best performance at around 200 °C in terms of harmless decomposition.     

Stabilization of two families of critical targets for hyperthermic cell killing and acquired thermotolerance of yeast cells

Hyperthermic cell killing profiles of Saccharomyces cerevisiae cells were biphasic and a shoulder (phase 1) was followed by an exponential killing (phase 2). Assuming that (i) the rate of thermal damage in particular macromolecules or their assemblies limits the rate of hyperthermic cell killing (the critical target model), and (ii) the damages of two families of targets are lethal independently, we built a ‘dual critical target model’ in order to interpret the biphasic cell killing. Time-courses of temperature-programmed fractional survival were traced for S. cerevisiae cells in exponentially growing phase, heat shocked, and in stationary phase. Non-linear curve-fitting of the time-courses by using the dual critial target model provided the Arrhenius parameters of denaturation of the two families of targets. The cells were killed more slowly in phase 1 than in phase 2. Arrest in stationary phase, not heat shock, stabilizes the family of targets that is critical to phase 1 death. On the other hand, both heat-shock response and arrest in stationary phase stabilizes the other family of targets that, in addition to the previous one, is responsible for phase 2 death. © 1998 John Wiley & Sons, Ltd.     

Synthesis of alternating polyamideurethans by reacting diisocyanates with N,N′-di-(6-hydroxy-caproyl)alkylenediamines and N-hydroxy-alkyl-6-hydroxycaproamide

Polyamideurethans of structures I and II were prepared by reacting N,N′-di-(6-hydroxycaproyl)alkylenediamines and N-hydroxyalkyl-6-hydroxycaproamide with hexa-methylene diisocyanate and 4,4′-diphenylmethane diisocyanate: where R₁ is either a dimethylene or hexamethylene radical, and R₂ is a hexamethylene or 4,4′-diphenylmethane radical. Polymers I and II were of a high degree of polymerization and crystallinity, had high enough melting points for practical use, and gave colorless tough films both by dry and melt castings. The polymers from hexamethylene diisocyanate were much more crystalline and thermally more stable above the melting points than those from 4,4′-diphenylmethane diisocyanate. Polymerization conditions and characteristic properties of the resulting polymers were studied.     

Use of Double Wash-Coatings of Platinum and Zeolite Catalysts to Improve Selective Reduction of NOx by Hydrocarbons

The selective catalytic reduction by hydrocarbons (HC-SCR) of NO _x under lean conditions has been improved by the use of double-layered catalysts with a lower layer of Pt/SiO₂ and an upper layer of a zeolite such as H-, Ce-, and Cu-ferrierite (-FER). H-FER wash-coated over Pt/SiO₂ (H-FER//Pt/SiO₂) performed best among the samples examined. The promotional effect was attributed to the synergy of the oxidation catalyst (Pt/SiO₂) in converting NO into NO₂, which is more reactive to C₃H₆, and the HC-SCR catalyst (H-FER). Cu-FER//Pt/SiO₂ was also effective at widening the temperature window, but with this combination the performance was attributed to a simple summation of the activity of two HC-SCR catalysts that were active at different temperatures.     

Carbon oxidation with platinum supported catalysts

The effect of the support oxide, Pt precursor and reactant gas composition on the catalysis of soot oxidation was investigated using carbon black as a model soot and simulated exhaust gases. The Pt precursors used were Pt(NH₃)₄(OH)₂, H₂PtCl₆·6H₂O, Pt(NH₃)₄(NO₃)₂, and Pt(NH₃)₄Cl₂. The support metal oxides used were SiO₂, Al₂O₃, and ZrO₂. Pt/SiO₂ prepared from Pt(NH₃)₄(OH)₂ showed the highest carbon oxidation activity. It had much higher activity in the condition of N₂+O₂+H₂O+NO+SO₂ than without NO and SO₂.     

A catalytic diesel particulate filter with a heat recovery function

Based on a folded sheet design, we made and tested a miniature diesel particulate filter (DPF) that can transfer the heat generated by catalytic oxidation in the DPF to its upstream, thus promoting substantial temperature rise at the position where pieces of SiC felt working as PM filters are situated. When 0.6% of H₂, corresponding to 50 K in adiabatic temperature rise, was added to a 43 L/min of exhaust gas, the observed maximum temperature rise at the filter material exceeded 350 K, from which the heat recovery rate was estimated to be more than 86%. The PM filtration rates were 80–90%.     

A structural study of polyelectrolyte gels in a unidirectionally swollen state

We investigated the structures of polyelectrolyte gels, poly(N-isopropylacrylamide-co-2-acrylamido-2-methylpropane sulfonic acid) (NIPA/AMPS) hydrogels in a unidirectionally swollen state by using small-angle X-ray scattering (SAXS). The SAXS results show that the structure of the NIPA/AMPS gels strongly depends upon the composition of NIPA/AMPS. Increase in composition of AMPS causes suppression of concentration fluctuations in the long wavelength. As a consequence, a NIPA/AMPS hydrogel with a low composition of AMPS macroscopically phase-separated at high temperatures, while microphase separation occurred for a NIPA/AMPS gel with a higher composition of AMPS. The instability in the microphase separation initially occurred in the direction perpendicular to the swelling for the latter gel. In the disordered state near the microphase separation region, an elliptic scattering pattern was observed, and the scattering intensity around the peak position in the direction perpendicular to the unidirectionally swelling was larger than that in the direction parallel to it. The behavior became more remarkable, as the interaction parameter χ became larger. These behaviors are consistent with the prediction from the Rabin-Panukov theory. The scattering vector at the scattering maximum in the perpendicular direction q_m,⊥ significantly shifted to smaller q, where q represents the magnitude of the scattering vector, when the microphase separation occurred. It is shown that the periodicity of the microphase-separated structure ranged from 300 to 400 Å.     

A Multifunctional Converter for Purifying Diesel Exhaust Gas with a Self-Heat Exchange Function

As a continuation of our study of heat-integrated converters, we have fabricated a multifunctional converter that can treat all the components of emissions from diesel vehicles, namely CO, hydrocarbons, nitrogen oxides (NO _x ), and particulate matter (PM). NO _x is reduced over a NH₃-SCR catalyst while PM is removed by a diesel particulate filter. The converter is also equipped with a self-heat exchanger that transfers heat from downstream to upstream of the converter, increasing the converter temperature and thereby substantially improving its performance. In an experiment using a 2.2-L engine vehicle operated at a constant speed of 60 km/h, the NO _x and PM reduction rates respectively reached 98 and 99.97 % due to efficient heating of the exhaust gas from 117 to 320 °C in the converter by the addition of H₂ in the exhaust gas combined with the self-heat exchange function. Under transient driving conditions (Japanese 10–15 mode), the total NO _x reduction rate was 96 %.