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11.
Eduardo Muñoz José L. Boldú Eduardo Andrade Octavio Novaro Xi. Bokhimi Tessy López Ricardo Gómez 《Journal of the American Ceramic Society》2001,84(2):392-98
Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. 相似文献
12.
María Dolores Ayala Isaac Abdel Carmen Martínez Francisco Gil Octavio López Albors 《LWT》2010,43(3):465-17
Sea bream, Sparus aurata L., specimens were studied in pre-rigor (3 h) and during the following post-mortem days: 1, 5, 10, 15 and 22. Muscle and textural parameters were evaluated on 6 specimens/stage. Structural results showed scarce fibre-to-fibre detachment on pre-rigor, which increased during the post-mortem degradation. Ultrastructural changes revealed rapid muscle degradation. In pre-rigor myofibrils were detached to both sarcolemma and endomysium. Intermyofibrillar spaces increased and some mitochondriae and sarcoplasmic reticulum were swollen. After 1 day, the sarcolemma appeared occasionally disrupted and the interfibrillar spaces increased. From 5 to 10 days, the I-band and Z line presented some alterations, although these were more severe at 15-22 days. Thus, in these two last stages, loss of I-band, Z line and actin filaments was observed, that coincides with the alteration of the hexagonal arrangement in these advanced stages. Also, the fragmentation of myofibrils increased from 5 to 10 days on. Sarcolemma and endomysium were gradually disrupted throughout the post-mortem stages with total loss at 22 days. Consequently, the interfibrillar spaces increased at last stages. Autophagic mechanisms increased from 5 days on, with an intense destruction of all the intracytoplasmic organelles. Textural parameters decreased from pre-rigor until 5-10 days, mainly associated to detachment of myofibers to sarcolemma-endomysium. 相似文献
13.
E. Michael Thurman Imma Ferrer Octavio Malato Amadeo Rodriguez Fern ndez-Alba 《Food Additives & Contaminants》2006,23(11):1169-1178
Traditionally, the screening of unknown pesticides in food has been accomplished by GC/MS methods using conventional library-searching routines. However, many of the new polar and thermally labile pesticides are more readily and easily analysed by LC/MS methods and no searchable libraries currently exist (with the exception of some user libraries, which are limited). Therefore, there is a need for LC/MS libraries that can detect pesticides and their degradation products. This paper reports an identification scheme using a combination of LC/MS time-of-flight (accurate mass) and an Access database of 350 pesticides that are amenable to positive ion electrospray. The approach differs from conventional library searching of fragment ions. The concept consists of three parts: (1) initial screening of possible pesticides in actual market-place fruit extracts (apple and orange) using accurate mass and generating an accurate mass via an automatic ion-extraction routine, (2) searching the Access database manually for screening identification of a pesticide, and (3) identification of the suspected compound by accurate mass of at least one fragment ion and comparison of retention time with an actual standard. Imazalil and iprodione were identified in apples and thiabendazole in oranges using this database approach. 相似文献
14.
The DiffServ’s Assured Forwarding (af) Per-Hop Behavior (phb) Group defines a differentiated forwarding of packets in four independent classes, each class having three levels of drop precedence. Specific end-to-end services based on thisphb are still being defined. A particular type of service that could assure a given rate to a traffic aggregate has been outlined elsewhere. In such a service, a fair distribution of bandwidth is one of the main concerns. This paper presents experimental work carried out to evaluate howaf distributes bandwidth among flows under different load conditions and traffic patterns. We focused on the effect that marking mechanisms have on bandwidth sharing among flows within a singleaf class. The traffic types we used includeudp flows, individual and aggregatedtcp flows, mix oftcp andudp, tcp sessions with heterogeneous round-trip times, as well as color-blind and color-aware re-marking at the aggregation point fortcp flows. Tests were performed on real and simulated networks. We have found certain conditions under whichaf distributes bandwidth fairly among nonadaptiveudp flows andtcp aggregates. Finally, we evaluate a basic rule for setting the parameters of the two-rate Three-Color Marker conditioning algorithm (trtcm) in order to achieve a better bandwidth distribution fortcp flows. 相似文献
15.
Applications of environmental scanning electron microscopy (ESEM) in biomaterials field 总被引:1,自引:0,他引:1
Various tasks were undertaken in our laboratory where environmental scanning electron microscopy (ESEM) has been of particular interest within the biomaterials field. The possibility of observing wet samples, as well as the fact that sample preparation is minimal, has improved shorter time scales and lower costs in microscopy. Minimal preparation has also reduced the possibility of introducing artifacts. Examples like cell cultures used for pit resorption assays, calcium phosphate deposition processes, and dissolution of phosphate glasses used as biomaterials are presented. Finally, a servohydraulic testing machine designed for mechanical testing in situ in ESEM has allowed the study of shape memory alloys for orthodontic applications or the behavior of different adhesives used in odontology. 相似文献
16.
Service composition in multi-Cloud environments must coordinate self-interested participants, automate service selection, (re)configure distributed services, and deal with incomplete information about Cloud providers and their services. This work proposes an agent-based approach to compose services in multi-Cloud environments for different types of Cloud services: one-time virtualized services, e.g., processing a rendering job, persistent virtualized services, e.g., infrastructure-as-a-service scenarios, vertical services, e.g., integrating homogenous services, and horizontal services, e.g., integrating heterogeneous services. Agents are endowed with a semi-recursive contract net protocol and service capability tables (information catalogs about Cloud participants) to compose services based on consumer requirements. Empirical results obtained from an agent-based testbed show that agents in this work can: successfully compose services to satisfy service requirements, autonomously select services based on dynamic fees, effectively cope with constantly changing consumers’ service needs that trigger updates, and compose services in multiple Clouds even with incomplete information about Cloud participants. 相似文献
17.
Octavio Pozo Garcia Vesa-Matti Tikkala Alexey Zakharov Sirkka-Liisa Jämsä-Jounela 《Control Engineering Practice》2013,21(6):818-828
The performance of a modern industrial plant can be severely affected by the performance of its key devices, such as valves. In particular, valve stiction can cause poor performance in control loops and can consequently lower the efficiency of the plant and the quality of the product. This paper presents an integrated FDD system for valve stiction which employs various FDD methods in a parallel configuration. A reliability index was integrated into each method in order to estimate their degree of influence in the final diagnosis of the system. Each method and the integrated system were tested using industrial data. 相似文献
18.
Natalya V. Likhanova Octavio Olivares-Xometl Noel Nava-Entzana Hector Dorantes 《Corrosion Science》2010,52(6):2088-2097
Ionic liquids with chemical formula 1,3-dioctadecylimidazolium bromide and N-Octadecylpyridinium bromide were synthesized by conventional and microwave-assisted reactions, respectively. Ionic liquids tested as corrosion inhibitors after polarization curves displayed corrosion protection efficiency within 82-88% at 100 ppm for mild steel in a 1 M aqueous solution of sulfuric acid. Standard free energy indicated that corrosion inhibition occurred by a chemical adsorption process. Surface analysis (SEM, EDX) completed by XRD and Mössbauer spectroscopy indicated the presence of carbon species pertaining to inhibitor and corrosion products, which was rationalized in an inhibition mechanism. 相似文献
19.
Martha Lomeli Luisa Maria Flores-Velez Imelda Esparza Roberto Torres Octavio Domínguez 《Journal of the American Ceramic Society》2009,92(7):1526-1533
The present work represents preliminary results concerning the effect of nanometric CaF2 particles on the sintering behavior of kaolin. The nanoparticles were synthesized using aqueous solutions of CaCl2 dissolved with an organic dispersant and HF. The morphology and particle size of the obtained nanoparticles were square-like, having a mean length of 25 nm. Kaolin was mixed with different amounts of nanometric CaF2 (from 0.625 to 5.0 wt%) and the mixtures were milled, pressed, and sintered. From sintering experiments, it was observed that additions of CaF2 nanoparticles in kaolin clay could shift the phase transition temperatures to lower values. Specifically, the densification temperature could be reduced by almost 150°C when 2.5 wt% of CaF2 was incorporated. Besides, adding 1.25% of nanometric CaF2 can achieve that compressive strength augments from 125 to 185 MPa in kaolin samples sintered at 1200°C, meaning an improvement of 40% in the properties of the final material. 相似文献
20.